Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitation

Detalhes bibliográficos
Autor(a) principal: Mesquita Júnior, Jarbas Soares de
Data de Publicação: 2021
Outros Autores: Figueiredo, Francisco Cardoso, Santos, Evânia Carvalho dos, Silva, Darlisson Slag Neri, Santos Júnior, José Ribeiro dos
Tipo de documento: Artigo
Idioma: por
Título da fonte: Research, Society and Development
Texto Completo: https://rsdjournal.org/index.php/rsd/article/view/15331
Resumo: The present work aimed to develop a composite based on cellulose, melamine and silica. Cellulose was obtained from the pruning residues of Mangifera indica for the chemically assisted primary treatment of effluents from the textile industry. The composite was characterized by FT-IR, SEM, TEM, TGA-DTG and Zeta Potential. The central composite planning was applied to optimize the composite mass and contact time in removing methylene blue. FT-IR showed that the composite presented the band for melamine at 815 cm-1. SEM and TEM revealed that on the composite surface there is melamine nitrogen, silicon and sodium from the catalyst. TGA-DTG showed that the composite is thermally more stable than cellulose, with 65% degradation. Due to the zeta potential, pH values above 5 provide greater stabilization and increase the anionic character of the composite. It was chosen as the best condition for the application 60 mg of composite and 30 minutes of contact time, with removal of 88.6 ± 3.5% of the methylene blue. The pH study revealed that above 5, the composite is more efficient. The dye adsorption process by the material was consistent with the Langmuir model (R2 = 0.9921). Thus, the cellulose-melamine-silica composite developed was effective in removing the methylene blue dye, presenting itself as a low-cost, biodegradable and efficient material, with potential for application in the treatment of effluents from the textile industry.
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spelling Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitationCelulosa (Mangifera indica) modificada por melamina-sílice aplicada en el tratamiento de efluentes con precipitación asistida químicamenteCelulose (Mangifera indica) modificada por melamina-sílica aplicada no tratamento de efluentes com precipitação quimicamente assistidaMangifera indicaCelulosaCEPTAzul de metilenoAdsorción.Mangifera indicaCeluloseCEPTAzul de MetilenoAdsorção.Mangifera indicaCelluloseCEPTMethylene BlueAdsorption.The present work aimed to develop a composite based on cellulose, melamine and silica. Cellulose was obtained from the pruning residues of Mangifera indica for the chemically assisted primary treatment of effluents from the textile industry. The composite was characterized by FT-IR, SEM, TEM, TGA-DTG and Zeta Potential. The central composite planning was applied to optimize the composite mass and contact time in removing methylene blue. FT-IR showed that the composite presented the band for melamine at 815 cm-1. SEM and TEM revealed that on the composite surface there is melamine nitrogen, silicon and sodium from the catalyst. TGA-DTG showed that the composite is thermally more stable than cellulose, with 65% degradation. Due to the zeta potential, pH values above 5 provide greater stabilization and increase the anionic character of the composite. It was chosen as the best condition for the application 60 mg of composite and 30 minutes of contact time, with removal of 88.6 ± 3.5% of the methylene blue. The pH study revealed that above 5, the composite is more efficient. The dye adsorption process by the material was consistent with the Langmuir model (R2 = 0.9921). Thus, the cellulose-melamine-silica composite developed was effective in removing the methylene blue dye, presenting itself as a low-cost, biodegradable and efficient material, with potential for application in the treatment of effluents from the textile industry.Este trabajo tuvo como objetivo desarrollar un composite a base de celulosa, melamina y sílice. La celulosa se obtuvo de los residuos de poda de Mangifera indica para el tratamiento primario asistido químicamente de efluentes de la industria textil. El compuesto se caracterizó por FT-IR, MEV, MET, TG-DTG y Zeta Potential. Se aplicó