Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidase
Autor(a) principal: | |
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Data de Publicação: | 2004 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532004000600017 |
Resumo: | The synthesis and solution characterization of the coordination compounds - [CuII(H2bbpeten)](NO3 )2, [H2bbpeten = N-(2-hydroxybenzyl)-N,N'-bis(2-pyridylmethyl)- N'-(2-hydroxyethyl)ethane-1,2-diamine]; [CuII(H3bpeten)](NO3 )2, [H3bpten = N,N'- bis- (2-hydroxybenzyl) -N-(2-pyridylmethyl)-N'-(2-hydroxyethyl)ethane-1,2-diamine]; [CuII(Hnbbpeten)]NO3, [H2nbbpeten = N-(5-nitro-2-hydroxybenzyl)-N,N '-bis(2- pyridylmethyl)-N'-(2-hydroxyethyl)ethane-1,2-diamine] and [CuII(Hbnbpeten)], [H3bnbpeten = N,N'-bis-(5-nitro-2-hydroxybenzyl)-N -2-pyridylmethyl)-N'-(2-hydroxyethyl)ethane-1,2-diamine] - are reported as copper(II) complexes containing alcoholic, pyridine and phenolic arms. Two of the ligands bear a NO2 group at the para position of one or two of the phenolic moieties. Electrochemical studies have been performed for the proligands and for the copper complexes. |
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Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidaseCuII complexeselectrochemical propertiesEPRgalactose oxidaseThe synthesis and solution characterization of the coordination compounds - [CuII(H2bbpeten)](NO3 )2, [H2bbpeten = N-(2-hydroxybenzyl)-N,N'-bis(2-pyridylmethyl)- N'-(2-hydroxyethyl)ethane-1,2-diamine]; [CuII(H3bpeten)](NO3 )2, [H3bpten = N,N'- bis- (2-hydroxybenzyl) -N-(2-pyridylmethyl)-N'-(2-hydroxyethyl)ethane-1,2-diamine]; [CuII(Hnbbpeten)]NO3, [H2nbbpeten = N-(5-nitro-2-hydroxybenzyl)-N,N '-bis(2- pyridylmethyl)-N'-(2-hydroxyethyl)ethane-1,2-diamine] and [CuII(Hbnbpeten)], [H3bnbpeten = N,N'-bis-(5-nitro-2-hydroxybenzyl)-N -2-pyridylmethyl)-N'-(2-hydroxyethyl)ethane-1,2-diamine] - are reported as copper(II) complexes containing alcoholic, pyridine and phenolic arms. Two of the ligands bear a NO2 group at the para position of one or two of the phenolic moieties. Electrochemical studies have been performed for the proligands and for the copper complexes.Sociedade Brasileira de Química2004-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532004000600017Journal of the Brazilian Chemical Society v.15 n.6 2004reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532004000600017info:eu-repo/semantics/openAccessRomanowski,Stela Maris de M.Tormena,FrancielenSantos,Viviane A. dosHermann,Monique de F.Mangrich,Antonio S.eng2005-01-24T00:00:00Zoai:scielo:S0103-50532004000600017Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2005-01-24T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidase |
title |
Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidase |
spellingShingle |
Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidase Romanowski,Stela Maris de M. CuII complexes electrochemical properties EPR galactose oxidase |
title_short |
Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidase |
title_full |
Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidase |
title_fullStr |
Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidase |
title_full_unstemmed |
Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidase |
title_sort |
Solution studies of copper(II) complexes as a contribution to the study of the active site of galactose oxidase |
author |
Romanowski,Stela Maris de M. |
author_facet |
Romanowski,Stela Maris de M. Tormena,Francielen Santos,Viviane A. dos Hermann,Monique de F. Mangrich,Antonio S. |
author_role |
author |
author2 |
Tormena,Francielen Santos,Viviane A. dos Hermann,Monique de F. Mangrich,Antonio S. |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Romanowski,Stela Maris de M. Tormena,Francielen Santos,Viviane A. dos Hermann,Monique de F. Mangrich,Antonio S. |
dc.subject.por.fl_str_mv |
CuII complexes electrochemical properties EPR galactose oxidase |
topic |
CuII complexes electrochemical properties EPR galactose oxidase |
description |
The synthesis and solution characterization of the coordination compounds - [CuII(H2bbpeten)](NO3 )2, [H2bbpeten = N-(2-hydroxybenzyl)-N,N'-bis(2-pyridylmethyl)- N'-(2-hydroxyethyl)ethane-1,2-diamine]; [CuII(H3bpeten)](NO3 )2, [H3bpten = N,N'- bis- (2-hydroxybenzyl) -N-(2-pyridylmethyl)-N'-(2-hydroxyethyl)ethane-1,2-diamine]; [CuII(Hnbbpeten)]NO3, [H2nbbpeten = N-(5-nitro-2-hydroxybenzyl)-N,N '-bis(2- pyridylmethyl)-N'-(2-hydroxyethyl)ethane-1,2-diamine] and [CuII(Hbnbpeten)], [H3bnbpeten = N,N'-bis-(5-nitro-2-hydroxybenzyl)-N -2-pyridylmethyl)-N'-(2-hydroxyethyl)ethane-1,2-diamine] - are reported as copper(II) complexes containing alcoholic, pyridine and phenolic arms. Two of the ligands bear a NO2 group at the para position of one or two of the phenolic moieties. Electrochemical studies have been performed for the proligands and for the copper complexes. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532004000600017 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532004000600017 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50532004000600017 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.15 n.6 2004 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
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1750318166099099648 |