Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopy

Detalhes bibliográficos
Autor(a) principal: Carvalho, Lívia C. [UNESP]
Data de Publicação: 2019
Outros Autores: Leite, Marcondes L., Morais, Camilo L.M., Lima, Kássio M.G., Teixeira, Gustavo H.A. [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1016/j.lwt.2018.12.056
http://hdl.handle.net/11449/188580
Resumo: We have developed a rapid non-destructive method to assess the oxidative stability of intact macadamia nuts using near-infrared spectroscopy (NIRS). Intact macadamia nuts of the cultivars HAES 344 ‘Kau’ HAES 660 ‘Keaau’ IAC 4–12 B, and IAC Campinas B were harvested and immediately oven-dried for 4 days at 30 °C, 2 days at 40 °C, and 1 day at 60 °C to achieve 1.5% kernel moisture content. At each drying step nuts were withdrawn and their moisture content, peroxide value (PV), and acidity index (AI) determined. The best partial least square model for PV prediction was obtained using the Savitzky-Golay (SG) second derivative resulting in a standard error of prediction (SEP) of 0.55 meq·kg −1 and a coefficient of determination (R 2 C ) of 0.57. The best AI prediction-model result was obtained using the SG second derivative (SEP = 0.14%, R 2 C = 0.29). Based on the maximum quality limits of 3 meq·kg −1 for PV and 0.5% for AI, the SEP values represented 18% and 28%, respectively. Therefore, the prediction method can be considered useful since the errors are lower than the quality limits. Thus, NIRS can be used to assess the oxidative stability of intact macadamia kernels.
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spelling Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopyAcidity indexMacadamia integrifolia Maiden & BetchePeroxide valueprincipal component analysisWe have developed a rapid non-destructive method to assess the oxidative stability of intact macadamia nuts using near-infrared spectroscopy (NIRS). Intact macadamia nuts of the cultivars HAES 344 ‘Kau’ HAES 660 ‘Keaau’ IAC 4–12 B, and IAC Campinas B were harvested and immediately oven-dried for 4 days at 30 °C, 2 days at 40 °C, and 1 day at 60 °C to achieve 1.5% kernel moisture content. At each drying step nuts were withdrawn and their moisture content, peroxide value (PV), and acidity index (AI) determined. The best partial least square model for PV prediction was obtained using the Savitzky-Golay (SG) second derivative resulting in a standard error of prediction (SEP) of 0.55 meq·kg −1 and a coefficient of determination (R 2 C ) of 0.57. The best AI prediction-model result was obtained using the SG second derivative (SEP = 0.14%, R 2 C = 0.29). Based on the maximum quality limits of 3 meq·kg −1 for PV and 0.5% for AI, the SEP values represented 18% and 28%, respectively. Therefore, the prediction method can be considered useful since the errors are lower than the quality limits. Thus, NIRS can be used to assess the oxidative stability of intact macadamia kernels.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Universidade Estadual Paulista (UNESP) Faculdade de Ciências Farmacêuticas (FCFAR) Departamento de Alimentos e Nutrição Campus de Araraquara, Rodovia Araraquara-Jaú km 1 – CP 502Instituto Federal de Educação Ciência e Tecnologia do Maranhão (IFMA) Campus São Luís-Maracanã, Avenida dos Curiós, s/n, Vila EsperançaUniversity of Central Lancashire School of Pharmacy and Biomedical SciencesUniversidade Federal do Rio Grande do Norte (UFRN) Instituto de Química Química Biológica e Quimiometria, Avenida Senador Salgado Filho, n° 3000, Bairro de Lagoa NovaUniversidade Estadual Paulista (UNESP) Faculdade de Ciências Agrárias e Veterinárias (FCAV) Campus de Jaboticabal, Via de Acesso Prof. Paulo Donato Castellane s/nUniversidade Estadual Paulista (UNESP) Faculdade de Ciências Farmacêuticas (FCFAR) Departamento de Alimentos e Nutrição Campus de Araraquara, Rodovia Araraquara-Jaú km 1 – CP 502Universidade Estadual Paulista (UNESP) Faculdade de Ciências Agrárias e Veterinárias (FCAV) Campus de Jaboticabal, Via de Acesso Prof. Paulo Donato Castellane s/nCAPES: 001Universidade Estadual Paulista (Unesp)Ciência e Tecnologia do