Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of time

Detalhes bibliográficos
Autor(a) principal: Carvalho,E. de
Data de Publicação: 2012
Outros Autores: Irvine,J. T. S.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Cerâmica (São Paulo. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132012000100002
Resumo: The conductivity behaviour of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 have been investigated as function of time using impedance spectroscopy. All samples were prepared by sol-gel and combustion process, sintered at 1500 °C for 12 h and the densities obtained were between 92 and 97%. The electrical measurements were performed at 600 °C. The conductivity values were fairly stable during the first 1800 h of the experiment but after this time the conductivity decreases. For some compositions of the system a semi-circle is detected through time, with capacitance values of an order of magnitude lower, 10-8 F/cm. This semi-circle becomes well defined with time. After the experiment, SEM pictures show that grain boundary is well defined and an increase of pore inside grains, in some cases the surface is damaged showing cracks and fissures indicating microstructure deterioration.
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spelling Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of timescandia-zirconiaac impedanceageingThe conductivity behaviour of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 have been investigated as function of time using impedance spectroscopy. All samples were prepared by sol-gel and combustion process, sintered at 1500 °C for 12 h and the densities obtained were between 92 and 97%. The electrical measurements were performed at 600 °C. The conductivity values were fairly stable during the first 1800 h of the experiment but after this time the conductivity decreases. For some compositions of the system a semi-circle is detected through time, with capacitance values of an order of magnitude lower, 10-8 F/cm. This semi-circle becomes well defined with time. After the experiment, SEM pictures show that grain boundary is well defined and an increase of pore inside grains, in some cases the surface is damaged showing cracks and fissures indicating microstructure deterioration.Associação Brasileira de Cerâmica2012-03-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132012000100002Cerâmica v.58 n.345 2012reponame:Cerâmica (São Paulo. Online)instname:Universidade de São Paulo (USP)instacron:USP10.1590/S0366-69132012000100002info:eu-repo/semantics/openAccessCarvalho,E. deIrvine,J. T. S.eng2012-03-28T00:00:00Zoai:scielo:S0366-69132012000100002Revistahttps://www.scielo.br/j/ce/PUBhttps://old.scielo.br/oai/scielo-oai.phpceram.abc@gmail.com||ceram.abc@gmail.com1678-45530366-6913opendoar:2012-03-28T00:00Cerâmica (São Paulo. Online) - Universidade de São Paulo (USP)false
dc.title.none.fl_str_mv Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of time
title Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of time
spellingShingle Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of time
Carvalho,E. de
scandia-zirconia
ac impedance
ageing
title_short Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of time
title_full Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of time
title_fullStr Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of time
title_full_unstemmed Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of time
title_sort Characterisation of conductivity of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 as function of time
author Carvalho,E. de
author_facet Carvalho,E. de
Irvine,J. T. S.
author_role author
author2 Irvine,J. T. S.
author2_role author
dc.contributor.author.fl_str_mv Carvalho,E. de
Irvine,J. T. S.
dc.subject.por.fl_str_mv scandia-zirconia
ac impedance
ageing
topic scandia-zirconia
ac impedance
ageing
description The conductivity behaviour of the (Ce xY0.2-x)Sc0.6 Zr3.2O8-δ (0 < x < 0.2) system and composition Ce0.04Y0.02Sc0.67Zr3.27O 7.66 have been investigated as function of time using impedance spectroscopy. All samples were prepared by sol-gel and combustion process, sintered at 1500 °C for 12 h and the densities obtained were between 92 and 97%. The electrical measurements were performed at 600 °C. The conductivity values were fairly stable during the first 1800 h of the experiment but after this time the conductivity decreases. For some compositions of the system a semi-circle is detected through time, with capacitance values of an order of magnitude lower, 10-8 F/cm. This semi-circle becomes well defined with time. After the experiment, SEM pictures show that grain boundary is well defined and an increase of pore inside grains, in some cases the surface is damaged showing cracks and fissures indicating microstructure deterioration.
publishDate 2012
dc.date.none.fl_str_mv 2012-03-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132012000100002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132012000100002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0366-69132012000100002
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Associação Brasileira de Cerâmica
publisher.none.fl_str_mv Associação Brasileira de Cerâmica
dc.source.none.fl_str_mv Cerâmica v.58 n.345 2012
reponame:Cerâmica (São Paulo. Online)
instname:Universidade de São Paulo (USP)
instacron:USP
instname_str Universidade de São Paulo (USP)
instacron_str USP
institution USP
reponame_str Cerâmica (São Paulo. Online)
collection Cerâmica (São Paulo. Online)
repository.name.fl_str_mv Cerâmica (São Paulo. Online) - Universidade de São Paulo (USP)
repository.mail.fl_str_mv ceram.abc@gmail.com||ceram.abc@gmail.com
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