OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM
Autor(a) principal: | |
---|---|
Data de Publicação: | 2015 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Brazilian Journal of Chemical Engineering |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000200501 |
Resumo: | Abstract5-Hydroxymethylfurfural (HMF) is considered to be an important building block for biorefineries and has a high potential for the production of chemicals and fuels. Production of HMF from glucose was studied using phosphoric acid as catalyst, in a water:acetone system with volume ratio of 1:2 and NaCl. An experimental design was applied to examine the influence of temperature, time and concentration of catalyst on the HMF yield. HMF yields of more than 50 % were obtained when using 200 ºC, 8.4 min and 0.8% of catalyst. The temperature is the main factor influencing the HMF yield. |
id |
ABEQ-1_02270aef32f8883e194932f02e5ae559 |
---|---|
oai_identifier_str |
oai:scielo:S0104-66322015000200501 |
network_acronym_str |
ABEQ-1 |
network_name_str |
Brazilian Journal of Chemical Engineering |
repository_id_str |
|
spelling |
OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM5-hydroxymethylfurfuralGlucoseAcetoneDesign of experimentsAbstract5-Hydroxymethylfurfural (HMF) is considered to be an important building block for biorefineries and has a high potential for the production of chemicals and fuels. Production of HMF from glucose was studied using phosphoric acid as catalyst, in a water:acetone system with volume ratio of 1:2 and NaCl. An experimental design was applied to examine the influence of temperature, time and concentration of catalyst on the HMF yield. HMF yields of more than 50 % were obtained when using 200 ºC, 8.4 min and 0.8% of catalyst. The temperature is the main factor influencing the HMF yield.Brazilian Society of Chemical Engineering2015-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000200501Brazilian Journal of Chemical Engineering v.32 n.2 2015reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/0104-6632.20150322s00003048info:eu-repo/semantics/openAccessMendonça,A. D. M.Siqueira,P. M.Souza,M. M. V. M.Pereira Jr.,N.eng2015-10-08T00:00:00Zoai:scielo:S0104-66322015000200501Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2015-10-08T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false |
dc.title.none.fl_str_mv |
OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM |
title |
OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM |
spellingShingle |
OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM Mendonça,A. D. M. 5-hydroxymethylfurfural Glucose Acetone Design of experiments |
title_short |
OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM |
title_full |
OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM |
title_fullStr |
OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM |
title_full_unstemmed |
OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM |
title_sort |
OPTIMIZATION OF PRODUCTION OF 5-HYDROXYMETHYLFURFURAL FROM GLUCOSE IN A WATER: ACETONE BIPHASIC SYSTEM |
author |
Mendonça,A. D. M. |
author_facet |
Mendonça,A. D. M. Siqueira,P. M. Souza,M. M. V. M. Pereira Jr.,N. |
author_role |
author |
author2 |
Siqueira,P. M. Souza,M. M. V. M. Pereira Jr.,N. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Mendonça,A. D. M. Siqueira,P. M. Souza,M. M. V. M. Pereira Jr.,N. |
dc.subject.por.fl_str_mv |
5-hydroxymethylfurfural Glucose Acetone Design of experiments |
topic |
5-hydroxymethylfurfural Glucose Acetone Design of experiments |
description |
Abstract5-Hydroxymethylfurfural (HMF) is considered to be an important building block for biorefineries and has a high potential for the production of chemicals and fuels. Production of HMF from glucose was studied using phosphoric acid as catalyst, in a water:acetone system with volume ratio of 1:2 and NaCl. An experimental design was applied to examine the influence of temperature, time and concentration of catalyst on the HMF yield. HMF yields of more than 50 % were obtained when using 200 ºC, 8.4 min and 0.8% of catalyst. The temperature is the main factor influencing the HMF yield. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000200501 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000200501 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/0104-6632.20150322s00003048 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
dc.source.none.fl_str_mv |
Brazilian Journal of Chemical Engineering v.32 n.2 2015 reponame:Brazilian Journal of Chemical Engineering instname:Associação Brasileira de Engenharia Química (ABEQ) instacron:ABEQ |
instname_str |
Associação Brasileira de Engenharia Química (ABEQ) |
instacron_str |
ABEQ |
institution |
ABEQ |
reponame_str |
Brazilian Journal of Chemical Engineering |
collection |
Brazilian Journal of Chemical Engineering |
repository.name.fl_str_mv |
Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ) |
repository.mail.fl_str_mv |
rgiudici@usp.br||rgiudici@usp.br |
_version_ |
1754213174708535296 |