REMOVAL OF NITRATE FROM DRINKING WATER BY USING PdCu STRUCTURED CATALYSTS BASED ON CORDIERITE MONOLITHS

• Autor(a) principal: Jaworski,María A.
• Data de Publicação: 2019
• Outros Autores: Barbero,Bibiana P., Siri,Guillermo J., Casella,Mónica L.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Brazilian Journal of Chemical Engineering
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000200705
• topic: Water pollution; Nitrate; Cordierite monoliths; PdCu catalyst; Structured catalyst

Abstract Structured catalysts were prepared, characterized and evaluated in NO3 - removal from drinking water. Different suspensions containing a previously optimized PdCu/5wt% ZrO2-Al2O3 powder catalyst (hereinafter PdCu/5ZAp) were prepared and deposited on cordierite monoliths by washcoating. The effect of suspension concentration, the particle size, the immersion number, the use of suspension stabilizer agent, and an alumina pre-coating on the coating adherence and catalytic performance were studied. All the prepared structured catalysts were active for the elimination of NO3 - and presented good selectivity to N2 (> 93%) in synthetic water samples. The catalyst performance was related to the amount of deposited catalyst. The highest activity and the best coating adherence were obtained with the structured catalyst prepared by a single immersion in a 14 wt% concentration suspension, which was obtained from the powder catalyst milled for 10 h and stabilized with colloidal alumina. This catalyst also showed good activity when it was reused for four cycles and when it was evaluated with real water samples.