Composite Superabsorbent Hydrogel of Acrylic Copolymer and Eggshell: Effect of Biofiller Addition

• Autor(a) principal: Queirós,Marcos Vinícius A.
• Data de Publicação: 2017
• Outros Autores: Bezerra,Maslândia N., Feitosa,Judith P. A.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Journal of the Brazilian Chemical Society (Online)
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017001002004
• topic: polymer-matrix composite; superabsorbent hydrogel; acrylamide; acrylate; eggshell

Eggshell (ES) is an abundant waste material which is mainly composed of calcium carbonate. A superabsorbent hydrogel composite based on poly(acrylamide-co-potassium acrylate) as matrix containing 17 wt.% of chicken ES powder as a filler was synthesized and compared with the gel without filler. The characterization was carried out by Fourier transform infrared (FTIR), scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX), thermogravimetric analysis (TGA), X-ray diffraction (XRD), rheological analysis and kinetics studies. The dispersion of ES in the polymeric matrix was homogeneous. The interaction between the acrylate and calcium cation was detected by FTIR analysis. The composite improved the gel strength and the absorption of water and saline solution increased by 100 and 41%, respectively. The high values for the swelling, the homogeneous structure and the good mechanical properties obtained with the incorporation of a relatively high content of a low-cost waste material indicate that this composite is suitable for application in the agriculture. In addition, this approach provides a more ecologically sound and useful destination for eggshell residue.