Maranhão (IFMA)School of Pharmacy and Biomedical SciencesQuímica Biológica e QuimiometriaCarvalho, Lívia C. [UNESP]Leite, Marcondes L.Morais, Camilo L.M.Lima, Kássio M.G.Teixeira, Gustavo H.A. [UNESP]2019-10-06T16:12:41Z2019-10-06T16:12:41Z2019-04-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article101-107http://dx.doi.org/10.1016/j.lwt.2018.12.056LWT, v. 103, p. 101-107.0023-6438http://hdl.handle.net/11449/18858010.1016/j.lwt.2018.12.0562-s2.0-85059581501Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengLWTinfo:eu-repo/semantics/openAccess2021-10-22T21:09:51Zoai:repositorio.unesp.br:11449/188580Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-22T21:09:51Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopy
title Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopy
spellingShingle Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopy
Carvalho, Lívia C. [UNESP]
Acidity index
Macadamia integrifolia Maiden & Betche
Peroxide value
principal component analysis
title_short Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopy
title_full Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopy
title_fullStr Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopy
title_full_unstemmed Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopy
title_sort Non-destructive assessment of the oxidative stability of intact macadamia nuts during the drying process by near-infrared spectroscopy
author Carvalho, Lívia C. [UNESP]
author_facet Carvalho, Lívia C. [UNESP]
Leite, Marcondes L.
Morais, Camilo L.M.
Lima, Kássio M.G.
Teixeira, Gustavo H.A. [UNESP]
author_role author
author2 Leite, Marcondes L.
Morais, Camilo L.M.
Lima, Kássio M.G.
Teixeira, Gustavo H.A. [UNESP]
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
Ciência e Tecnologia do Maranhão (IFMA)
School of Pharmacy and Biomedical Sciences
Química Biológica e Quimiometria
dc.contributor.author.fl_str_mv Carvalho, Lívia C. [UNESP]
Leite, Marcondes L.
Morais, Camilo L.M.
Lima, Kássio M.G.
Teixeira, Gustavo H.A. [UNESP]
dc.subject.por.fl_str_mv Acidity index
Macadamia integrifolia Maiden & Betche
Peroxide value
principal component analysis
topic Acidity index
Macadamia integrifolia Maiden & Betche
Peroxide value
principal component analysis
description We have developed a rapid non-destructive method to assess the oxidative stability of intact macadamia nuts using near-infrared spectroscopy (NIRS). Intact macadamia nuts of the cultivars HAES 344 ‘Kau’ HAES 660 ‘Keaau’ IAC 4–12 B, and IAC Campinas B were harvested and immediately oven-dried for 4 days at 30 °C, 2 days at 40 °C, and 1 day at 60 °C to achieve 1.5% kernel moisture content. At each drying step nuts were withdrawn and their moisture content, peroxide value (PV), and acidity index (AI) determined. The best partial least square model for PV prediction was obtained using the Savitzky-Golay (SG) second derivative resulting in a standard error of prediction (SEP) of 0.55 meq·kg −1 and a coefficient of determination (R 2 C ) of 0.57. The best AI prediction-model result was obtained using the SG second derivative (SEP = 0.14%, R 2 C = 0.29). Based on the maximum quality limits of 3 meq·kg −1 for PV and 0.5% for AI, the SEP values represented 18% and 28%, respectively. Therefore, the prediction method can be considered useful since the errors are lower than the quality limits. Thus, NIRS can be used to assess the oxidative stability of intact macadamia kernels.
publishDate 2019
dc.date.none.fl_str_mv 2019-10-06T16:12:41Z
2019-10-06T16:12:41Z
2019-04-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1016/j.lwt.2018.12.056
LWT, v. 103, p. 101-107.
0023-6438
http://hdl.handle.net/11449/188580
10.1016/j.lwt.2018.12.056
2-s2.0-85059581501
url http://dx.doi.org/10.1016/j.lwt.2018.12.056
http://hdl.handle.net/11449/188580
identifier_str_mv LWT, v. 103, p. 101-107.
0023-6438
10.1016/j.lwt.2018.12.056
2-s2.0-85059581501
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv LWT
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 101-107
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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