Moisture sorption characteristics of microalgae Spirulina platensis

Detalhes bibliográficos
Autor(a) principal: Oliveira,E. G.
Data de Publicação: 2009
Outros Autores: Rosa,G. S., Moraes,M. A., Pinto,L. A. A.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Brazilian Journal of Chemical Engineering
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322009000100018
Resumo: In recent times, the microalgae Spirulina platensis has been used as a functional ingredient in several food applications; its process involving drying and storage steps. Moisture equilibrium data for adsorption isotherms of microalgae Spirulina were investigated at 10, 20 and 30ºC and for desorption, at 40, 50 and 60ºC, using the gravimetric static method. The experimental data were analyzed by GAB and BET models. The GAB equation showed the best fitting to the experimental data with R² ≈ 99% and MRE < 10%. The water surface area values calculated by GAB and BET models were very similar. The isosteric heats were determined by application of Clausius-Clapeyron equation to sorption isotherms obtained from the best-fitting equation. The isosteric heat and the entropy of desorption isotherm presented similar behavior, with a sharp change in an equilibrium moisture content of 10%. The enthalpy-entropy compensation theory was applied to the isotherms, indicating that they are enthalpy-controlled.
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spelling Moisture sorption characteristics of microalgae Spirulina platensisSpirulina platensisEquilibrium isothermsHeat of sorptionDifferential entropyIn recent times, the microalgae Spirulina platensis has been used as a functional ingredient in several food applications; its process involving drying and storage steps. Moisture equilibrium data for adsorption isotherms of microalgae Spirulina were investigated at 10, 20 and 30ºC and for desorption, at 40, 50 and 60ºC, using the gravimetric static method. The experimental data were analyzed by GAB and BET models. The GAB equation showed the best fitting to the experimental data with R² ≈ 99% and MRE < 10%. The water surface area values calculated by GAB and BET models were very similar. The isosteric heats were determined by application of Clausius-Clapeyron equation to sorption isotherms obtained from the best-fitting equation. The isosteric heat and the entropy of desorption isotherm presented similar behavior, with a sharp change in an equilibrium moisture content of 10%. The enthalpy-entropy compensation theory was applied to the isotherms, indicating that they are enthalpy-controlled.Brazilian Society of Chemical Engineering2009-03-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322009000100018Brazilian Journal of Chemical Engineering v.26 n.1 2009reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/S0104-66322009000100018info:eu-repo/semantics/openAccessOliveira,E. G.Rosa,G. S.Moraes,M. A.Pinto,L. A. A.eng2009-03-10T00:00:00Zoai:scielo:S0104-66322009000100018Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2009-03-10T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false
dc.title.none.fl_str_mv Moisture sorption characteristics of microalgae Spirulina platensis
title Moisture sorption characteristics of microalgae Spirulina platensis
spellingShingle Moisture sorption characteristics of microalgae Spirulina platensis
Oliveira,E. G.
Spirulina platensis
Equilibrium isotherms
Heat of sorption
Differential entropy
title_short Moisture sorption characteristics of microalgae Spirulina platensis
title_full Moisture sorption characteristics of microalgae Spirulina platensis
title_fullStr Moisture sorption characteristics of microalgae Spirulina platensis
title_full_unstemmed Moisture sorption characteristics of microalgae Spirulina platensis
title_sort Moisture sorption characteristics of microalgae Spirulina platensis
author Oliveira,E. G.
author_facet Oliveira,E. G.
Rosa,G. S.
Moraes,M. A.
Pinto,L. A. A.
author_role author
author2 Rosa,G. S.
Moraes,M. A.
Pinto,L. A. A.
author2_role author
author
author
dc.contributor.author.fl_str_mv Oliveira,E. G.
Rosa,G. S.
Moraes,M. A.
Pinto,L. A. A.
dc.subject.por.fl_str_mv Spirulina platensis
Equilibrium isotherms
Heat of sorption
Differential entropy
topic Spirulina platensis
Equilibrium isotherms
Heat of sorption
Differential entropy
description In recent times, the microalgae Spirulina platensis has been used as a functional ingredient in several food applications; its process involving drying and storage steps. Moisture equilibrium data for adsorption isotherms of microalgae Spirulina were investigated at 10, 20 and 30ºC and for desorption, at 40, 50 and 60ºC, using the gravimetric static method. The experimental data were analyzed by GAB and BET models. The GAB equation showed the best fitting to the experimental data with R² ≈ 99% and MRE < 10%. The water surface area values calculated by GAB and BET models were very similar. The isosteric heats were determined by application of Clausius-Clapeyron equation to sorption isotherms obtained from the best-fitting equation. The isosteric heat and the entropy of desorption isotherm presented similar behavior, with a sharp change in an equilibrium moisture content of 10%. The enthalpy-entropy compensation theory was applied to the isotherms, indicating that they are enthalpy-controlled.
publishDate 2009
dc.date.none.fl_str_mv 2009-03-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322009000100018
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322009000100018
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0104-66322009000100018
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
dc.source.none.fl_str_mv Brazilian Journal of Chemical Engineering v.26 n.1 2009
reponame:Brazilian Journal of Chemical Engineering
instname:Associação Brasileira de Engenharia Química (ABEQ)
instacron:ABEQ
instname_str Associação Brasileira de Engenharia Química (ABEQ)
instacron_str ABEQ
institution ABEQ
reponame_str Brazilian Journal of Chemical Engineering
collection Brazilian Journal of Chemical Engineering
repository.name.fl_str_mv Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)
repository.mail.fl_str_mv rgiudici@usp.br||rgiudici@usp.br
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