Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide

Detalhes bibliográficos
Autor(a) principal: Oliveira, Adriano Bof De
Data de Publicação: 2014
Outros Autores: Beck, Johannes, Daniels, Jörg, Farias, Renan Lira De, Godoy Netto, Adelino Vieira De [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1107/S1600536814015980
http://hdl.handle.net/11449/220213
Resumo: The title compound, C11H21N3S, consists of a menthone moiety attached to an extended thiosemicarbazone group with the N - N - C - N torsion angle being 11.92 (16)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, molecules are linked via pairs of N - H⋯S hydrogen bonds, forming chains along the a axis. The absolute structure could be assigned with reference to the starting material, i.e. enantiopure (-)-menthone [Flack parameter = 0.05 (5)].
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spelling Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamidecrystal structurehydrogen-bonding polymerthiocarbazoneThe title compound, C11H21N3S, consists of a menthone moiety attached to an extended thiosemicarbazone group with the N - N - C - N torsion angle being 11.92 (16)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, molecules are linked via pairs of N - H⋯S hydrogen bonds, forming chains along the a axis. The absolute structure could be assigned with reference to the starting material, i.e. enantiopure (-)-menthone [Flack parameter = 0.05 (5)].Departamento de Química Universidade Federal de Sergipe, Av. Marechal Rondon s/nInstitut für Anorganische Chemie Universität Bonn, Gerhard-Domagk-Strasse 1Instituto de Química Universidade Estadual Paulista, Rua Francisco Degni s/nInstituto de Química Universidade Estadual Paulista, Rua Francisco Degni s/nUniversidade Federal de Sergipe (UFS)Universität BonnUniversidade Estadual Paulista (UNESP)Oliveira, Adriano Bof DeBeck, JohannesDaniels, JörgFarias, Renan Lira DeGodoy Netto, Adelino Vieira De [UNESP]2022-04-28T19:00:19Z2022-04-28T19:00:19Z2014-08-06info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleo903-o904http://dx.doi.org/10.1107/S1600536814015980Acta Crystallographica Section E: Structure Reports Online, v. 70, n. 9, p. o903-o904, 2014.1600-5368http://hdl.handle.net/11449/22021310.1107/S16005368140159802-s2.0-84907017809Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengActa Crystallographica Section E: Structure Reports Onlineinfo:eu-repo/semantics/openAccess2022-04-28T19:00:19Zoai:repositorio.unesp.br:11449/220213Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462022-04-28T19:00:19Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide
title Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide
spellingShingle Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide
Oliveira, Adriano Bof De
crystal structure
hydrogen-bonding polymer
thiocarbazone
title_short Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide
title_full Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide
title_fullStr Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide
title_full_unstemmed Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide
title_sort Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide
author Oliveira, Adriano Bof De
author_facet Oliveira, Adriano Bof De
Beck, Johannes
Daniels, Jörg
Farias, Renan Lira De
Godoy Netto, Adelino Vieira De [UNESP]
author_role author
author2 Beck, Johannes
Daniels, Jörg
Farias, Renan Lira De
Godoy Netto, Adelino Vieira De [UNESP]
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade Federal de Sergipe (UFS)
Universität Bonn
Universidade Estadual Paulista (UNESP)
dc.contributor.author.fl_str_mv Oliveira, Adriano Bof De
Beck, Johannes
Daniels, Jörg
Farias, Renan Lira De
Godoy Netto, Adelino Vieira De [UNESP]
dc.subject.por.fl_str_mv crystal structure
hydrogen-bonding polymer
thiocarbazone
topic crystal structure
hydrogen-bonding polymer
thiocarbazone
description The title compound, C11H21N3S, consists of a menthone moiety attached to an extended thiosemicarbazone group with the N - N - C - N torsion angle being 11.92 (16)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, molecules are linked via pairs of N - H⋯S hydrogen bonds, forming chains along the a axis. The absolute structure could be assigned with reference to the starting material, i.e. enantiopure (-)-menthone [Flack parameter = 0.05 (5)].
publishDate 2014
dc.date.none.fl_str_mv 2014-08-06
2022-04-28T19:00:19Z
2022-04-28T19:00:19Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1107/S1600536814015980
Acta Crystallographica Section E: Structure Reports Online, v. 70, n. 9, p. o903-o904, 2014.
1600-5368
http://hdl.handle.net/11449/220213
10.1107/S1600536814015980
2-s2.0-84907017809
url http://dx.doi.org/10.1107/S1600536814015980
http://hdl.handle.net/11449/220213
identifier_str_mv Acta Crystallographica Section E: Structure Reports Online, v. 70, n. 9, p. o903-o904, 2014.
1600-5368
10.1107/S1600536814015980
2-s2.0-84907017809
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Acta Crystallographica Section E: Structure Reports Online
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv o903-o904
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1799965120209616896

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