CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS

Detalhes bibliográficos
Autor(a) principal: Quiroga,A. González
Data de Publicação: 2015
Outros Autores: Silvera,A. Bula, Padilla,R. Vasquez, Costa,A. C. da, Maciel Filho,R.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Brazilian Journal of Chemical Engineering
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000400805
Resumo: Abstract An attractive operation strategy for the enzymatic hydrolysis of lignocellulosics results from dividing the process into three stages with complementary goals: continuous enzyme adsorption at low-solids loading (5% w/w) with recycling of the liquid phase; continuous liquefaction at high-solids content (up to 20% w/w); and, finally, continuous or semicontinuous hydrolysis with supplementation of fresh enzymes. This paper presents a detailed modeling and simulation framework for the aforementioned operation strategies. The limiting micromixing situations of macrofluid and microfluid are used to predict conversions. The adsorption and liquefaction stages are modeled as a continuous stirred tank and a plug flow reactor, respectively. Two alternatives for the third stage are studied: a train of five cascading stirred tanks and a battery of batch reactors in parallel. Simulation results show that glucose concentrations greater than 100 g L-1 could be reached with both of the alternatives for the third stage.
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spelling CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICSReactorHigh-solidsContinuousSemicontinuousMicromixingRecyclingAbstract An attractive operation strategy for the enzymatic hydrolysis of lignocellulosics results from dividing the process into three stages with complementary goals: continuous enzyme adsorption at low-solids loading (5% w/w) with recycling of the liquid phase; continuous liquefaction at high-solids content (up to 20% w/w); and, finally, continuous or semicontinuous hydrolysis with supplementation of fresh enzymes. This paper presents a detailed modeling and simulation framework for the aforementioned operation strategies. The limiting micromixing situations of macrofluid and microfluid are used to predict conversions. The adsorption and liquefaction stages are modeled as a continuous stirred tank and a plug flow reactor, respectively. Two alternatives for the third stage are studied: a train of five cascading stirred tanks and a battery of batch reactors in parallel. Simulation results show that glucose concentrations greater than 100 g L-1 could be reached with both of the alternatives for the third stage.Brazilian Society of Chemical Engineering2015-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000400805Brazilian Journal of Chemical Engineering v.32 n.4 2015reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/0104-6632.20150324s00003547info:eu-repo/semantics/openAccessQuiroga,A. GonzálezSilvera,A. BulaPadilla,R. VasquezCosta,A. C. daMaciel Filho,R.eng2016-03-14T00:00:00Zoai:scielo:S0104-66322015000400805Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2016-03-14T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false
dc.title.none.fl_str_mv CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS
title CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS
spellingShingle CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS
Quiroga,A. González
Reactor
High-solids
Continuous
Semicontinuous
Micromixing
Recycling
title_short CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS
title_full CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS
title_fullStr CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS
title_full_unstemmed CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS
title_sort CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS
author Quiroga,A. González
author_facet Quiroga,A. González
Silvera,A. Bula
Padilla,R. Vasquez
Costa,A. C. da
Maciel Filho,R.
author_role author
author2 Silvera,A. Bula
Padilla,R. Vasquez
Costa,A. C. da
Maciel Filho,R.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Quiroga,A. González
Silvera,A. Bula
Padilla,R. Vasquez
Costa,A. C. da
Maciel Filho,R.
dc.subject.por.fl_str_mv Reactor
High-solids
Continuous
Semicontinuous
Micromixing
Recycling
topic Reactor
High-solids
Continuous
Semicontinuous
Micromixing
Recycling
description Abstract An attractive operation strategy for the enzymatic hydrolysis of lignocellulosics results from dividing the process into three stages with complementary goals: continuous enzyme adsorption at low-solids loading (5% w/w) with recycling of the liquid phase; continuous liquefaction at high-solids content (up to 20% w/w); and, finally, continuous or semicontinuous hydrolysis with supplementation of fresh enzymes. This paper presents a detailed modeling and simulation framework for the aforementioned operation strategies. The limiting micromixing situations of macrofluid and microfluid are used to predict conversions. The adsorption and liquefaction stages are modeled as a continuous stirred tank and a plug flow reactor, respectively. Two alternatives for the third stage are studied: a train of five cascading stirred tanks and a battery of batch reactors in parallel. Simulation results show that glucose concentrations greater than 100 g L-1 could be reached with both of the alternatives for the third stage.
publishDate 2015
dc.date.none.fl_str_mv 2015-12-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000400805
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000400805
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0104-6632.20150324s00003547
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
dc.source.none.fl_str_mv Brazilian Journal of Chemical Engineering v.32 n.4 2015
reponame:Brazilian Journal of Chemical Engineering
instname:Associação Brasileira de Engenharia Química (ABEQ)
instacron:ABEQ
instname_str Associação Brasileira de Engenharia Química (ABEQ)
instacron_str ABEQ
institution ABEQ
reponame_str Brazilian Journal of Chemical Engineering
collection Brazilian Journal of Chemical Engineering
repository.name.fl_str_mv Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)
repository.mail.fl_str_mv rgiudici@usp.br||rgiudici@usp.br
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