PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE

Detalhes bibliográficos
Autor(a) principal: Coppini,Mariane
Data de Publicação: 2019
Outros Autores: Magro,Jacir D., Martello,Rafael, Valério,Alexsandra, Zenevicz,Mara C., Oliveira,Débora de, Oliveira,José V.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Brazilian Journal of Chemical Engineering
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000200923
Resumo: Abstract The feedstock cost can comprise more than 75% of the overall biodiesel cost, and then economic issues are the main limitations of biodiesel production. This research focused on the use of alternative feedstock and production processes. The production of fatty acid esters from residues becomes an interesting alternative route since it is possible to reduce the cost of the process. The present work aimed to produce methyl esters from the residual oil of the poultry industry, using a commercial soluble lipase Eversa Transform 2.0® (NS-40116). The effects of methanol (1.2 to 1.8 eqv), water (1 to 2 wt%) and enzyme (0.1 to 0.5 wt%) contents on reaction conversion were evaluated through a 2³ experimental design with three central points, at 45 ºC, 250 rpm for 16 and 24 h of reaction time. From the results, by using 0.3 wt% enzyme, 1.5 wt% water, and 1.5 eqv of methanol it was possible to reach the most effective esters conversion (90.61%).
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spelling PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUEAgroindustryFAMEHydroesterificationEnzymeChicken fatAbstract The feedstock cost can comprise more than 75% of the overall biodiesel cost, and then economic issues are the main limitations of biodiesel production. This research focused on the use of alternative feedstock and production processes. The production of fatty acid esters from residues becomes an interesting alternative route since it is possible to reduce the cost of the process. The present work aimed to produce methyl esters from the residual oil of the poultry industry, using a commercial soluble lipase Eversa Transform 2.0® (NS-40116). The effects of methanol (1.2 to 1.8 eqv), water (1 to 2 wt%) and enzyme (0.1 to 0.5 wt%) contents on reaction conversion were evaluated through a 2³ experimental design with three central points, at 45 ºC, 250 rpm for 16 and 24 h of reaction time. From the results, by using 0.3 wt% enzyme, 1.5 wt% water, and 1.5 eqv of methanol it was possible to reach the most effective esters conversion (90.61%).Brazilian Society of Chemical Engineering2019-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000200923Brazilian Journal of Chemical Engineering v.36 n.2 2019reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/0104-6632.20190362s20180389info:eu-repo/semantics/openAccessCoppini,MarianeMagro,Jacir D.Martello,RafaelValério,AlexsandraZenevicz,Mara C.Oliveira,Débora deOliveira,José V.eng2019-09-25T00:00:00Zoai:scielo:S0104-66322019000200923Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2019-09-25T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false
dc.title.none.fl_str_mv PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE
title PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE
spellingShingle PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE
Coppini,Mariane
Agroindustry
FAME
Hydroesterification
Enzyme
Chicken fat
title_short PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE
title_full PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE
title_fullStr PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE
title_full_unstemmed PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE
title_sort PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE
author Coppini,Mariane
author_facet Coppini,Mariane
Magro,Jacir D.
Martello,Rafael
Valério,Alexsandra
Zenevicz,Mara C.
Oliveira,Débora de
Oliveira,José V.
author_role author
author2 Magro,Jacir D.
Martello,Rafael
Valério,Alexsandra
Zenevicz,Mara C.
Oliveira,Débora de
Oliveira,José V.
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Coppini,Mariane
Magro,Jacir D.
Martello,Rafael
Valério,Alexsandra
Zenevicz,Mara C.
Oliveira,Débora de
Oliveira,José V.
dc.subject.por.fl_str_mv Agroindustry
FAME
Hydroesterification
Enzyme
Chicken fat
topic Agroindustry
FAME
Hydroesterification
Enzyme
Chicken fat
description Abstract The feedstock cost can comprise more than 75% of the overall biodiesel cost, and then economic issues are the main limitations of biodiesel production. This research focused on the use of alternative feedstock and production processes. The production of fatty acid esters from residues becomes an interesting alternative route since it is possible to reduce the cost of the process. The present work aimed to produce methyl esters from the residual oil of the poultry industry, using a commercial soluble lipase Eversa Transform 2.0® (NS-40116). The effects of methanol (1.2 to 1.8 eqv), water (1 to 2 wt%) and enzyme (0.1 to 0.5 wt%) contents on reaction conversion were evaluated through a 2³ experimental design with three central points, at 45 ºC, 250 rpm for 16 and 24 h of reaction time. From the results, by using 0.3 wt% enzyme, 1.5 wt% water, and 1.5 eqv of methanol it was possible to reach the most effective esters conversion (90.61%).
publishDate 2019
dc.date.none.fl_str_mv 2019-06-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000200923
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000200923
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0104-6632.20190362s20180389
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
dc.source.none.fl_str_mv Brazilian Journal of Chemical Engineering v.36 n.2 2019
reponame:Brazilian Journal of Chemical Engineering
instname:Associação Brasileira de Engenharia Química (ABEQ)
instacron:ABEQ
instname_str Associação Brasileira de Engenharia Química (ABEQ)
instacron_str ABEQ
institution ABEQ
reponame_str Brazilian Journal of Chemical Engineering
collection Brazilian Journal of Chemical Engineering
repository.name.fl_str_mv Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)
repository.mail.fl_str_mv rgiudici@usp.br||rgiudici@usp.br
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