A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap model

Detalhes bibliográficos
Autor(a) principal: Malta,O.L.
Data de Publicação: 1998
Outros Autores: Mauro,A.E., Mattioli,M.P.D., Sargentelli,V., Brito,H.F.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000300007
Resumo: We present a theoretical description of ligand field effects in the di-mu-azido- bis[{azido( N,N-diethylethylenediamine)} copper(II)] compound by the Simple Overlap Model. The ligand field Hamiltonian is expressed in terms of irreducible tensor operators for an assumed D3h site symmetry occupied by the copper ion. The ligand field parameters, calculated from the available structural data, indicate that the copper ion is under the influence of a very strong ligand field. The energy of the d-d absorption band is well reproduced phenomenologically by the model.
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spelling A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap modelcopper(II)complexesamine ligandsligand fieldWe present a theoretical description of ligand field effects in the di-mu-azido- bis[{azido( N,N-diethylethylenediamine)} copper(II)] compound by the Simple Overlap Model. The ligand field Hamiltonian is expressed in terms of irreducible tensor operators for an assumed D3h site symmetry occupied by the copper ion. The ligand field parameters, calculated from the available structural data, indicate that the copper ion is under the influence of a very strong ligand field. The energy of the d-d absorption band is well reproduced phenomenologically by the model.Sociedade Brasileira de Química1998-05-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000300007Journal of the Brazilian Chemical Society v.9 n.3 1998reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531998000300007info:eu-repo/semantics/openAccessMalta,O.L.Mauro,A.E.Mattioli,M.P.D.Sargentelli,V.Brito,H.F.eng2002-11-06T00:00:00Zoai:scielo:S0103-50531998000300007Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2002-11-06T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap model
title A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap model
spellingShingle A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap model
Malta,O.L.
copper(II)
complexes
amine ligands
ligand field
title_short A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap model
title_full A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap model
title_fullStr A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap model
title_full_unstemmed A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap model
title_sort A description of ligand field effects in the Di-mu-Azido-Bis [{Azido(N,N-Diethylethylenediamine)}Copper(II)] compound by the simple overlap model
author Malta,O.L.
author_facet Malta,O.L.
Mauro,A.E.
Mattioli,M.P.D.
Sargentelli,V.
Brito,H.F.
author_role author
author2 Mauro,A.E.
Mattioli,M.P.D.
Sargentelli,V.
Brito,H.F.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Malta,O.L.
Mauro,A.E.
Mattioli,M.P.D.
Sargentelli,V.
Brito,H.F.
dc.subject.por.fl_str_mv copper(II)
complexes
amine ligands
ligand field
topic copper(II)
complexes
amine ligands
ligand field
description We present a theoretical description of ligand field effects in the di-mu-azido- bis[{azido( N,N-diethylethylenediamine)} copper(II)] compound by the Simple Overlap Model. The ligand field Hamiltonian is expressed in terms of irreducible tensor operators for an assumed D3h site symmetry occupied by the copper ion. The ligand field parameters, calculated from the available structural data, indicate that the copper ion is under the influence of a very strong ligand field. The energy of the d-d absorption band is well reproduced phenomenologically by the model.
publishDate 1998
dc.date.none.fl_str_mv 1998-05-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000300007
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000300007
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50531998000300007
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.9 n.3 1998
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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