Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.

Detalhes bibliográficos
Autor(a) principal: Moraes, F. V. de
Data de Publicação: 2003
Outros Autores: Alcantara, I. L. de, Roldan, P. D., Castro, G. R. de, Margionte, MAL, Padilha, P. D.
Tipo de documento: Artigo
Idioma: por
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://hdl.handle.net/11449/195745
Resumo: This paper described the preparation of 2-aminothiazole modified silica gel (SiAT) and the results of a study of the sorption and preconcentration (in batch and in flow using a column technique) of Cd(II) in aqueous medium. The sorption capacities for metal ion was 1.12 mmol g-1. The results obtained in the flow experiments, showed a recovery of 98% of Cd(II) adsorbed in a column packed with 1 g of SiAT, using 5.0 mL of 2.0 mol L-1 hydrochloric acid as eluent. An enrichment factor of 25 (150 mL solution containing 25 dug L-1 of Cd(II), 5.0 mL concentrated) was obtained by this preconcentration procedure. The sorption-desorption of Cd(II) made possible the development of a preconcentration method and quantification:by Flame AAS of Cd(II) at trace level in aqueous samples.
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spelling Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.preconcentration2-aminothiazole modified silica gelflame atomic absorption spectrometryThis paper described the preparation of 2-aminothiazole modified silica gel (SiAT) and the results of a study of the sorption and preconcentration (in batch and in flow using a column technique) of Cd(II) in aqueous medium. The sorption capacities for metal ion was 1.12 mmol g-1. The results obtained in the flow experiments, showed a recovery of 98% of Cd(II) adsorbed in a column packed with 1 g of SiAT, using 5.0 mL of 2.0 mol L-1 hydrochloric acid as eluent. An enrichment factor of 25 (150 mL solution containing 25 dug L-1 of Cd(II), 5.0 mL concentrated) was obtained by this preconcentration procedure. The sorption-desorption of Cd(II) made possible the development of a preconcentration method and quantification:by Flame AAS of Cd(II) at trace level in aqueous samples.Univ Estadual Paulista, Inst Biociencias, Dept Quim & Bioquim, BR-18618000 Botucatu, SP, BrazilUNESP, Inst Quim, Dept Quim Analit, BR-14800900 Araraquara, SP, BrazilUniv Estadual Paulista, Inst Biociencias, Dept Quim & Bioquim, BR-18618000 Botucatu, SP, BrazilUNESP, Inst Quim, Dept Quim Analit, BR-14800900 Araraquara, SP, BrazilEditora UnespUniversidade Estadual Paulista (Unesp)Moraes, F. V. deAlcantara, I. L. deRoldan, P. D.Castro, G. R. deMargionte, MALPadilha, P. D.2020-12-10T18:02:05Z2020-12-10T18:02:05Z2003-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article9-17Ecletica Quimica. Sao Paulo: Editora Unesp, v. 28, n. 1, p. 9-17, 2003.0100-4670http://hdl.handle.net/11449/195745WOS:000186315900001Web of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporEcletica Quimicainfo:eu-repo/semantics/openAccess2021-10-23T11:39:19Zoai:repositorio.unesp.br:11449/195745Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-23T11:39:19Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.
title Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.
spellingShingle Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.
Moraes, F. V. de
preconcentration
2-aminothiazole modified silica gel
flame atomic absorption spectrometry
title_short Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.
title_full Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.
title_fullStr Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.
title_full_unstemmed Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.
title_sort Determination of Cd(II) by FAAS in aqueous medium after preconcentration in line on a SiAT.
author Moraes, F. V. de
author_facet Moraes, F. V. de
Alcantara, I. L. de
Roldan, P. D.
Castro, G. R. de
Margionte, MAL
Padilha, P. D.
author_role author
author2 Alcantara, I. L. de
Roldan, P. D.
Castro, G. R. de
Margionte, MAL
Padilha, P. D.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Moraes, F. V. de
Alcantara, I. L. de
Roldan, P. D.
Castro, G. R. de
Margionte, MAL
Padilha, P. D.
dc.subject.por.fl_str_mv preconcentration
2-aminothiazole modified silica gel
flame atomic absorption spectrometry
topic preconcentration
2-aminothiazole modified silica gel
flame atomic absorption spectrometry
description This paper described the preparation of 2-aminothiazole modified silica gel (SiAT) and the results of a study of the sorption and preconcentration (in batch and in flow using a column technique) of Cd(II) in aqueous medium. The sorption capacities for metal ion was 1.12 mmol g-1. The results obtained in the flow experiments, showed a recovery of 98% of Cd(II) adsorbed in a column packed with 1 g of SiAT, using 5.0 mL of 2.0 mol L-1 hydrochloric acid as eluent. An enrichment factor of 25 (150 mL solution containing 25 dug L-1 of Cd(II), 5.0 mL concentrated) was obtained by this preconcentration procedure. The sorption-desorption of Cd(II) made possible the development of a preconcentration method and quantification:by Flame AAS of Cd(II) at trace level in aqueous samples.
publishDate 2003
dc.date.none.fl_str_mv 2003-01-01
2020-12-10T18:02:05Z
2020-12-10T18:02:05Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv Ecletica Quimica. Sao Paulo: Editora Unesp, v. 28, n. 1, p. 9-17, 2003.
0100-4670
http://hdl.handle.net/11449/195745
WOS:000186315900001
identifier_str_mv Ecletica Quimica. Sao Paulo: Editora Unesp, v. 28, n. 1, p. 9-17, 2003.
0100-4670
WOS:000186315900001
url http://hdl.handle.net/11449/195745
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv Ecletica Quimica
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 9-17
dc.publisher.none.fl_str_mv Editora Unesp
publisher.none.fl_str_mv Editora Unesp
dc.source.none.fl_str_mv Web of Science
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1799965047271718912

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