Stress effects on the kinetics of hydride formation and growth in metals
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Latin American journal of solids and structures (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1679-78252018001000704 |
Resumo: | Abstract Although metal hydrides are considered promising candidates for solid-state hydrogen storage, their use for practical applications remains a challenge due to the limitation imposed by the slow kinetics of hydrogen uptake and release, which has driven the interest in using metal nanoparticles as advanced materials of new hydrogen-storage systems since they display fast hydrogenation and dehydrogenation kinetics. Nevertheless, the understanding of the adsorption/release kinetics requires the investigation of the role played by the stress which appears to accommodate the misfit between the metal and hydride phases. In this paper, we present a continuum theory capable of assessing how the misfit stress affects the kinetics of hydride formation and growth in metallic nanoparticles. The theory is then applied to study the kinetics of adsorption/release in spherical particles. This work extends Duda and Tomassetti (2015, 2016) by considering stress-dependent hydrogen mobility. |
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Latin American journal of solids and structures (Online) |
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Stress effects on the kinetics of hydride formation and growth in metalsdiffusion-induced stressconfigurational forceshydrogen-storage systemsphase transformationAbstract Although metal hydrides are considered promising candidates for solid-state hydrogen storage, their use for practical applications remains a challenge due to the limitation imposed by the slow kinetics of hydrogen uptake and release, which has driven the interest in using metal nanoparticles as advanced materials of new hydrogen-storage systems since they display fast hydrogenation and dehydrogenation kinetics. Nevertheless, the understanding of the adsorption/release kinetics requires the investigation of the role played by the stress which appears to accommodate the misfit between the metal and hydride phases. In this paper, we present a continuum theory capable of assessing how the misfit stress affects the kinetics of hydride formation and growth in metallic nanoparticles. The theory is then applied to study the kinetics of adsorption/release in spherical particles. This work extends Duda and Tomassetti (2015, 2016) by considering stress-dependent hydrogen mobility.Associação Brasileira de Ciências Mecânicas2018-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1679-78252018001000704Latin American Journal of Solids and Structures v.15 n.10 2018reponame:Latin American journal of solids and structures (Online)instname:Associação Brasileira de Engenharia e Ciências Mecânicas (ABCM)instacron:ABCM10.1590/1679-78254335info:eu-repo/semantics/openAccessSouza,Angela C.Cruz,Antônio G.B. daDuda,Fernando P.eng2018-10-19T00:00:00Zoai:scielo:S1679-78252018001000704Revistahttp://www.scielo.br/scielo.php?script=sci_serial&pid=1679-7825&lng=pt&nrm=isohttps://old.scielo.br/oai/scielo-oai.phpabcm@abcm.org.br||maralves@usp.br1679-78251679-7817opendoar:2018-10-19T00:00Latin American journal of solids and structures (Online) - Associação Brasileira de Engenharia e Ciências Mecânicas (ABCM)false |
dc.title.none.fl_str_mv |
Stress effects on the kinetics of hydride formation and growth in metals |
title |
Stress effects on the kinetics of hydride formation and growth in metals |
spellingShingle |
Stress effects on the kinetics of hydride formation and growth in metals Souza,Angela C. diffusion-induced stress configurational forces hydrogen-storage systems phase transformation |
title_short |
Stress effects on the kinetics of hydride formation and growth in metals |
title_full |
Stress effects on the kinetics of hydride formation and growth in metals |
title_fullStr |
Stress effects on the kinetics of hydride formation and growth in metals |
title_full_unstemmed |
Stress effects on the kinetics of hydride formation and growth in metals |
title_sort |
Stress effects on the kinetics of hydride formation and growth in metals |
author |
Souza,Angela C. |
author_facet |
Souza,Angela C. Cruz,Antônio G.B. da Duda,Fernando P. |
author_role |
author |
author2 |
Cruz,Antônio G.B. da Duda,Fernando P. |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Souza,Angela C. Cruz,Antônio G.B. da Duda,Fernando P. |
dc.subject.por.fl_str_mv |
diffusion-induced stress configurational forces hydrogen-storage systems phase transformation |
topic |
diffusion-induced stress configurational forces hydrogen-storage systems phase transformation |
description |
Abstract Although metal hydrides are considered promising candidates for solid-state hydrogen storage, their use for practical applications remains a challenge due to the limitation imposed by the slow kinetics of hydrogen uptake and release, which has driven the interest in using metal nanoparticles as advanced materials of new hydrogen-storage systems since they display fast hydrogenation and dehydrogenation kinetics. Nevertheless, the understanding of the adsorption/release kinetics requires the investigation of the role played by the stress which appears to accommodate the misfit between the metal and hydride phases. In this paper, we present a continuum theory capable of assessing how the misfit stress affects the kinetics of hydride formation and growth in metallic nanoparticles. The theory is then applied to study the kinetics of adsorption/release in spherical particles. This work extends Duda and Tomassetti (2015, 2016) by considering stress-dependent hydrogen mobility. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1679-78252018001000704 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1679-78252018001000704 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1679-78254335 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Associação Brasileira de Ciências Mecânicas |
publisher.none.fl_str_mv |
Associação Brasileira de Ciências Mecânicas |
dc.source.none.fl_str_mv |
Latin American Journal of Solids and Structures v.15 n.10 2018 reponame:Latin American journal of solids and structures (Online) instname:Associação Brasileira de Engenharia e Ciências Mecânicas (ABCM) instacron:ABCM |
instname_str |
Associação Brasileira de Engenharia e Ciências Mecânicas (ABCM) |
instacron_str |
ABCM |
institution |
ABCM |
reponame_str |
Latin American journal of solids and structures (Online) |
collection |
Latin American journal of solids and structures (Online) |
repository.name.fl_str_mv |
Latin American journal of solids and structures (Online) - Associação Brasileira de Engenharia e Ciências Mecânicas (ABCM) |
repository.mail.fl_str_mv |
abcm@abcm.org.br||maralves@usp.br |
_version_ |
1754302889688301568 |