Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theory
Autor(a) principal: | |
---|---|
Data de Publicação: | 2000 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Brazilian Journal of Chemical Engineering |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400040 |
Resumo: | A modified form of the Hicks and Young algorithm was used with the Mattedi-Tavares-Castier lattice equation of state (MTC lattice EOS) to calculate critical points of binary mixtures that exhibit several types of critical behavior. Several qualitative aspects of the critical curves, such as maxima and minima in critical pressure, and minima in critical temperature, could be predicted using the MTC lattice EOS. These results were in agreement with experimental information available in the literature, illustrating the flexibility of the functional form of the MTC lattice EOS. We observed however that the MTC lattice EOS failed to predict maxima in pressure for two of the studied systems: ethane + ethanol and methane + n-hexane. We also observed that the agreement between the calculated and experimental critical properties was at most semi-quantitative in some examples. Despite these limitations, in many ways similar to those of other EOS in common use when applied to critical point calculations, we can conclude that the MTC lattice EOS has the ability to predict several types of critical curves of complex shape. |
id |
ABEQ-1_9a33d866093eba254fd16a5a141914c2 |
---|---|
oai_identifier_str |
oai:scielo:S0104-66322000000400040 |
network_acronym_str |
ABEQ-1 |
network_name_str |
Brazilian Journal of Chemical Engineering |
repository_id_str |
|
spelling |
Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theorycritical pointsequations of statelatticesmixturesA modified form of the Hicks and Young algorithm was used with the Mattedi-Tavares-Castier lattice equation of state (MTC lattice EOS) to calculate critical points of binary mixtures that exhibit several types of critical behavior. Several qualitative aspects of the critical curves, such as maxima and minima in critical pressure, and minima in critical temperature, could be predicted using the MTC lattice EOS. These results were in agreement with experimental information available in the literature, illustrating the flexibility of the functional form of the MTC lattice EOS. We observed however that the MTC lattice EOS failed to predict maxima in pressure for two of the studied systems: ethane + ethanol and methane + n-hexane. We also observed that the agreement between the calculated and experimental critical properties was at most semi-quantitative in some examples. Despite these limitations, in many ways similar to those of other EOS in common use when applied to critical point calculations, we can conclude that the MTC lattice EOS has the ability to predict several types of critical curves of complex shape.Brazilian Society of Chemical Engineering2000-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400040Brazilian Journal of Chemical Engineering v.17 n.4-7 2000reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/S0104-66322000000400040info:eu-repo/semantics/openAccessMattedi,S.Tavares,F.W.Castier,M.eng2001-03-16T00:00:00Zoai:scielo:S0104-66322000000400040Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2001-03-16T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false |
dc.title.none.fl_str_mv |
Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theory |
title |
Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theory |
spellingShingle |
Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theory Mattedi,S. critical points equations of state lattices mixtures |
title_short |
Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theory |
title_full |
Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theory |
title_fullStr |
Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theory |
title_full_unstemmed |
Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theory |
title_sort |
Calculation of mixture critical diagrams using an equation of state based on the lattice fluid theory |
author |
Mattedi,S. |
author_facet |
Mattedi,S. Tavares,F.W. Castier,M. |
author_role |
author |
author2 |
Tavares,F.W. Castier,M. |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Mattedi,S. Tavares,F.W. Castier,M. |
dc.subject.por.fl_str_mv |
critical points equations of state lattices mixtures |
topic |
critical points equations of state lattices mixtures |
description |
A modified form of the Hicks and Young algorithm was used with the Mattedi-Tavares-Castier lattice equation of state (MTC lattice EOS) to calculate critical points of binary mixtures that exhibit several types of critical behavior. Several qualitative aspects of the critical curves, such as maxima and minima in critical pressure, and minima in critical temperature, could be predicted using the MTC lattice EOS. These results were in agreement with experimental information available in the literature, illustrating the flexibility of the functional form of the MTC lattice EOS. We observed however that the MTC lattice EOS failed to predict maxima in pressure for two of the studied systems: ethane + ethanol and methane + n-hexane. We also observed that the agreement between the calculated and experimental critical properties was at most semi-quantitative in some examples. Despite these limitations, in many ways similar to those of other EOS in common use when applied to critical point calculations, we can conclude that the MTC lattice EOS has the ability to predict several types of critical curves of complex shape. |
publishDate |
2000 |
dc.date.none.fl_str_mv |
2000-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400040 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400040 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0104-66322000000400040 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
dc.source.none.fl_str_mv |
Brazilian Journal of Chemical Engineering v.17 n.4-7 2000 reponame:Brazilian Journal of Chemical Engineering instname:Associação Brasileira de Engenharia Química (ABEQ) instacron:ABEQ |
instname_str |
Associação Brasileira de Engenharia Química (ABEQ) |
instacron_str |
ABEQ |
institution |
ABEQ |
reponame_str |
Brazilian Journal of Chemical Engineering |
collection |
Brazilian Journal of Chemical Engineering |
repository.name.fl_str_mv |
Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ) |
repository.mail.fl_str_mv |
rgiudici@usp.br||rgiudici@usp.br |
_version_ |
1754213170777423872 |