Drying and shrinkage of polymer gels

• Autor(a) principal: Waje,S. S.
• Data de Publicação: 2005
• Outros Autores: Meshram,M. W., Chaudhary,V., Pandey,R., Mahanawar,P. A., Thorat,B. N.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Brazilian Journal of Chemical Engineering
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322005000200007
• topic: Polymer gel; Drying characteristics; Diffusion coefficient; Modified gel thickness; Contraction coefficient

The polymer hydrogel was synthesized by photo-polymerization process (UV light, 60 ºC) in presence of Photo-initiator (IrgacureR) and Cross-linker (NN'-methylene bisacrylamide; MBAM). In the present work, the drying of polymer hydrogel was carried out to study the effect of temperature, gel-sheet thickness, monomer ratio of acryl acid to acrylamide (AA/AM), concentration of MBAM and quantity of monomers. A correlation has been developed for modified sheet thickness as a function of contraction coefficient and degree of drying. Effective diffusivity was estimated from Fickian-diffusive model considering modified sheet thickness and was found to be in the range of 1.1 <FONT FACE=Symbol>´</FONT> 10-10-5.93 <FONT FACE=Symbol>´</FONT> 10-10 m²/s. The activation energy obtained using Arrhenius type equation was found to be in the range of 2979-10737 kJ/kmol H2O. The drying behavior shows an initial shoot-up in drying rate followed by constant rate and two falling rate periods.