Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillation

Detalhes bibliográficos
Autor(a) principal: Rodrigues, Leonardo Milani Avelar
Data de Publicação: 2020
Outros Autores: Cardoso, Maria das Graças, Santiago, Wilder Douglas, Barbosa, Richard Bispo, Santiago, Juliana de Andrade, Lima, Lidiany Mendonça Zacaroni, Nelson, David Lee
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Research, Society and Development
Texto Completo: https://rsdjournal.org/index.php/rsd/article/view/4879
Resumo: The present work aimed to characterize and quantify four contaminants (ethyl carbamate, 2,3-butanedione, furfural and 5-hydroxymethylfurfural) present in still and industrial cachaça. The four contaminants ethyl carbamate, 2,3-butanedione, furfural (FU) and 5-hydroxymethylfurfural (5-HMF) were analyzed in spirits produced by alembic and column distillation. Forty-four samples of cachaça were collected in the southern, central-western, and southeastern regions of the state of Minas Gerais and in the state of São Paulo. The samples were subjected to chromatographic analysis. Ethyl carbamate, 2,3-butanedione, furfural and 5-HMF were characterized and quantified by HPLC. Two samples of spirits were found to contain concentrations of ethyl carbamate that were greater than the legal limits, ranging from 245.31 to 235.53 μg L-1. None of the alembic samples had concentrations higher than the legal limit. The spirits obtained by column disitllation contained higher concentrations of the 2,3-butanedione than the alembic liquors. An analytical method was developed and validated for the quantification of furfural and 5-HMF, and the spirits obtained by column distillation contained concentrations higher than the limit established by legislation.
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spelling Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillationCuantificación de contaminantes orgánicos en aguardientes de cana/cachaza producidos por destilación en columna y todavía cobreQuantificação de contaminantes orgânicos em aguardentes de cana/cachaça produzidas por destilação em coluna e de alambique de cobreCaña de azúcarCalidadBebidasContaminantesCana de açucarBebidasQualidadeContaminantessugar canedrinksqualitycontaminantsThe present work aimed to characterize and quantify four contaminants (ethyl carbamate, 2,3-butanedione, furfural and 5-hydroxymethylfurfural) present in still and industrial cachaça. The four contaminants ethyl carbamate, 2,3-butanedione, furfural (FU) and 5-hydroxymethylfurfural (5-HMF) were analyzed in spirits produced by alembic and column distillation. Forty-four samples of cachaça were collected in the southern, central-western, and southeastern regions of the state of Minas Gerais and in the state of São Paulo. The samples were subjected to chromatographic analysis. Ethyl carbamate, 2,3-butanedione, furfural and 5-HMF were characterized and quantified by HPLC. Two samples of spirits were found to contain concentrations of ethyl carbamate that were greater than the legal limits, ranging from 245.31 to 235.53 μg L-1. None of the alembic samples had concentrations higher than the legal limit. The spirits obtained by column disitllation contained higher concentrations of the 2,3-butanedione than the alembic liquors. An analytical method was developed and validated for the quantification of furfural and 5-HMF, and the spirits obtained by column distillation contained concentrations higher than the limit established by legislation.El presente trabajo tuvo como objetivo caracterizar y cuantificar cuatro contaminantes (carbamato de etilo, 2,3-butanodiona, furfural y 5-hidroximetilfurfural) presentes en la cachaça industrial e inmóvil. Fueron analizados cuatro contaminantes en bebidas producidas por destilación de alambique y columna: carbamato de etilo, 2,3-butanodiona, furfural (FU) y 5-hidroximetilfurfural (5-HMF). Cuarenta y cuatro muestras de aguardientes (conocidas popularmente en el Brasil como “cachaça”, cachaza) se recolectaron en las regiones sur, medio oeste y sudeste de los estados de Minas Gerais y São Paulo (Brasil). Las muestras fueron sometidas a análisis cromatográfico y el carbamato de etilo, la 2,3-butanodiona, el furfural y el 5-HMF se caracterizaron y cuantificaron por la técnica de cromatografía líquida de alto desempeño (HPLC). Se encontró que dos muestras de bebidas contenían concentraciones de carbamato de etilo entre 245,31 y 235,53 μg L-1, valores por encima de los límites legales. Ninguna de las muestras de alambique mostró concentraciones superiores al límite legal. Las bebidas obtenidas de la destilación de columna contenían concentraciones de 2,3-butanodiona más altas que aquellas obtenidas por la técnica de alambique. Se desarrolló y validó un método analítico para la cuantificación de furfural y 5-HMF, y las bebidas obtenidas por destilación de columna contenían concentraciones superiores al límite establecido por la legislación vigente.No presente trabalho objetivou-se caracterizar e quantificar quatro contaminantes (carbamato de etila, 2,3-butanodiona, furfural e 5-hidroximetilfurfural) presentes em cachaça de alambique e industrial. Os quatro contaminantes carbamato de etila, 2,3-butanodiona, furfural (FU) e 5- hidroximetilfurfural (5-HMF) foram analisados em bebidas produzidas por destilação de alambique e coluna. Quarenta e quatro amostras de cachaças foram coletadas nas regiões sul, centro-oeste e sudeste dos Estados de Minas Gerais e São Paulo. O carbamato de etila, 2,3-butanodiona, furfural e 5-HMF foram caracterizados e quantificados por HPLC. Verificou-se que duas amostras de bebidas continham concentrações de carbamato de etila superiores aos limites legais, variando de 245,31 a 235,53 μg L-1. Nenhuma das amostras de alambique apresentou concentrações superiores