Forensic investigation of formaldehyde in illicit products for hair treatment by dad‐hplc: a case study

• Autor(a) principal: Okumura, Leonardo L.
• Data de Publicação: 2016
• Outros Autores: Oiye, Erica N., Ribeiro, Maria Fernanda M., Saczk, Adelir A., Ciancaglini, Pietro, Oliveira, Marcelo F. de
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: LOCUS Repositório Institucional da UFV
• Texto Completo: https://doi.org/10.1111/1556-4029.13068; http://www.locus.ufv.br/handle/123456789/19660
• topic: Forensic science; Formaldehyde; Hair straightening; High-performance liquid chromatography; Forensic chemistry; 2,4-dinitrophenylhydrazine

The illegal use of formalin (commercial formaldehyde) in cosmetic products harms the health of individuals exposed to this substance. Over the last years, the commercial availability of these products, especially those containing irregular dosage of formaldehyde, has increased in Brazil. This work analyzes some products for hair treatment available in the Brazilian market and verifies their safety. The adopted analytical methodology involved sample derivatization with 2,4‐dinitrophenylhydrazine, followed by high‐performance liquid chromatography with ultraviolet detection (UV–VIS) at λ = 365 nm. The limit of quantification is 2.5 × 10−3% w/w, and the recovery tests were around 93%. Some of the samples contained high and illegal formaldehyde levels ranging from 9% to 19% (w/w) and others presented suitable concentrations of the analyte. On the basis of the results, this work discusses the efficiency and practicality of this analytical method for forensic purposes.