Modified screen-printed electrode for the FIA-amperometric determination of 2-nitro-p-phenylenediamine

• Autor(a) principal: Huayhuas-Chipana, Bryan C. [UNESP]
• Data de Publicação: 2017
• Outros Autores: Foguel, Marcos Vinicius [UNESP], Gonçalves, Luís Moreira, Sotomayor, Maria D.P.T. [UNESP]
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da UNESP
• Texto Completo: http://dx.doi.org/10.1016/j.microc.2016.11.020; http://hdl.handle.net/11449/173883
• topic: 2-Nitro-p-phenylenediamine; Electroanalysis; Electrochemical sensor; Electrochemistry; Flow analysis; Microfluidics

This work presents the development of a modified sensor coupled to a flow injection analysis (FIA) system for the determination of 2-nitro-p-phenylenediamine, an important compound in hair dyes. To achieve this, a commercial screen-printed gold electrode (SPAuE) previously electrochemically treated to become nanostructured, was covered with a self-assembled monolayer (SAM) of 3-mercapto-1-propanesulfonate (MPS) and, subsequently, was covered by multilayers of chitosan, sodium dodecyl sulphonate (SDS) and nickel(II) phthalocyanine-tetrasulfonic acid (NiPcTs) in a layer-by-layer technique to improve the sensor's sensibility. The analytical response of the proposed methodology was evaluated in batch by square wave voltammetry (SWV) and by amperometry coupled to a FIA system, with limits of detection of 1.2 and 1.6 μmol L− 1, respectively.