Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-gel

Detalhes bibliográficos
Autor(a) principal: Geraldo, Viviany
Data de Publicação: 2003
Outros Autores: Scalvi, Luis Vicente De Andrade [UNESP], Morais, Evandro Augusto De, Santilli, Celso Valentim [UNESP], Pulcinelli, Sandra Helena [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1590/S1516-14392003000400004
http://hdl.handle.net/11449/212954
Resumo: Transparent electrically conducting antimony-doped SnO2 thin films have been prepared by sol-gel dip-coating process from colloidal aqueous suspension. The effect of doping content on the structural, optical and electrical properties is analyzed. Results from infrared optical transmission and reflection have shown that the higher the Sb concentration the lower the transmission intensity and the higher the reflection signal. Absorption intensity increases as well. Results of X-ray reflectometry and electron microscopy have shown that the density of films fired at 400 °C after each dip is higher than that of multi-dipped films prepared with a single annealing. Both the electrical characteristics in the dark and the increase in conductivity as function of illumination through different filters, at 190 K, evidence that the transport properties of these films are dominated by the presence of defects, including the trapping at grain boundary due to excess of oxygen.
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spelling Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-geltin dioxidenanostructuressol-geloptical propertiesTransparent electrically conducting antimony-doped SnO2 thin films have been prepared by sol-gel dip-coating process from colloidal aqueous suspension. The effect of doping content on the structural, optical and electrical properties is analyzed. Results from infrared optical transmission and reflection have shown that the higher the Sb concentration the lower the transmission intensity and the higher the reflection signal. Absorption intensity increases as well. Results of X-ray reflectometry and electron microscopy have shown that the density of films fired at 400 °C after each dip is higher than that of multi-dipped films prepared with a single annealing. Both the electrical characteristics in the dark and the increase in conductivity as function of illumination through different filters, at 190 K, evidence that the transport properties of these films are dominated by the presence of defects, including the trapping at grain boundary due to excess of oxygen.Universidade de São Paulo, Instituto de Física de São CarlosUniversidade Estadual Paulista, Instituto de Química de AraraquaraUniversidade Estadual Paulista, FCUniversidade Estadual Paulista, Instituto de Química de AraraquaraUniversidade Estadual Paulista, FCABM, ABC, ABPolUniversidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)Geraldo, VivianyScalvi, Luis Vicente De Andrade [UNESP]Morais, Evandro Augusto DeSantilli, Celso Valentim [UNESP]Pulcinelli, Sandra Helena [UNESP]2021-07-14T10:47:43Z2021-07-14T10:47:43Z2003-12info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article451-456application/pdfhttp://dx.doi.org/10.1590/S1516-14392003000400004Materials Research. São Carlos, SP, Brazil: ABM, ABC, ABPol, v. 6, n. 4, p. 451-456, 2003.1516-14391980-5373http://hdl.handle.net/11449/21295410.1590/S1516-14392003000400004S1516-14392003000400004S1516-14392003000400004.pdfSciELOreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengMaterials Researchinfo:eu-repo/semantics/openAccess2023-10-25T06:05:30Zoai:repositorio.unesp.br:11449/212954Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462023-10-25T06:05:30Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-gel
title Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-gel
spellingShingle Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-gel
Geraldo, Viviany
tin dioxide
nanostructures
sol-gel
optical properties
title_short Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-gel
title_full Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-gel
title_fullStr Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-gel
title_full_unstemmed Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-gel
title_sort Sb doping effects and oxygen adsorption in SnO2 thin films deposited via sol-gel
author Geraldo, Viviany
author_facet Geraldo, Viviany
Scalvi, Luis Vicente De Andrade [UNESP]
Morais, Evandro Augusto De
Santilli, Celso Valentim [UNESP]
Pulcinelli, Sandra Helena [UNESP]
author_role author
author2 Scalvi, Luis Vicente De Andrade [UNESP]
Morais, Evandro Augusto De
Santilli, Celso Valentim [UNESP]
Pulcinelli, Sandra Helena [UNESP]
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade de São Paulo (USP)
Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Geraldo, Viviany
Scalvi, Luis Vicente De Andrade [UNESP]
Morais, Evandro Augusto De
Santilli, Celso Valentim [UNESP]
Pulcinelli, Sandra Helena [UNESP]
dc.subject.por.fl_str_mv tin dioxide
nanostructures
sol-gel
optical properties
topic tin dioxide
nanostructures
sol-gel
optical properties
description Transparent electrically conducting antimony-doped SnO2 thin films have been prepared by sol-gel dip-coating process from colloidal aqueous suspension. The effect of doping content on the structural, optical and electrical properties is analyzed. Results from infrared optical transmission and reflection have shown that the higher the Sb concentration the lower the transmission intensity and the higher the reflection signal. Absorption intensity increases as well. Results of X-ray reflectometry and electron microscopy have shown that the density of films fired at 400 °C after each dip is higher than that of multi-dipped films prepared with a single annealing. Both the electrical characteristics in the dark and the increase in conductivity as function of illumination through different filters, at 190 K, evidence that the transport properties of these films are dominated by the presence of defects, including the trapping at grain boundary due to excess of oxygen.
publishDate 2003
dc.date.none.fl_str_mv 2003-12
2021-07-14T10:47:43Z
2021-07-14T10:47:43Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1590/S1516-14392003000400004
Materials Research. São Carlos, SP, Brazil: ABM, ABC, ABPol, v. 6, n. 4, p. 451-456, 2003.
1516-1439
1980-5373
http://hdl.handle.net/11449/212954
10.1590/S1516-14392003000400004
S1516-14392003000400004
S1516-14392003000400004.pdf
url http://dx.doi.org/10.1590/S1516-14392003000400004
http://hdl.handle.net/11449/212954
identifier_str_mv Materials Research. São Carlos, SP, Brazil: ABM, ABC, ABPol, v. 6, n. 4, p. 451-456, 2003.
1516-1439
1980-5373
10.1590/S1516-14392003000400004
S1516-14392003000400004
S1516-14392003000400004.pdf
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Materials Research
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 451-456
application/pdf
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv SciELO
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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