A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settings
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Brazilian Journal of Geology |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S2317-48892018000100161 |
Resumo: | ABSTRACT: In this study, the crystallization dynamics and the fingerprints of two topaz crystals from the Ouro Preto region (Brazil), two from the Eastern Brazilian Pegmatite Province (EBPP), one from the Western part of the United States (US) and one from Pakistan were characterized. The combination of scanning electron microscope-cathodoluminescence (SEM-CL) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) data allowed for the characterization of these samples. Samples from the Ouro Preto region showed primary crystallization and recrystallization processes, which were demonstrated by a CL-heterogeneous core and CL-homogeneous rims in the SEM-CL images. Their fingerprint was composed of Ca, Ti, V, Cr, Mn, Fe, Cu and Zn. Samples from the EBPP showed both dark and CL-homogeneous SEM-CL images, implying slow and late-stage crystallization, typical of pegmatites. Their fingerprints were composed of Li, Nb, LREE, Ta and W, and of Ti, Nb and HREE. A sample from a Western part of the US displayed CL-heterogeneity with growth and resorption events and well-preserved growth zones, which were noticeable through the SEM-CL images. Its fingerprint was composed of Li, Ti, V, Mn, Nb, LREE, Ta and W. A sample from Pakistan showed an evident metamorphic recrystallization process, which was visible by the incipient and CL-homogeneous luminescence given by the SEM-CL images. Its fingerprint was composed of Ca, Cr, V, Zn, LREE, HREE and W. |
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Brazilian Journal of Geology |
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A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settingstopaztrace elementscathodoluminescencecrystallization dynamicsfingerprintABSTRACT: In this study, the crystallization dynamics and the fingerprints of two topaz crystals from the Ouro Preto region (Brazil), two from the Eastern Brazilian Pegmatite Province (EBPP), one from the Western part of the United States (US) and one from Pakistan were characterized. The combination of scanning electron microscope-cathodoluminescence (SEM-CL) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) data allowed for the characterization of these samples. Samples from the Ouro Preto region showed primary crystallization and recrystallization processes, which were demonstrated by a CL-heterogeneous core and CL-homogeneous rims in the SEM-CL images. Their fingerprint was composed of Ca, Ti, V, Cr, Mn, Fe, Cu and Zn. Samples from the EBPP showed both dark and CL-homogeneous SEM-CL images, implying slow and late-stage crystallization, typical of pegmatites. Their fingerprints were composed of Li, Nb, LREE, Ta and W, and of Ti, Nb and HREE. A sample from a Western part of the US displayed CL-heterogeneity with growth and resorption events and well-preserved growth zones, which were noticeable through the SEM-CL images. Its fingerprint was composed of Li, Ti, V, Mn, Nb, LREE, Ta and W. A sample from Pakistan showed an evident metamorphic recrystallization process, which was visible by the incipient and CL-homogeneous luminescence given by the SEM-CL images. Its fingerprint was composed of Ca, Cr, V, Zn, LREE, HREE and W.Sociedade Brasileira de Geologia2018-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S2317-48892018000100161Brazilian Journal of Geology v.48 n.1 2018reponame:Brazilian Journal of Geologyinstname:Sociedade Brasileira de Geologia (SBGEO)instacron:SBGEO10.1590/2317-4889201820170127info:eu-repo/semantics/openAccessGauzzi,TeodoroGraça,Leonardo Martinseng2018-04-03T00:00:00Zoai:scielo:S2317-48892018000100161Revistahttp://bjg.siteoficial.ws/index.htmhttps://old.scielo.br/oai/scielo-oai.phpsbgsede@sbgeo.org.br||claudio.riccomini@gmail.com2317-46922317-4692opendoar:2018-04-03T00:00Brazilian Journal of Geology - Sociedade Brasileira de Geologia (SBGEO)false |
dc.title.none.fl_str_mv |
A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settings |
title |
A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settings |
spellingShingle |
A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settings Gauzzi,Teodoro topaz trace elements cathodoluminescence crystallization dynamics fingerprint |
title_short |
A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settings |
title_full |
A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settings |
title_fullStr |
A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settings |
title_full_unstemmed |
A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settings |
title_sort |
A cathodoluminescence-assisted LA-ICP-MS study of topaz from different geological settings |
author |
Gauzzi,Teodoro |
author_facet |
Gauzzi,Teodoro Graça,Leonardo Martins |
author_role |
author |
author2 |
Graça,Leonardo Martins |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Gauzzi,Teodoro Graça,Leonardo Martins |
dc.subject.por.fl_str_mv |
topaz trace elements cathodoluminescence crystallization dynamics fingerprint |
topic |
topaz trace elements cathodoluminescence crystallization dynamics fingerprint |
description |
ABSTRACT: In this study, the crystallization dynamics and the fingerprints of two topaz crystals from the Ouro Preto region (Brazil), two from the Eastern Brazilian Pegmatite Province (EBPP), one from the Western part of the United States (US) and one from Pakistan were characterized. The combination of scanning electron microscope-cathodoluminescence (SEM-CL) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) data allowed for the characterization of these samples. Samples from the Ouro Preto region showed primary crystallization and recrystallization processes, which were demonstrated by a CL-heterogeneous core and CL-homogeneous rims in the SEM-CL images. Their fingerprint was composed of Ca, Ti, V, Cr, Mn, Fe, Cu and Zn. Samples from the EBPP showed both dark and CL-homogeneous SEM-CL images, implying slow and late-stage crystallization, typical of pegmatites. Their fingerprints were composed of Li, Nb, LREE, Ta and W, and of Ti, Nb and HREE. A sample from a Western part of the US displayed CL-heterogeneity with growth and resorption events and well-preserved growth zones, which were noticeable through the SEM-CL images. Its fingerprint was composed of Li, Ti, V, Mn, Nb, LREE, Ta and W. A sample from Pakistan showed an evident metamorphic recrystallization process, which was visible by the incipient and CL-homogeneous luminescence given by the SEM-CL images. Its fingerprint was composed of Ca, Cr, V, Zn, LREE, HREE and W. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S2317-48892018000100161 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S2317-48892018000100161 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/2317-4889201820170127 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Geologia |
publisher.none.fl_str_mv |
Sociedade Brasileira de Geologia |
dc.source.none.fl_str_mv |
Brazilian Journal of Geology v.48 n.1 2018 reponame:Brazilian Journal of Geology instname:Sociedade Brasileira de Geologia (SBGEO) instacron:SBGEO |
instname_str |
Sociedade Brasileira de Geologia (SBGEO) |
instacron_str |
SBGEO |
institution |
SBGEO |
reponame_str |
Brazilian Journal of Geology |
collection |
Brazilian Journal of Geology |
repository.name.fl_str_mv |
Brazilian Journal of Geology - Sociedade Brasileira de Geologia (SBGEO) |
repository.mail.fl_str_mv |
sbgsede@sbgeo.org.br||claudio.riccomini@gmail.com |
_version_ |
1752122398851727360 |