Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions

Detalhes bibliográficos
Autor(a) principal: Li,X.H.
Data de Publicação: 2008
Outros Autores: Jalbout,A. F., Xiang,W.D.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Eclética Química
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702008000200002
Resumo: A new Cu(II) trimers, [Cu3(dcp)2(H2O)8]. 4DMF, with the ligand 3,5-pyrazoledicarboxylic acid monohydrate (H3dcp) has been prepared by solvent method. Its solid-state structure has been characterized by elemental analysis, thermal analysis (TGA and DSC), and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this complex has extended 1-D,2-D and 3-D supramolecular architectures directed by weak interactions (hydrogen bond and aromatic π-π stacking interaction) leading to a sandwich solid-state structure.
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spelling Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactionsCopper complexcrystal structuresupramolecularπ-π interactionA new Cu(II) trimers, [Cu3(dcp)2(H2O)8]. 4DMF, with the ligand 3,5-pyrazoledicarboxylic acid monohydrate (H3dcp) has been prepared by solvent method. Its solid-state structure has been characterized by elemental analysis, thermal analysis (TGA and DSC), and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this complex has extended 1-D,2-D and 3-D supramolecular architectures directed by weak interactions (hydrogen bond and aromatic π-π stacking interaction) leading to a sandwich solid-state structure.Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP2008-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702008000200002Eclética Química v.33 n.2 2008reponame:Eclética Químicainstname:Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)instacron:UNESP10.1590/S0100-46702008000200002info:eu-repo/semantics/openAccessLi,X.H.Jalbout,A. F.Xiang,W.D.eng2008-07-17T00:00:00Zoai:scielo:S0100-46702008000200002Revistahttp://revista.iq.unesp.br/ojs/index.php/ecletica/PUBhttps://revista.iq.unesp.br/ojs/index.php/ecletica/oaiecletica@ctrlk.com.br||ecletica@iq.unesp.br1678-46181678-4618opendoar:2008-07-17T00:00Eclética Química - Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)false
dc.title.none.fl_str_mv Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions
title Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions
spellingShingle Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions
Li,X.H.
Copper complex
crystal structure
supramolecular
π-π interaction
title_short Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions
title_full Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions
title_fullStr Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions
title_full_unstemmed Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions
title_sort Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions
author Li,X.H.
author_facet Li,X.H.
Jalbout,A. F.
Xiang,W.D.
author_role author
author2 Jalbout,A. F.
Xiang,W.D.
author2_role author
author
dc.contributor.author.fl_str_mv Li,X.H.
Jalbout,A. F.
Xiang,W.D.
dc.subject.por.fl_str_mv Copper complex
crystal structure
supramolecular
π-π interaction
topic Copper complex
crystal structure
supramolecular
π-π interaction
description A new Cu(II) trimers, [Cu3(dcp)2(H2O)8]. 4DMF, with the ligand 3,5-pyrazoledicarboxylic acid monohydrate (H3dcp) has been prepared by solvent method. Its solid-state structure has been characterized by elemental analysis, thermal analysis (TGA and DSC), and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this complex has extended 1-D,2-D and 3-D supramolecular architectures directed by weak interactions (hydrogen bond and aromatic π-π stacking interaction) leading to a sandwich solid-state structure.
publishDate 2008
dc.date.none.fl_str_mv 2008-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702008000200002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702008000200002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0100-46702008000200002
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP
publisher.none.fl_str_mv Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP
dc.source.none.fl_str_mv Eclética Química v.33 n.2 2008
reponame:Eclética Química
instname:Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Eclética Química
collection Eclética Química
repository.name.fl_str_mv Eclética Química - Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)
repository.mail.fl_str_mv ecletica@ctrlk.com.br||ecletica@iq.unesp.br
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