la planificación central del compuesto para optimizar la masa del compuesto y el tiempo de contacto para eliminar el azul de metileno. FT-IR mostró que el composite presentaba la banda de melamina a 815 cm-1. SEM y MET revelaron que en la superficie compuesta hay nitrógeno de melamina, silicio y sodio del catalizador. TG-DTG demostró que el material compuesto es térmicamente más estable que la celulosa, con un 65% de degradación. Debido al potencial zeta, los valores de pH superiores a 5 proporcionan una mayor estabilización y aumentan el carácter aniónico del material compuesto. Se eligió como la mejor condición para la aplicación de 60 mg de composite y 30 minutos de tiempo de contacto, con remoción del 88,6 ± 3,5% del azul de metileno. El estudio de pH reveló que por encima de 5, el compuesto es más eficiente. El proceso de adsorción del tinte por el material fue consistente con el modelo de Langmuir (R2 = 0.9921). Así, el compuesto de celulosa-melamina-sílice desarrollado fue eficaz para eliminar el colorante azul de metileno, presentándose como un material de bajo costo, biodegradable y eficiente, con potencial de aplicación en el tratamiento de efluentes de la industria textil.Este trabalho objetivou desenvolver um compósito a base de celulose, melamina e sílica. A celulose foi obtida dos resíduos de poda da Mangifera indica para o tratamento primário quimicamente assistido de efluentes da indústria têxtil. O compósito foi caracterizado por FT-IR, MEV, MET, TG-DTG e Potencial Zeta. O planejamento composto central foi aplicado para otimização da massa de compósito e tempo de contato na remoção de azul de metileno. O FT-IR mostrou que o compósito apresentou a banda para a melamina em 815 cm-1. O MEV e MET revelaram que na superfície do compósito há Nitrogênio da melamina, Silício e Sódio oriundos do catalisador. O TG-DTG mostrou que o compósito é termicamente mais estável que a celulose, com 65% de degradação. Pelo potencial zeta, valores de pH acima de 5 propiciam maior estabilização e incremento do caráter aniônico do compósito. Escolheu-se como a melhor condição para a aplicação 60 mg de compósito e 30 minutos de tempo de contato, com remoção de 88,6 ± 3,5% do azul de metileno. O estudo do pH revelou que acima de 5, o compósito é mais eficiente. O processo de adsorção do corante pelo material apresentou-se coerente ao modelo de Langmuir (R2 = 0,9921). Assim, o compósito de celulose-melamina-sílica desenvolvido foi eficaz na remoção do corante azul de metileno, apresentando-se como um material de baixo custo, biodegradável e eficiente, com potencialidades para a aplicação no tratamento dos efluentes da indústria têxtil.Research, Society and Development2021-05-20info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/1533110.33448/rsd-v10i6.15331Research, Society and Development; Vol. 10 No. 6; e3710615331Research, Society and Development; Vol. 10 Núm. 6; e3710615331Research, Society and Development; v. 10 n. 6; e37106153312525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIporhttps://rsdjournal.org/index.php/rsd/article/view/15331/13830Copyright (c) 2021 Jarbas Soares de Mesquita Júnior; Francisco Cardoso Figueiredo; Evânia Carvalho dos Santos; Darlisson Slag Neri Silva; José Ribeiro dos Santos Júniorhttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessMesquita Júnior, Jarbas Soares de Figueiredo, Francisco CardosoSantos, Evânia Carvalho dosSilva, Darlisson Slag NeriSantos Júnior, José Ribeiro dos2021-06-10T22:51:46Zoai:ojs.pkp.sfu.ca:article/15331Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:36:10.966949Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false
dc.title.none.fl_str_mv Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitation
Celulosa (Mangifera indica) modificada por melamina-sílice aplicada en el tratamiento de efluentes con precipitación asistida químicamente
Celulose (Mangifera indica) modificada por melamina-sílica aplicada no tratamento de efluentes com precipitação quimicamente assistida
title Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitation
spellingShingle Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitation
Mesquita Júnior, Jarbas Soares de
Mangifera indica
Celulosa
CEPT
Azul de metileno
Adsorción.
