Ionic liquids’ cation and anion influence on aromatic amine solubility

Bibliographic Details
Main Author: Morais, Ana Rita C.
Publication Date: 2013
Other Authors: Lopes, André, Bogel-Lukasik, Ewa, Lukasik, Rafal M.
Format: Article
Language: eng
Source: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Download full: http://hdl.handle.net/10400.9/2334
Summary: he mutual solubility of aniline and a series of imidazolium based ionic liquids with bis(trifluoromethylsulfonyl)amide, chloride, dicyanamide, tetrafluoroborate, and hexafluorophospate anions were studied. The produced results show the potential in the new solvent systems which can be used in amine chemistry. The liquid–liquid equilibrium (LLE) and solid–liquid equilibrium (SLE) measurements were performed using a dynamic (synthetic) method. The mutual solubility of aniline in bis(trifluoromethylsulfonyl)amide and hexafluorophosphate ionic liquids was complete in the examined range of temperatures. The solubility of remaining studied ionic liquids decreases with the decrease of Kamlet–Taft basicity of ionic liquid anion. In other words, the solubility was the lowest for a chloride ionic liquid and increases for dicyanamide and for tetrafluoroborate ionic liquids. Additionally, the increase of the alkyl chain length of the IL cation effects negatively the solubility of aniline in the investigated ionic liquids.
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spelling Ionic liquids’ cation and anion influence on aromatic amine solubilityIonic liquidsLiquid-liquid equilibriumSolid–liquid equilibriumhe mutual solubility of aniline and a series of imidazolium based ionic liquids with bis(trifluoromethylsulfonyl)amide, chloride, dicyanamide, tetrafluoroborate, and hexafluorophospate anions were studied. The produced results show the potential in the new solvent systems which can be used in amine chemistry. The liquid–liquid equilibrium (LLE) and solid–liquid equilibrium (SLE) measurements were performed using a dynamic (synthetic) method. The mutual solubility of aniline in bis(trifluoromethylsulfonyl)amide and hexafluorophosphate ionic liquids was complete in the examined range of temperatures. The solubility of remaining studied ionic liquids decreases with the decrease of Kamlet–Taft basicity of ionic liquid anion. In other words, the solubility was the lowest for a chloride ionic liquid and increases for dicyanamide and for tetrafluoroborate ionic liquids. Additionally, the increase of the alkyl chain length of the IL cation effects negatively the solubility of aniline in the investigated ionic liquids.ACS PublicationsRepositório do LNEGMorais, Ana Rita C.Lopes, AndréBogel-Lukasik, EwaLukasik, Rafal M.2014-03-20T16:05:13Z20132013-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.9/2334engMorais, Ana Rita C.; Lopes, André M. da Costa; Bogel-Lukasik, E.; Bogel-Lukasik, R. Ionic liquids’ cation and anion influence on aromatic amine solubility. In: Industrial & Engineering Chemistry Research, 2013, Vol. 52, nº 41, p. 14722–147260888-5885info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-26T06:44:15Zoai:repositorio.lneg.pt:10400.9/2334Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T15:35:13.654557Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Ionic liquids’ cation and anion influence on aromatic amine solubility
title Ionic liquids’ cation and anion influence on aromatic amine solubility
spellingShingle Ionic liquids’ cation and anion influence on aromatic amine solubility
Morais, Ana Rita C.
Ionic liquids
Liquid-liquid equilibrium
Solid–liquid equilibrium
title_short Ionic liquids’ cation and anion influence on aromatic amine solubility
title_full Ionic liquids’ cation and anion influence on aromatic amine solubility
title_fullStr Ionic liquids’ cation and anion influence on aromatic amine solubility
title_full_unstemmed Ionic liquids’ cation and anion influence on aromatic amine solubility
title_sort Ionic liquids’ cation and anion influence on aromatic amine solubility
author Morais, Ana Rita C.
author_facet Morais, Ana Rita C.
Lopes, André
Bogel-Lukasik, Ewa
Lukasik, Rafal M.
author_role author
author2 Lopes, André
Bogel-Lukasik, Ewa
Lukasik, Rafal M.
author2_role author
author
author
dc.contributor.none.fl_str_mv Repositório do LNEG
dc.contributor.author.fl_str_mv Morais, Ana Rita C.
Lopes, André
Bogel-Lukasik, Ewa
Lukasik, Rafal M.
dc.subject.por.fl_str_mv Ionic liquids
Liquid-liquid equilibrium
Solid–liquid equilibrium
topic Ionic liquids
Liquid-liquid equilibrium
Solid–liquid equilibrium
description he mutual solubility of aniline and a series of imidazolium based ionic liquids with bis(trifluoromethylsulfonyl)amide, chloride, dicyanamide, tetrafluoroborate, and hexafluorophospate anions were studied. The produced results show the potential in the new solvent systems which can be used in amine chemistry. The liquid–liquid equilibrium (LLE) and solid–liquid equilibrium (SLE) measurements were performed using a dynamic (synthetic) method. The mutual solubility of aniline in bis(trifluoromethylsulfonyl)amide and hexafluorophosphate ionic liquids was complete in the examined range of temperatures. The solubility of remaining studied ionic liquids decreases with the decrease of Kamlet–Taft basicity of ionic liquid anion. In other words, the solubility was the lowest for a chloride ionic liquid and increases for dicyanamide and for tetrafluoroborate ionic liquids. Additionally, the increase of the alkyl chain length of the IL cation effects negatively the solubility of aniline in the investigated ionic liquids.
publishDate 2013
dc.date.none.fl_str_mv 2013
2013-01-01T00:00:00Z
2014-03-20T16:05:13Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.9/2334
url http://hdl.handle.net/10400.9/2334
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Morais, Ana Rita C.; Lopes, André M. da Costa; Bogel-Lukasik, E.; Bogel-Lukasik, R. Ionic liquids’ cation and anion influence on aromatic amine solubility. In: Industrial & Engineering Chemistry Research, 2013, Vol. 52, nº 41, p. 14722–14726
0888-5885
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv ACS Publications
publisher.none.fl_str_mv ACS Publications
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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