An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1002/app.49750 http://hdl.handle.net/11449/202008 |
Resumo: | In this paper, we report the controlled fabrication of layer-by-layer (LbL) films deposited on gold substrates with three different supramolecular architectures using polypyrrole (Ppy) and magnetite nanoparticles (Fe3O4-np), besides conventional poly(allylamine hydrochloride) (PAH) e poly(vinyl sulfonic acid) (PVS) polyelectrolytes, demonstrating the synergistic effect between Ppy and Fe3O4-np such as a result of their interaction. Modified gold electrodes were analyzed by contact angle (wettability), surface plasmon resonance (SPR), raman spectroscopy, cyclic voltammetry, and electrochemical impedance spectroscopy. The (Fe3O4-np/Ppy)3 architecture was also evaluated by scanning electron microscopy. The modified gold electrodes present more homogeneous covering, higher electron transfer and a decrease of resistance with the incorporation of the nanostructured materials such as Ppy and Fe3O4-np forming (Fe3O4-np/Ppy)3 LbL film. The results carried out in this study suggest that the (Fe3O4-np/Ppy)3 LbL film can be applied as a possible electrochemical or optical non-enzymatic sensor for analytical detection. |
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Repositório Institucional da UNESP |
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An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer filmsLayer-by-Layermicroscopyoptical propertiesself-assemblyIn this paper, we report the controlled fabrication of layer-by-layer (LbL) films deposited on gold substrates with three different supramolecular architectures using polypyrrole (Ppy) and magnetite nanoparticles (Fe3O4-np), besides conventional poly(allylamine hydrochloride) (PAH) e poly(vinyl sulfonic acid) (PVS) polyelectrolytes, demonstrating the synergistic effect between Ppy and Fe3O4-np such as a result of their interaction. Modified gold electrodes were analyzed by contact angle (wettability), surface plasmon resonance (SPR), raman spectroscopy, cyclic voltammetry, and electrochemical impedance spectroscopy. The (Fe3O4-np/Ppy)3 architecture was also evaluated by scanning electron microscopy. The modified gold electrodes present more homogeneous covering, higher electron transfer and a decrease of resistance with the incorporation of the nanostructured materials such as Ppy and Fe3O4-np forming (Fe3O4-np/Ppy)3 LbL film. The results carried out in this study suggest that the (Fe3O4-np/Ppy)3 LbL film can be applied as a possible electrochemical or optical non-enzymatic sensor for analytical detection.Center of Science and Technology for Sustainability (CCTS) Federal University of São Carlos (UFSCar)Department of Analytical Chemistry Institute of Chemistry State University of Campinas (UNICAMP)Sao Paulo State University Julio de Mesquita Filho (UNESP)Sao Paulo State University Julio de Mesquita Filho (UNESP)Universidade Federal de São Carlos (UFSCar)Universidade Estadual de Campinas (UNICAMP)Universidade Estadual Paulista (Unesp)de Lima, Lucas F.Maciel, Cristiane C. [UNESP]Ferreira, André L.Rubira, Rafael J. G. [UNESP]Constantino, Carlos J. L. [UNESP]Ferreira, Marystela2020-12-12T02:47:27Z2020-12-12T02:47:27Z2020-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1002/app.49750Journal of Applied Polymer Science.1097-46280021-8995http://hdl.handle.net/11449/20200810.1002/app.497502-s2.0-85089312608Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Applied Polymer Scienceinfo:eu-repo/semantics/openAccess2021-10-23T08:38:59Zoai:repositorio.unesp.br:11449/202008Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-23T08:38:59Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films |
title |
An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films |
spellingShingle |
An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films de Lima, Lucas F. Layer-by-Layer microscopy optical properties self-assembly |
title_short |
An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films |
title_full |
An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films |
title_fullStr |
An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films |
title_full_unstemmed |
An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films |
title_sort |
An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films |
author |
de Lima, Lucas F. |
author_facet |
de Lima, Lucas F. Maciel, Cristiane C. [UNESP] Ferreira, André L. Rubira, Rafael J. G. [UNESP] Constantino, Carlos J. L. [UNESP] Ferreira, Marystela |
author_role |
author |
author2 |
Maciel, Cristiane C. [UNESP] Ferreira, André L. Rubira, Rafael J. G. [UNESP] Constantino, Carlos J. L. [UNESP] Ferreira, Marystela |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Federal de São Carlos (UFSCar) Universidade Estadual de Campinas (UNICAMP) Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
de Lima, Lucas F. Maciel, Cristiane C. [UNESP] Ferreira, André L. Rubira, Rafael J. G. [UNESP] Constantino, Carlos J. L. [UNESP] Ferreira, Marystela |
dc.subject.por.fl_str_mv |
Layer-by-Layer microscopy optical properties self-assembly |
topic |
Layer-by-Layer microscopy optical properties self-assembly |
description |
In this paper, we report the controlled fabrication of layer-by-layer (LbL) films deposited on gold substrates with three different supramolecular architectures using polypyrrole (Ppy) and magnetite nanoparticles (Fe3O4-np), besides conventional poly(allylamine hydrochloride) (PAH) e poly(vinyl sulfonic acid) (PVS) polyelectrolytes, demonstrating the synergistic effect between Ppy and Fe3O4-np such as a result of their interaction. Modified gold electrodes were analyzed by contact angle (wettability), surface plasmon resonance (SPR), raman spectroscopy, cyclic voltammetry, and electrochemical impedance spectroscopy. The (Fe3O4-np/Ppy)3 architecture was also evaluated by scanning electron microscopy. The modified gold electrodes present more homogeneous covering, higher electron transfer and a decrease of resistance with the incorporation of the nanostructured materials such as Ppy and Fe3O4-np forming (Fe3O4-np/Ppy)3 LbL film. The results carried out in this study suggest that the (Fe3O4-np/Ppy)3 LbL film can be applied as a possible electrochemical or optical non-enzymatic sensor for analytical detection. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-12-12T02:47:27Z 2020-12-12T02:47:27Z 2020-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1002/app.49750 Journal of Applied Polymer Science. 1097-4628 0021-8995 http://hdl.handle.net/11449/202008 10.1002/app.49750 2-s2.0-85089312608 |
url |
http://dx.doi.org/10.1002/app.49750 http://hdl.handle.net/11449/202008 |
identifier_str_mv |
Journal of Applied Polymer Science. 1097-4628 0021-8995 10.1002/app.49750 2-s2.0-85089312608 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Applied Polymer Science |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1799964587317002240 |