Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization
Autor(a) principal: | |
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Data de Publicação: | 2000 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Brazilian Journal of Chemical Engineering |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400004 |
Resumo: | Particle size distribution (PSD) of polystyrene particles produced by suspension polymerization is of fundamental importance in determining suspension stability and product quality attributes. Within a population balance framework, a model is proposed for suspension polymerization reactors to describe the evolution of the PSD. The model includes description of breakage and coalescence rates in terms of reaction kinetics and rheology of the dispersed phase. The model is validated with experimental data of styrene suspension polymerization. |
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Brazilian Journal of Chemical Engineering |
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Mathematical modeling of polystyrene particle size distribution produced by suspension polymerizationSuspension polymerizationparticle size distributionpopulation balancecoalescencebreakageParticle size distribution (PSD) of polystyrene particles produced by suspension polymerization is of fundamental importance in determining suspension stability and product quality attributes. Within a population balance framework, a model is proposed for suspension polymerization reactors to describe the evolution of the PSD. The model includes description of breakage and coalescence rates in terms of reaction kinetics and rheology of the dispersed phase. The model is validated with experimental data of styrene suspension polymerization.Brazilian Society of Chemical Engineering2000-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400004Brazilian Journal of Chemical Engineering v.17 n.4-7 2000reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/S0104-66322000000400004info:eu-repo/semantics/openAccessMachado,R.A.F.Pinto,J.C.Araújo,P.H.H.Bolzan,A.eng2001-03-16T00:00:00Zoai:scielo:S0104-66322000000400004Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2001-03-16T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false |
dc.title.none.fl_str_mv |
Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization |
title |
Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization |
spellingShingle |
Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization Machado,R.A.F. Suspension polymerization particle size distribution population balance coalescence breakage |
title_short |
Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization |
title_full |
Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization |
title_fullStr |
Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization |
title_full_unstemmed |
Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization |
title_sort |
Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization |
author |
Machado,R.A.F. |
author_facet |
Machado,R.A.F. Pinto,J.C. Araújo,P.H.H. Bolzan,A. |
author_role |
author |
author2 |
Pinto,J.C. Araújo,P.H.H. Bolzan,A. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Machado,R.A.F. Pinto,J.C. Araújo,P.H.H. Bolzan,A. |
dc.subject.por.fl_str_mv |
Suspension polymerization particle size distribution population balance coalescence breakage |
topic |
Suspension polymerization particle size distribution population balance coalescence breakage |
description |
Particle size distribution (PSD) of polystyrene particles produced by suspension polymerization is of fundamental importance in determining suspension stability and product quality attributes. Within a population balance framework, a model is proposed for suspension polymerization reactors to describe the evolution of the PSD. The model includes description of breakage and coalescence rates in terms of reaction kinetics and rheology of the dispersed phase. The model is validated with experimental data of styrene suspension polymerization. |
publishDate |
2000 |
dc.date.none.fl_str_mv |
2000-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400004 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400004 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0104-66322000000400004 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
dc.source.none.fl_str_mv |
Brazilian Journal of Chemical Engineering v.17 n.4-7 2000 reponame:Brazilian Journal of Chemical Engineering instname:Associação Brasileira de Engenharia Química (ABEQ) instacron:ABEQ |
instname_str |
Associação Brasileira de Engenharia Química (ABEQ) |
instacron_str |
ABEQ |
institution |
ABEQ |
reponame_str |
Brazilian Journal of Chemical Engineering |
collection |
Brazilian Journal of Chemical Engineering |
repository.name.fl_str_mv |
Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ) |
repository.mail.fl_str_mv |
rgiudici@usp.br||rgiudici@usp.br |
_version_ |
1754213170731286528 |