ao limite legal. As bebidas obtidas pela desililação da coluna continham concentrações mais altas de 2,3-butanodiona do que as cachças de alambique. Um método analítico foi desenvolvido e validado para a quantificação de furfural e 5-HMF, e bebidas obtidas por destilação em coluna continham concentrações superiores ao limite estabelecido pela legislação.Research, Society and Development2020-06-16info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/487910.33448/rsd-v9i7.4879Research, Society and Development; Vol. 9 No. 7; e930974879Research, Society and Development; Vol. 9 Núm. 7; e930974879Research, Society and Development; v. 9 n. 7; e9309748792525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIenghttps://rsdjournal.org/index.php/rsd/article/view/4879/4419Copyright (c) 2020 Leonardo Milani Avelar Rodrigues, Maria das Graças Cardoso, Wilder Douglas Santiago, Richard Bispo Barbosa, Juliana de Andrade Santiago, Lidiany Mendonça Zacaroni Lima, David Lee Nelsoninfo:eu-repo/semantics/openAccessRodrigues, Leonardo Milani AvelarCardoso, Maria das GraçasSantiago, Wilder DouglasBarbosa, Richard BispoSantiago, Juliana de AndradeLima, Lidiany Mendonça ZacaroniNelson, David Lee2020-08-20T18:05:03Zoai:ojs.pkp.sfu.ca:article/4879Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:28:35.382661Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false
dc.title.none.fl_str_mv Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillation
Cuantificación de contaminantes orgánicos en aguardientes de cana/cachaza producidos por destilación en columna y todavía cobre
Quantificação de contaminantes orgânicos em aguardentes de cana/cachaça produzidas por destilação em coluna e de alambique de cobre
title Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillation
spellingShingle Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillation
Rodrigues, Leonardo Milani Avelar
Caña de azúcar
Calidad
Bebidas
Contaminantes
Cana de açucar
Bebidas
Qualidade
Contaminantes
sugar cane
drinks
quality
contaminants
title_short Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillation
title_full Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillation
title_fullStr Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillation
title_full_unstemmed Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillation
title_sort Organic contaminants in distilled sugar cane spirits produced by column and copper alembic distillation
author Rodrigues, Leonardo Milani Avelar
author_facet Rodrigues, Leonardo Milani Avelar
Cardoso, Maria das Graças
Santiago, Wilder Douglas
Barbosa, Richard Bispo
Santiago, Juliana de Andrade
Lima, Lidiany Mendonça Zacaroni
Nelson, David Lee
author_role author
author2 Cardoso, Maria das Graças
Santiago, Wilder Douglas
Barbosa, Richard Bispo
Santiago, Juliana de Andrade
Lima, Lidiany Mendonça Zacaroni
Nelson, David Lee
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Rodrigues, Leonardo Milani Avelar
Cardoso, Maria das Graças
Santiago, Wilder Douglas
Barbosa, Richard Bispo
Santiago, Juliana de Andrade
Lima, Lidiany Mendonça Zacaroni
Nelson, David Lee
dc.subject.por.fl_str_mv Caña de azúcar
Calidad
Bebidas
Contaminantes
Cana de açucar
Bebidas
Qualidade
Contaminantes
sugar cane
drinks
quality
contaminants
topic Caña de azúcar
Calidad
Bebidas
Contaminantes
Cana de açucar
Bebidas
Qualidade
Contaminantes
sugar cane
drinks
quality
contaminants
description The present work aimed to characterize and quantify four contaminants (ethyl carbamate, 2,3-butanedione, furfural and 5-hydroxymethylfurfural) present in still and industrial cachaça. The four contaminants ethyl carbamate, 2,3-butanedione, furfural (FU) and 5-hydroxymethylfurfural (5-HMF) were analyzed in spirits produced by alembic and column distillation. Forty-four samples of cachaça were collected in the southern, central-western, and southeastern regions of the state of Minas Gerais and in the state of São Paulo. The samples were subjected to chromatographic analysis. Ethyl carbamate, 2,3-butanedione, furfural and 5-HMF were characterized and quantified by HPLC. Two samples of spirits were found to contain concentrations of ethyl carbamate that were greater than the legal limits, ranging from 245.31 to 235.53 μg L-1. None of the alembic samples had concentrations higher than the legal limit. The spirits obtained by column disitllation contained higher concentrations of the 2,3-butanedione than the alembic liquors. An analytical method was developed and validated for the quantification of furfural and 5-HMF, and the spirits obtained by column distillation contained concentrations higher than the limit established by legislation.
publishDate 2020
dc.date.none.fl_str_mv 2020-06-16
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/4879
10.33448/rsd-v9i7.4879
url https://rsdjournal.org/index.php/rsd/article/view/4879
identifier_str_mv 10.33448/rsd-v9i7.4879
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/4879/4419
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Research, Society and Development
publisher.none.fl_str_mv Research, Society and Development
dc.source.none.fl_str_mv Research, Society and Development; Vol. 9 No. 7; e930974879
Research, Society and Development; Vol. 9 Núm. 7; e930974879
Research, Society and Development; v. 9 n. 7; e930974879
2525-3409
reponame:Research, Society and Development
instname:Universidade Federal de Itajubá (UNIFEI)
instacron:UNIFEI
instname_str Universidade Federal de Itajubá (UNIFEI)
instacron_str UNIFEI
institution UNIFEI
reponame_str Research, Society and Development
collection Research, Society and Development
repository.name.fl_str_mv Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)
repository.mail.fl_str_mv rsd.articles@gmail.com
_version_ 1797052815800008704

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