Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditions

Detalhes bibliográficos
Autor(a) principal: Perin,Gelson
Data de Publicação: 2005
Outros Autores: Jacob,Raquel G., Botteselle,Giancarlo V., Kublik,Emerson L., Lenardão,Eder J., Cella,Rodrigo, Santos,Paulo César Silva dos
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000500027
Resumo: A simple, clean and efficient method has been developed for the synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno-alpha,beta-unsaturated esters by a one-pot reaction of aldehydes with phenylselenoacetonitrile or ethyl(phenylseleno)acetate respectively, in the presence of a solid supported catalyst (KF/Al2O3), without any solvent.
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spelling Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditionssolvent-free reactionKnoevenagel condensationphenylselenoacrylonitrilesA simple, clean and efficient method has been developed for the synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno-alpha,beta-unsaturated esters by a one-pot reaction of aldehydes with phenylselenoacetonitrile or ethyl(phenylseleno)acetate respectively, in the presence of a solid supported catalyst (KF/Al2O3), without any solvent.Sociedade Brasileira de Química2005-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000500027Journal of the Brazilian Chemical Society v.16 n.4 2005reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532005000500027info:eu-repo/semantics/openAccessPerin,GelsonJacob,Raquel G.Botteselle,Giancarlo V.Kublik,Emerson L.Lenardão,Eder J.Cella,RodrigoSantos,Paulo César Silva doseng2005-08-25T00:00:00Zoai:scielo:S0103-50532005000500027Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2005-08-25T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditions
title Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditions
spellingShingle Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditions
Perin,Gelson
solvent-free reaction
Knoevenagel condensation
phenylselenoacrylonitriles
title_short Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditions
title_full Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditions
title_fullStr Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditions
title_full_unstemmed Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditions
title_sort Clean and atom-economic synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno- alpha,beta-unsaturated esters by knoevenagel reaction under solvent-free conditions
author Perin,Gelson
author_facet Perin,Gelson
Jacob,Raquel G.
Botteselle,Giancarlo V.
Kublik,Emerson L.
Lenardão,Eder J.
Cella,Rodrigo
Santos,Paulo César Silva dos
author_role author
author2 Jacob,Raquel G.
Botteselle,Giancarlo V.
Kublik,Emerson L.
Lenardão,Eder J.
Cella,Rodrigo
Santos,Paulo César Silva dos
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Perin,Gelson
Jacob,Raquel G.
Botteselle,Giancarlo V.
Kublik,Emerson L.
Lenardão,Eder J.
Cella,Rodrigo
Santos,Paulo César Silva dos
dc.subject.por.fl_str_mv solvent-free reaction
Knoevenagel condensation
phenylselenoacrylonitriles
topic solvent-free reaction
Knoevenagel condensation
phenylselenoacrylonitriles
description A simple, clean and efficient method has been developed for the synthesis of alpha-phenylselenoacrylonitriles and alpha-phenylseleno-alpha,beta-unsaturated esters by a one-pot reaction of aldehydes with phenylselenoacetonitrile or ethyl(phenylseleno)acetate respectively, in the presence of a solid supported catalyst (KF/Al2O3), without any solvent.
publishDate 2005
dc.date.none.fl_str_mv 2005-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000500027
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000500027
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532005000500027
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.16 n.4 2005
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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