An interdisciplinary approach to the electrochemistry at solid electrodes

Detalhes bibliográficos
Autor(a) principal: Arvia,A.J.
Data de Publicação: 1997
Outros Autores: Salvarezza,R.C.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531997000200002
Resumo: An interdisciplinary approach to the electrochemistry at solid electrodes is presented here taking into account new basic interpretations for either phase growth or phase disruption under conditions far from equilibrium. For this purpose imaging data derived from scanning tunneling microscopy (STM) and atomic force microscopy (AFM) at different scale lengths are extremely useful. This approach provides new insights into roughness development, roughness decay and reactivity at solid electrodes. The study of mobile interfaces by the sequential application of in situ STM data and an interpretation based on the dynamic scaling theory furnish a qualitative and a quantitative description of surface irregularities, and provide information about the interface evolution mechanism under steady and non-steady roughness regimes. Various examples of electrochemical interest are discussed on the basis of this interdisciplinary approach.
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spelling An interdisciplinary approach to the electrochemistry at solid electrodesirregular electrode surfacesnanoscopiesdynamic scalingAn interdisciplinary approach to the electrochemistry at solid electrodes is presented here taking into account new basic interpretations for either phase growth or phase disruption under conditions far from equilibrium. For this purpose imaging data derived from scanning tunneling microscopy (STM) and atomic force microscopy (AFM) at different scale lengths are extremely useful. This approach provides new insights into roughness development, roughness decay and reactivity at solid electrodes. The study of mobile interfaces by the sequential application of in situ STM data and an interpretation based on the dynamic scaling theory furnish a qualitative and a quantitative description of surface irregularities, and provide information about the interface evolution mechanism under steady and non-steady roughness regimes. Various examples of electrochemical interest are discussed on the basis of this interdisciplinary approach.Sociedade Brasileira de Química1997-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531997000200002Journal of the Brazilian Chemical Society v.8 n.2 1997reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531997000200002info:eu-repo/semantics/openAccessArvia,A.J.Salvarezza,R.C.eng2012-10-30T00:00:00Zoai:scielo:S0103-50531997000200002Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2012-10-30T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv An interdisciplinary approach to the electrochemistry at solid electrodes
title An interdisciplinary approach to the electrochemistry at solid electrodes
spellingShingle An interdisciplinary approach to the electrochemistry at solid electrodes
Arvia,A.J.
irregular electrode surfaces
nanoscopies
dynamic scaling
title_short An interdisciplinary approach to the electrochemistry at solid electrodes
title_full An interdisciplinary approach to the electrochemistry at solid electrodes
title_fullStr An interdisciplinary approach to the electrochemistry at solid electrodes
title_full_unstemmed An interdisciplinary approach to the electrochemistry at solid electrodes
title_sort An interdisciplinary approach to the electrochemistry at solid electrodes
author Arvia,A.J.
author_facet Arvia,A.J.
Salvarezza,R.C.
author_role author
author2 Salvarezza,R.C.
author2_role author
dc.contributor.author.fl_str_mv Arvia,A.J.
Salvarezza,R.C.
dc.subject.por.fl_str_mv irregular electrode surfaces
nanoscopies
dynamic scaling
topic irregular electrode surfaces
nanoscopies
dynamic scaling
description An interdisciplinary approach to the electrochemistry at solid electrodes is presented here taking into account new basic interpretations for either phase growth or phase disruption under conditions far from equilibrium. For this purpose imaging data derived from scanning tunneling microscopy (STM) and atomic force microscopy (AFM) at different scale lengths are extremely useful. This approach provides new insights into roughness development, roughness decay and reactivity at solid electrodes. The study of mobile interfaces by the sequential application of in situ STM data and an interpretation based on the dynamic scaling theory furnish a qualitative and a quantitative description of surface irregularities, and provide information about the interface evolution mechanism under steady and non-steady roughness regimes. Various examples of electrochemical interest are discussed on the basis of this interdisciplinary approach.
publishDate 1997
dc.date.none.fl_str_mv 1997-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531997000200002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531997000200002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50531997000200002
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.8 n.2 1997
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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