Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilization
Autor(a) principal: | |
---|---|
Data de Publicação: | 2021 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1021/acs.jafc.0c07333 http://hdl.handle.net/11449/205993 |
Resumo: | The development of smart and eco-friendly fertilizers is pivotal to guarantee food security sustainably. Phosphate rock and struvite are promising alternatives for P fertilization; nevertheless, the solubility of these sources is a challenge for consistent use efficiency. Here, we propose using a polysulfide obtained via inverse vulcanization as a novel controlled-release fertilizer matrix in a system containing either Bayóvar rock (Bay) or struvite (Str). The polysulfide provides S for plants after being biologically oxidized to sulfate in soil, generating local acidity for P solubilization. After 15 days of soil incubation, the composites with 75 wt % Str and 75 wt % Bay achieved, respectively, 3 and 2 times the S oxidation from the elemental sulfur reference. Results indicated that P content stimulates the soil microorganisms' activity for S oxidation. The matrix had a physical role in improving Bay dissolution and regulating the rapid release from Str. Moreover, the available P in soil was 25-30 mg/dm3 for Bay composites, while for pure Bay, it was 9 mg/dm3. |
id |
UNSP_d3d278bd51af520a19a9a04a5752a9e8 |
---|---|
oai_identifier_str |
oai:repositorio.unesp.br:11449/205993 |
network_acronym_str |
UNSP |
network_name_str |
Repositório Institucional da UNESP |
repository_id_str |
2946 |
spelling |
Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilizationfertilizerinverse vulcanizationphosphatepolysulfidestruvitesulfurThe development of smart and eco-friendly fertilizers is pivotal to guarantee food security sustainably. Phosphate rock and struvite are promising alternatives for P fertilization; nevertheless, the solubility of these sources is a challenge for consistent use efficiency. Here, we propose using a polysulfide obtained via inverse vulcanization as a novel controlled-release fertilizer matrix in a system containing either Bayóvar rock (Bay) or struvite (Str). The polysulfide provides S for plants after being biologically oxidized to sulfate in soil, generating local acidity for P solubilization. After 15 days of soil incubation, the composites with 75 wt % Str and 75 wt % Bay achieved, respectively, 3 and 2 times the S oxidation from the elemental sulfur reference. Results indicated that P content stimulates the soil microorganisms' activity for S oxidation. The matrix had a physical role in improving Bay dissolution and regulating the rapid release from Str. Moreover, the available P in soil was 25-30 mg/dm3 for Bay composites, while for pure Bay, it was 9 mg/dm3.Department of Chemistry Federal University of São Carlos, Washington Luiz Highway, km 235Embrapa Instrumentation, XV de Novembro Street, 1452UNESP Botucatu Av. Universitária, 3780 - Altos do ParaísoAgricultural Research and Rural Extension Company of Santa Catarina, 6800 Highway, Antônio HeilUNESP Botucatu Av. Universitária, 3780 - Altos do ParaísoUniversidade Federal de São Carlos (UFSCar)Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA)Universidade Estadual Paulista (Unesp)Agricultural Research and Rural Extension Company of Santa CatarinaDo Valle, Stella FortunaGiroto, Amanda SoaresReis, Heitor Pontes Gestal [UNESP]Guimarães, Gelton G. F.Ribeiro, Caue2021-06-25T10:24:46Z2021-06-25T10:24:46Z2021-03-03info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article2392-2402http://dx.doi.org/10.1021/acs.jafc.0c07333Journal of Agricultural and Food Chemistry, v. 69, n. 8, p. 2392-2402, 2021.1520-51180021-8561http://hdl.handle.net/11449/20599310.1021/acs.jafc.0c073332-s2.0-85101978866Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Agricultural and Food Chemistryinfo:eu-repo/semantics/openAccess2021-10-22T20:28:44Zoai:repositorio.unesp.br:11449/205993Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-22T20:28:44Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilization |
title |
Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilization |
spellingShingle |
Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilization Do Valle, Stella Fortuna fertilizer inverse vulcanization phosphate polysulfide struvite sulfur |
title_short |
Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilization |
title_full |
Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilization |
title_fullStr |
Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilization |
title_full_unstemmed |
Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilization |
title_sort |
Synergy of Phosphate-Controlled Release and Sulfur Oxidation in Novel Polysulfide Composites for Sustainable Fertilization |
author |
Do Valle, Stella Fortuna |
author_facet |
Do Valle, Stella Fortuna Giroto, Amanda Soares Reis, Heitor Pontes Gestal [UNESP] Guimarães, Gelton G. F. Ribeiro, Caue |
author_role |
author |
author2 |
Giroto, Amanda Soares Reis, Heitor Pontes Gestal [UNESP] Guimarães, Gelton G. F. Ribeiro, Caue |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Universidade Federal de São Carlos (UFSCar) Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA) Universidade Estadual Paulista (Unesp) Agricultural Research and Rural Extension Company of Santa Catarina |
dc.contributor.author.fl_str_mv |
Do Valle, Stella Fortuna Giroto, Amanda Soares Reis, Heitor Pontes Gestal [UNESP] Guimarães, Gelton G. F. Ribeiro, Caue |
dc.subject.por.fl_str_mv |
fertilizer inverse vulcanization phosphate polysulfide struvite sulfur |
topic |
fertilizer inverse vulcanization phosphate polysulfide struvite sulfur |
description |
The development of smart and eco-friendly fertilizers is pivotal to guarantee food security sustainably. Phosphate rock and struvite are promising alternatives for P fertilization; nevertheless, the solubility of these sources is a challenge for consistent use efficiency. Here, we propose using a polysulfide obtained via inverse vulcanization as a novel controlled-release fertilizer matrix in a system containing either Bayóvar rock (Bay) or struvite (Str). The polysulfide provides S for plants after being biologically oxidized to sulfate in soil, generating local acidity for P solubilization. After 15 days of soil incubation, the composites with 75 wt % Str and 75 wt % Bay achieved, respectively, 3 and 2 times the S oxidation from the elemental sulfur reference. Results indicated that P content stimulates the soil microorganisms' activity for S oxidation. The matrix had a physical role in improving Bay dissolution and regulating the rapid release from Str. Moreover, the available P in soil was 25-30 mg/dm3 for Bay composites, while for pure Bay, it was 9 mg/dm3. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-06-25T10:24:46Z 2021-06-25T10:24:46Z 2021-03-03 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1021/acs.jafc.0c07333 Journal of Agricultural and Food Chemistry, v. 69, n. 8, p. 2392-2402, 2021. 1520-5118 0021-8561 http://hdl.handle.net/11449/205993 10.1021/acs.jafc.0c07333 2-s2.0-85101978866 |
url |
http://dx.doi.org/10.1021/acs.jafc.0c07333 http://hdl.handle.net/11449/205993 |
identifier_str_mv |
Journal of Agricultural and Food Chemistry, v. 69, n. 8, p. 2392-2402, 2021. 1520-5118 0021-8561 10.1021/acs.jafc.0c07333 2-s2.0-85101978866 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Agricultural and Food Chemistry |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
2392-2402 |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1799964798763401216 |