Neoaustin: a meroterpene produced by Penicillium sp.
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1107/S1600536809006618 http://hdl.handle.net/11449/8514 |
Resumo: | The title meroterpene neoaustin {systematic name: (1'S,2'R,3S,7'R,9'S,11'S,12'R)-11'-hydroxy- 2,2,2',9',12'-pentamethyl-6',15'-dimethylene-2,6-dihydro-13'-oxaspiro[pyran-3,5'-tetracyclo[7.5.1.0(1,11).0(2,7)]pentadecane]-6,10',14'-trione}, C(25)H(30)O(6), comprises five rings, three six-membered and two five-membered. The absolute configuration was established based on [alpha D] = + 166.91 degrees (c 1.21, CH(2)Cl(2)). In the crystal, the molecules are connected into a supramolecular helical chain via O-H center dot center dot center dot O hydrogen bonds reinforced by C-H center dot center dot center dot O contacts. |
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Repositório Institucional da UNESP |
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spelling |
Neoaustin: a meroterpene produced by Penicillium sp.The title meroterpene neoaustin {systematic name: (1'S,2'R,3S,7'R,9'S,11'S,12'R)-11'-hydroxy- 2,2,2',9',12'-pentamethyl-6',15'-dimethylene-2,6-dihydro-13'-oxaspiro[pyran-3,5'-tetracyclo[7.5.1.0(1,11).0(2,7)]pentadecane]-6,10',14'-trione}, C(25)H(30)O(6), comprises five rings, three six-membered and two five-membered. The absolute configuration was established based on [alpha D] = + 166.91 degrees (c 1.21, CH(2)Cl(2)). In the crystal, the molecules are connected into a supramolecular helical chain via O-H center dot center dot center dot O hydrogen bonds reinforced by C-H center dot center dot center dot O contacts.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, BrazilUNESP, Dept Phys, BR-17033360 Bauru, SP, BrazilUNESP, Dept Phys, BR-17033360 Bauru, SP, BrazilFAPESP: 08/02531-5Wiley-Blackwell Publishing, IncUniversidade Federal de São Carlos (UFSCar)Universidade Estadual Paulista (Unesp)Zukerman-Schpector, JulioMaganhi, Stella H.Fill, Taicia PachecoRodrigues-Fo, EdsonCaracelli, Ignez [UNESP]2014-05-20T13:26:24Z2014-05-20T13:26:24Z2009-03-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleO612-U2621application/pdfhttp://dx.doi.org/10.1107/S1600536809006618Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell Publishing, Inc, v. 65, p. O612-U2621, 2009.1600-5368http://hdl.handle.net/11449/851410.1107/S1600536809006618WOS:000264796100234WOS000264796100234.pdfWeb of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengActa Crystallographica Section E: Structure Reports Online0,138info:eu-repo/semantics/openAccess2024-04-25T17:40:31Zoai:repositorio.unesp.br:11449/8514Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-04-25T17:40:31Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Neoaustin: a meroterpene produced by Penicillium sp. |
title |
Neoaustin: a meroterpene produced by Penicillium sp. |
spellingShingle |
Neoaustin: a meroterpene produced by Penicillium sp. Zukerman-Schpector, Julio |
title_short |
Neoaustin: a meroterpene produced by Penicillium sp. |
title_full |
Neoaustin: a meroterpene produced by Penicillium sp. |
title_fullStr |
Neoaustin: a meroterpene produced by Penicillium sp. |
title_full_unstemmed |
Neoaustin: a meroterpene produced by Penicillium sp. |
title_sort |
Neoaustin: a meroterpene produced by Penicillium sp. |
author |
Zukerman-Schpector, Julio |
author_facet |
Zukerman-Schpector, Julio Maganhi, Stella H. Fill, Taicia Pacheco Rodrigues-Fo, Edson Caracelli, Ignez [UNESP] |
author_role |
author |
author2 |
Maganhi, Stella H. Fill, Taicia Pacheco Rodrigues-Fo, Edson Caracelli, Ignez [UNESP] |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Universidade Federal de São Carlos (UFSCar) Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Zukerman-Schpector, Julio Maganhi, Stella H. Fill, Taicia Pacheco Rodrigues-Fo, Edson Caracelli, Ignez [UNESP] |
description |
The title meroterpene neoaustin {systematic name: (1'S,2'R,3S,7'R,9'S,11'S,12'R)-11'-hydroxy- 2,2,2',9',12'-pentamethyl-6',15'-dimethylene-2,6-dihydro-13'-oxaspiro[pyran-3,5'-tetracyclo[7.5.1.0(1,11).0(2,7)]pentadecane]-6,10',14'-trione}, C(25)H(30)O(6), comprises five rings, three six-membered and two five-membered. The absolute configuration was established based on [alpha D] = + 166.91 degrees (c 1.21, CH(2)Cl(2)). In the crystal, the molecules are connected into a supramolecular helical chain via O-H center dot center dot center dot O hydrogen bonds reinforced by C-H center dot center dot center dot O contacts. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-03-01 2014-05-20T13:26:24Z 2014-05-20T13:26:24Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1107/S1600536809006618 Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell Publishing, Inc, v. 65, p. O612-U2621, 2009. 1600-5368 http://hdl.handle.net/11449/8514 10.1107/S1600536809006618 WOS:000264796100234 WOS000264796100234.pdf |
url |
http://dx.doi.org/10.1107/S1600536809006618 http://hdl.handle.net/11449/8514 |
identifier_str_mv |
Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell Publishing, Inc, v. 65, p. O612-U2621, 2009. 1600-5368 10.1107/S1600536809006618 WOS:000264796100234 WOS000264796100234.pdf |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Acta Crystallographica Section E: Structure Reports Online 0,138 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
O612-U2621 application/pdf |
dc.publisher.none.fl_str_mv |
Wiley-Blackwell Publishing, Inc |
publisher.none.fl_str_mv |
Wiley-Blackwell Publishing, Inc |
dc.source.none.fl_str_mv |
Web of Science reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1799965726709121024 |