Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes

Detalhes bibliográficos
Autor(a) principal: Lima, Rosemar de
Data de Publicação: 2021
Outros Autores: Bento, Heitor B. S. [UNESP], Reis, Cristiano E. R., Vilas Boas, Renata N., Freitas, Larissa de, Carvalho, Ana K. F., Castro, Heizir F. de
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1007/s10562-021-03663-z
http://hdl.handle.net/11449/209396
Resumo: Six lipases were immobilized on a styrene-divinylbenzene support and evaluated on the batch esterification reaction of stearic acid with fusel oil. After a screening design, the two most appropriate lipases were assayed on a packed-bed system, achieving high conversion rates (90-93%) and productivities of isoamyl stearate up to 3144 mmol g(-1) min(-1), which can be used as a substitute to fossil-derived lubricants. Graphic
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spelling Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous ProcessesEnzymatic catalysisHeterogeneous catalysisImmobilizationSix lipases were immobilized on a styrene-divinylbenzene support and evaluated on the batch esterification reaction of stearic acid with fusel oil. After a screening design, the two most appropriate lipases were assayed on a packed-bed system, achieving high conversion rates (90-93%) and productivities of isoamyl stearate up to 3144 mmol g(-1) min(-1), which can be used as a substitute to fossil-derived lubricants. GraphicFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Univ Sao Paulo, Engn Sch Lorena, Lorena, SP, BrazilSao Paulo State Univ, Sch Pharmaceut Sci, Araraquara, SP, BrazilEARTH Univ, Guacimo, Limon, Costa RicaUniv Fed Rural Rio de Janeiro, Seropedica, RJ, BrazilUniv Fed Alfenas, Inst Chem, Alfenas, MG, BrazilSao Paulo State Univ, Sch Pharmaceut Sci, Araraquara, SP, BrazilFAPESP: 2016/10636-8FAPESP: 2020/15513-7CAPES: 001SpringerUniversidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)EARTH UnivUniv Fed Rural Rio de JaneiroUniv Fed AlfenasLima, Rosemar deBento, Heitor B. S. [UNESP]Reis, Cristiano E. R.Vilas Boas, Renata N.Freitas, Larissa deCarvalho, Ana K. F.Castro, Heizir F. de2021-06-25T12:16:50Z2021-06-25T12:16:50Z2021-05-19info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article12http://dx.doi.org/10.1007/s10562-021-03663-zCatalysis Letters. New York: Springer, 12 p., 2021.1011-372Xhttp://hdl.handle.net/11449/20939610.1007/s10562-021-03663-zWOS:000652091200002Web of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengCatalysis Lettersinfo:eu-repo/semantics/openAccess2021-10-23T19:28:10Zoai:repositorio.unesp.br:11449/209396Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-23T19:28:10Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes
title Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes
spellingShingle Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes
Lima, Rosemar de
Enzymatic catalysis
Heterogeneous catalysis
Immobilization
title_short Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes
title_full Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes
title_fullStr Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes
title_full_unstemmed Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes
title_sort Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes
author Lima, Rosemar de
author_facet Lima, Rosemar de
Bento, Heitor B. S. [UNESP]
Reis, Cristiano E. R.
Vilas Boas, Renata N.
Freitas, Larissa de
Carvalho, Ana K. F.
Castro, Heizir F. de
author_role author
author2 Bento, Heitor B. S. [UNESP]
Reis, Cristiano E. R.
Vilas Boas, Renata N.
Freitas, Larissa de
Carvalho, Ana K. F.
Castro, Heizir F. de
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade de São Paulo (USP)
Universidade Estadual Paulista (Unesp)
EARTH Univ
Univ Fed Rural Rio de Janeiro
Univ Fed Alfenas
dc.contributor.author.fl_str_mv Lima, Rosemar de
Bento, Heitor B. S. [UNESP]
Reis, Cristiano E. R.
Vilas Boas, Renata N.
Freitas, Larissa de
Carvalho, Ana K. F.
Castro, Heizir F. de
dc.subject.por.fl_str_mv Enzymatic catalysis
Heterogeneous catalysis
Immobilization
topic Enzymatic catalysis
Heterogeneous catalysis
Immobilization
description Six lipases were immobilized on a styrene-divinylbenzene support and evaluated on the batch esterification reaction of stearic acid with fusel oil. After a screening design, the two most appropriate lipases were assayed on a packed-bed system, achieving high conversion rates (90-93%) and productivities of isoamyl stearate up to 3144 mmol g(-1) min(-1), which can be used as a substitute to fossil-derived lubricants. Graphic
publishDate 2021
dc.date.none.fl_str_mv 2021-06-25T12:16:50Z
2021-06-25T12:16:50Z
2021-05-19
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1007/s10562-021-03663-z
Catalysis Letters. New York: Springer, 12 p., 2021.
1011-372X
http://hdl.handle.net/11449/209396
10.1007/s10562-021-03663-z
WOS:000652091200002
url http://dx.doi.org/10.1007/s10562-021-03663-z
http://hdl.handle.net/11449/209396
identifier_str_mv Catalysis Letters. New York: Springer, 12 p., 2021.
1011-372X
10.1007/s10562-021-03663-z
WOS:000652091200002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Catalysis Letters
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 12
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv Web of Science
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1799965627936407552

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