Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles

Detalhes bibliográficos
Autor(a) principal: SOUZA,RODRIGO OCTÁVIO M.A. DE
Data de Publicação: 2019
Outros Autores: MIRANDA,LEANDRO S. DE MARIZ E
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Anais da Academia Brasileira de Ciências (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652019000200401
Resumo: Abstract The chemistry of 1,2,3-triazoles gained much attention since the discovery of the copper catalyzed Alkyne-azide cycloaddition (CuAAC) reaction which delivers exclusively the 1,4-regioisomer in high yields. On the other hand there is still no universal methodology capable of delivering the N2 substituted regioisomer. The unique properties of these N2-substituted 1,2,3-triazoles have stimulated synthetic efforts on the developments of methodologies capable of delivering it in high yield and selectivity. These efforts are the subject of the presented review.
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spelling Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles1,2,3-TriazolesHeterocyclesRegiosselectivityarylationAbstract The chemistry of 1,2,3-triazoles gained much attention since the discovery of the copper catalyzed Alkyne-azide cycloaddition (CuAAC) reaction which delivers exclusively the 1,4-regioisomer in high yields. On the other hand there is still no universal methodology capable of delivering the N2 substituted regioisomer. The unique properties of these N2-substituted 1,2,3-triazoles have stimulated synthetic efforts on the developments of methodologies capable of delivering it in high yield and selectivity. These efforts are the subject of the presented review.Academia Brasileira de Ciências2019-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652019000200401Anais da Academia Brasileira de Ciências v.91 suppl.1 2019reponame:Anais da Academia Brasileira de Ciências (Online)instname:Academia Brasileira de Ciências (ABC)instacron:ABC10.1590/0001-3765201820180751info:eu-repo/semantics/openAccessSOUZA,RODRIGO OCTÁVIO M.A. DEMIRANDA,LEANDRO S. DE MARIZ Eeng2019-02-22T00:00:00Zoai:scielo:S0001-37652019000200401Revistahttp://www.scielo.br/aabchttps://old.scielo.br/oai/scielo-oai.php||aabc@abc.org.br1678-26900001-3765opendoar:2019-02-22T00:00Anais da Academia Brasileira de Ciências (Online) - Academia Brasileira de Ciências (ABC)false
dc.title.none.fl_str_mv Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles
title Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles
spellingShingle Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles
SOUZA,RODRIGO OCTÁVIO M.A. DE
1,2,3-Triazoles
Heterocycles
Regiosselectivity
arylation
title_short Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles
title_full Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles
title_fullStr Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles
title_full_unstemmed Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles
title_sort Strategies Towards the Synthesis of N2-Substituted 1,2,3-Triazoles
author SOUZA,RODRIGO OCTÁVIO M.A. DE
author_facet SOUZA,RODRIGO OCTÁVIO M.A. DE
MIRANDA,LEANDRO S. DE MARIZ E
author_role author
author2 MIRANDA,LEANDRO S. DE MARIZ E
author2_role author
dc.contributor.author.fl_str_mv SOUZA,RODRIGO OCTÁVIO M.A. DE
MIRANDA,LEANDRO S. DE MARIZ E
dc.subject.por.fl_str_mv 1,2,3-Triazoles
Heterocycles
Regiosselectivity
arylation
topic 1,2,3-Triazoles
Heterocycles
Regiosselectivity
arylation
description Abstract The chemistry of 1,2,3-triazoles gained much attention since the discovery of the copper catalyzed Alkyne-azide cycloaddition (CuAAC) reaction which delivers exclusively the 1,4-regioisomer in high yields. On the other hand there is still no universal methodology capable of delivering the N2 substituted regioisomer. The unique properties of these N2-substituted 1,2,3-triazoles have stimulated synthetic efforts on the developments of methodologies capable of delivering it in high yield and selectivity. These efforts are the subject of the presented review.
publishDate 2019
dc.date.none.fl_str_mv 2019-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652019000200401
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652019000200401
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0001-3765201820180751
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Academia Brasileira de Ciências
publisher.none.fl_str_mv Academia Brasileira de Ciências
dc.source.none.fl_str_mv Anais da Academia Brasileira de Ciências v.91 suppl.1 2019
reponame:Anais da Academia Brasileira de Ciências (Online)
instname:Academia Brasileira de Ciências (ABC)
instacron:ABC
instname_str Academia Brasileira de Ciências (ABC)
instacron_str ABC
institution ABC
reponame_str Anais da Academia Brasileira de Ciências (Online)
collection Anais da Academia Brasileira de Ciências (Online)
repository.name.fl_str_mv Anais da Academia Brasileira de Ciências (Online) - Academia Brasileira de Ciências (ABC)
repository.mail.fl_str_mv ||aabc@abc.org.br
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