Mangifera indica
Celulose
CEPT
Azul de Metileno
Adsorção.
Mangifera indica
Cellulose
CEPT
Methylene Blue
Adsorption.
title_short Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitation
title_full Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitation
title_fullStr Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitation
title_full_unstemmed Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitation
title_sort Cellulose (Mangifera indica) modified by melamine-silica applied in the treatment of effluents with chemically assisted precipitation
author Mesquita Júnior, Jarbas Soares de
author_facet Mesquita Júnior, Jarbas Soares de
Figueiredo, Francisco Cardoso
Santos, Evânia Carvalho dos
Silva, Darlisson Slag Neri
Santos Júnior, José Ribeiro dos
author_role author
author2 Figueiredo, Francisco Cardoso
Santos, Evânia Carvalho dos
Silva, Darlisson Slag Neri
Santos Júnior, José Ribeiro dos
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Mesquita Júnior, Jarbas Soares de
Figueiredo, Francisco Cardoso
Santos, Evânia Carvalho dos
Silva, Darlisson Slag Neri
Santos Júnior, José Ribeiro dos
dc.subject.por.fl_str_mv Mangifera indica
Celulosa
CEPT
Azul de metileno
Adsorción.
Mangifera indica
Celulose
CEPT
Azul de Metileno
Adsorção.
Mangifera indica
Cellulose
CEPT
Methylene Blue
Adsorption.
topic Mangifera indica
Celulosa
CEPT
Azul de metileno
Adsorción.
Mangifera indica
Celulose
CEPT
Azul de Metileno
Adsorção.
Mangifera indica
Cellulose
CEPT
Methylene Blue
Adsorption.
description The present work aimed to develop a composite based on cellulose, melamine and silica. Cellulose was obtained from the pruning residues of Mangifera indica for the chemically assisted primary treatment of effluents from the textile industry. The composite was characterized by FT-IR, SEM, TEM, TGA-DTG and Zeta Potential. The central composite planning was applied to optimize the composite mass and contact time in removing methylene blue. FT-IR showed that the composite presented the band for melamine at 815 cm-1. SEM and TEM revealed that on the composite surface there is melamine nitrogen, silicon and sodium from the catalyst. TGA-DTG showed that the composite is thermally more stable than cellulose, with 65% degradation. Due to the zeta potential, pH values above 5 provide greater stabilization and increase the anionic character of the composite. It was chosen as the best condition for the application 60 mg of composite and 30 minutes of contact time, with removal of 88.6 ± 3.5% of the methylene blue. The pH study revealed that above 5, the composite is more efficient. The dye adsorption process by the material was consistent with the Langmuir model (R2 = 0.9921). Thus, the cellulose-melamine-silica composite developed was effective in removing the methylene blue dye, presenting itself as a low-cost, biodegradable and efficient material, with potential for application in the treatment of effluents from the textile industry.
publishDate 2021
dc.date.none.fl_str_mv 2021-05-20
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/15331
10.33448/rsd-v10i6.15331
url https://rsdjournal.org/index.php/rsd/article/view/15331
identifier_str_mv 10.33448/rsd-v10i6.15331
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/15331/13830
dc.rights.driver.fl_str_mv https://creativecommons.org/licenses/by/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Research, Society and Development
publisher.none.fl_str_mv Research, Society and Development
dc.source.none.fl_str_mv Research, Society and Development; Vol. 10 No. 6; e3710615331
Research, Society and Development; Vol. 10 Núm. 6; e3710615331
Research, Society and Development; v. 10 n. 6; e3710615331
2525-3409
reponame:Research, Society and Development
instname:Universidade Federal de Itajubá (UNIFEI)
instacron:UNIFEI
instname_str Universidade Federal de Itajubá (UNIFEI)
instacron_str UNIFEI
institution UNIFEI
reponame_str Research, Society and Development
collection Research, Society and Development
repository.name.fl_str_mv Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)
repository.mail.fl_str_mv rsd.articles@gmail.com
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