Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic Activity
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000300619 |
Resumo: | The visible light driven BiPO4 nanocubes with sufficient surface oxygen deficiency were fabricated by a hydrothermal process and subsequently ultrasonic assistant Fe reduction process. The products were characterized by XRD, DRS, XPS, SEM and TEM which showed that the BiPO4 had cuboid-like shape with a smooth surface and clear edges and the oxygen vacancies were succesfully introduced on the surface of the BiPO4 nanocubes. The as prepared oxygen-deficient BiPO4 nanocubes showed greatly enhanced visible light induced photocatalytic activity in degradation of Rhodamine B. The enhanced photocatalytic performance and expanded visible light response of BiPO4 may be due to the introduction of surface oxygen vacancies which can generate the oxygen vacancies mid-gap states lower to the conduction band of BiPO4. |
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Materials research (São Carlos. Online) |
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Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic ActivityBiPO4NanocubesPhotocatalysisOxygen vacancyThe visible light driven BiPO4 nanocubes with sufficient surface oxygen deficiency were fabricated by a hydrothermal process and subsequently ultrasonic assistant Fe reduction process. The products were characterized by XRD, DRS, XPS, SEM and TEM which showed that the BiPO4 had cuboid-like shape with a smooth surface and clear edges and the oxygen vacancies were succesfully introduced on the surface of the BiPO4 nanocubes. The as prepared oxygen-deficient BiPO4 nanocubes showed greatly enhanced visible light induced photocatalytic activity in degradation of Rhodamine B. The enhanced photocatalytic performance and expanded visible light response of BiPO4 may be due to the introduction of surface oxygen vacancies which can generate the oxygen vacancies mid-gap states lower to the conduction band of BiPO4.ABM, ABC, ABPol2017-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000300619Materials Research v.20 n.3 2017reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2016-0569info:eu-repo/semantics/openAccessShi,BingtaoYin,HaoyongLi,TaoGong,JianyingLv,ShumeiNie,Qiulineng2017-06-23T00:00:00Zoai:scielo:S1516-14392017000300619Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2017-06-23T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic Activity |
title |
Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic Activity |
spellingShingle |
Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic Activity Shi,Bingtao BiPO4 Nanocubes Photocatalysis Oxygen vacancy |
title_short |
Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic Activity |
title_full |
Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic Activity |
title_fullStr |
Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic Activity |
title_full_unstemmed |
Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic Activity |
title_sort |
Synthesis of Surface Oxygen-deficient BiPO4 Nanocubes with Enhanced Visible Light Induced Photocatalytic Activity |
author |
Shi,Bingtao |
author_facet |
Shi,Bingtao Yin,Haoyong Li,Tao Gong,Jianying Lv,Shumei Nie,Qiulin |
author_role |
author |
author2 |
Yin,Haoyong Li,Tao Gong,Jianying Lv,Shumei Nie,Qiulin |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Shi,Bingtao Yin,Haoyong Li,Tao Gong,Jianying Lv,Shumei Nie,Qiulin |
dc.subject.por.fl_str_mv |
BiPO4 Nanocubes Photocatalysis Oxygen vacancy |
topic |
BiPO4 Nanocubes Photocatalysis Oxygen vacancy |
description |
The visible light driven BiPO4 nanocubes with sufficient surface oxygen deficiency were fabricated by a hydrothermal process and subsequently ultrasonic assistant Fe reduction process. The products were characterized by XRD, DRS, XPS, SEM and TEM which showed that the BiPO4 had cuboid-like shape with a smooth surface and clear edges and the oxygen vacancies were succesfully introduced on the surface of the BiPO4 nanocubes. The as prepared oxygen-deficient BiPO4 nanocubes showed greatly enhanced visible light induced photocatalytic activity in degradation of Rhodamine B. The enhanced photocatalytic performance and expanded visible light response of BiPO4 may be due to the introduction of surface oxygen vacancies which can generate the oxygen vacancies mid-gap states lower to the conduction band of BiPO4. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000300619 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000300619 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2016-0569 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.20 n.3 2017 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212670658052096 |