Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems

Detalhes bibliográficos
Autor(a) principal: Şaka,Irfan
Data de Publicação: 2008
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Brazilian Journal of Physics
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332008000300003
Resumo: A DEPT pulse sequence is well-known 13C-detected, edited-pulse and cross polarization transfer NMR experiment which offers to selective detection capability of CH, CH2 and CH3 groups from each other. The product operator theory is widely used for analytical descriptions of the cross polarization transfer NMR experiments for weakly coupled spin systems. In this study, analytical descriptions of the DEPT NMR experiment have been presented for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems by using product operator theory. Then a theoretical discussion and experimental suggestions were made. It has been investigated that this experiment can be used to edit 14N sub-spectra of partly or full deuterated 14NDn (n=1, 2, 3, 4) groups.
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spelling Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systemsNMR; DEPTProduct operator theoryDeuterated nitrogen groupsA DEPT pulse sequence is well-known 13C-detected, edited-pulse and cross polarization transfer NMR experiment which offers to selective detection capability of CH, CH2 and CH3 groups from each other. The product operator theory is widely used for analytical descriptions of the cross polarization transfer NMR experiments for weakly coupled spin systems. In this study, analytical descriptions of the DEPT NMR experiment have been presented for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems by using product operator theory. Then a theoretical discussion and experimental suggestions were made. It has been investigated that this experiment can be used to edit 14N sub-spectra of partly or full deuterated 14NDn (n=1, 2, 3, 4) groups.Sociedade Brasileira de Física2008-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332008000300003Brazilian Journal of Physics v.38 n.3a 2008reponame:Brazilian Journal of Physicsinstname:Sociedade Brasileira de Física (SBF)instacron:SBF10.1590/S0103-97332008000300003info:eu-repo/semantics/openAccessŞaka,Irfaneng2008-09-22T00:00:00Zoai:scielo:S0103-97332008000300003Revistahttp://www.sbfisica.org.br/v1/home/index.php/pt/ONGhttps://old.scielo.br/oai/scielo-oai.phpsbfisica@sbfisica.org.br||sbfisica@sbfisica.org.br1678-44480103-9733opendoar:2008-09-22T00:00Brazilian Journal of Physics - Sociedade Brasileira de Física (SBF)false
dc.title.none.fl_str_mv Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems
title Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems
spellingShingle Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems
Şaka,Irfan
NMR; DEPT
Product operator theory
Deuterated nitrogen groups
title_short Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems
title_full Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems
title_fullStr Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems
title_full_unstemmed Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems
title_sort Analytical descriptions of DEPT NMR spectroscopy for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems
author Şaka,Irfan
author_facet Şaka,Irfan
author_role author
dc.contributor.author.fl_str_mv Şaka,Irfan
dc.subject.por.fl_str_mv NMR; DEPT
Product operator theory
Deuterated nitrogen groups
topic NMR; DEPT
Product operator theory
Deuterated nitrogen groups
description A DEPT pulse sequence is well-known 13C-detected, edited-pulse and cross polarization transfer NMR experiment which offers to selective detection capability of CH, CH2 and CH3 groups from each other. The product operator theory is widely used for analytical descriptions of the cross polarization transfer NMR experiments for weakly coupled spin systems. In this study, analytical descriptions of the DEPT NMR experiment have been presented for ISn(I = 1,S = 1; n = 1, 2, 3, 4) spin systems by using product operator theory. Then a theoretical discussion and experimental suggestions were made. It has been investigated that this experiment can be used to edit 14N sub-spectra of partly or full deuterated 14NDn (n=1, 2, 3, 4) groups.
publishDate 2008
dc.date.none.fl_str_mv 2008-09-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332008000300003
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332008000300003
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-97332008000300003
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Física
publisher.none.fl_str_mv Sociedade Brasileira de Física
dc.source.none.fl_str_mv Brazilian Journal of Physics v.38 n.3a 2008
reponame:Brazilian Journal of Physics
instname:Sociedade Brasileira de Física (SBF)
instacron:SBF
instname_str Sociedade Brasileira de Física (SBF)
instacron_str SBF
institution SBF
reponame_str Brazilian Journal of Physics
collection Brazilian Journal of Physics
repository.name.fl_str_mv Brazilian Journal of Physics - Sociedade Brasileira de Física (SBF)
repository.mail.fl_str_mv sbfisica@sbfisica.org.br||sbfisica@sbfisica.org.br
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