Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ Semiconductor

Detalhes bibliográficos
Autor(a) principal: Gomes,L. P. V.
Data de Publicação: 2020
Outros Autores: Pedro,S. S., López,A., Camara,A. R., Cella,N., Sosman,L. P.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000300214
Resumo: This work presents the investigation, at room temperature, of Zn2TiO4samples containing Ni2+ ions as substitutional impurities. Samples with molecular formula Zn2(1-x)Ni2xTiO4, where x = 0.00, 0.0007, 0.001, 0.0013, 0.002 and 0.003, in which Zn2+ ions were replaced by Ni2+ ions, were prepared through solid-state method, crystalline data were obtained by X-ray diffraction, the elemental composition was determined by X-ray fluorescence and the optical properties were investigated through photoluminescence and photoacoustic techniques. The photoluminescence spectra showed broadbands from 640 nm to 800 nm. The emission of the Zn2(1-x)Ni2xTiO4 samples was assigned to the overlapping of the Ni2+and the Zn2TiO4 emission. The most intense photoluminescence signal was obtained with excitation radiation at a wavelength of 360 nm for the sample with x = 0.001. The photoacoustic spectra showed absorption bands characteristic of semiconductor materials due to the host Zn2TiO4. The energy bandgap of the Zn2(1-x)Ni2xTiO4was obtained from photoacoustic absorption spectra.
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spelling Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ SemiconductorPhotoluminescence, photoacousticNi2+semiconductor materialThis work presents the investigation, at room temperature, of Zn2TiO4samples containing Ni2+ ions as substitutional impurities. Samples with molecular formula Zn2(1-x)Ni2xTiO4, where x = 0.00, 0.0007, 0.001, 0.0013, 0.002 and 0.003, in which Zn2+ ions were replaced by Ni2+ ions, were prepared through solid-state method, crystalline data were obtained by X-ray diffraction, the elemental composition was determined by X-ray fluorescence and the optical properties were investigated through photoluminescence and photoacoustic techniques. The photoluminescence spectra showed broadbands from 640 nm to 800 nm. The emission of the Zn2(1-x)Ni2xTiO4 samples was assigned to the overlapping of the Ni2+and the Zn2TiO4 emission. The most intense photoluminescence signal was obtained with excitation radiation at a wavelength of 360 nm for the sample with x = 0.001. The photoacoustic spectra showed absorption bands characteristic of semiconductor materials due to the host Zn2TiO4. The energy bandgap of the Zn2(1-x)Ni2xTiO4was obtained from photoacoustic absorption spectra.ABM, ABC, ABPol2020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000300214Materials Research v.23 n.3 2020reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2020-0061info:eu-repo/semantics/openAccessGomes,L. P. V.Pedro,S. S.López,A.Camara,A. R.Cella,N.Sosman,L. P.eng2020-07-10T00:00:00Zoai:scielo:S1516-14392020000300214Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2020-07-10T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ Semiconductor
title Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ Semiconductor
spellingShingle Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ Semiconductor
Gomes,L. P. V.
Photoluminescence, photoacoustic
Ni2+
semiconductor material
title_short Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ Semiconductor
title_full Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ Semiconductor
title_fullStr Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ Semiconductor
title_full_unstemmed Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ Semiconductor
title_sort Photoluminescence, Photoacoustic and Structural Characteristics of Polycrystalline Zn2TiO4: Ni2+ Semiconductor
author Gomes,L. P. V.
author_facet Gomes,L. P. V.
Pedro,S. S.
López,A.
Camara,A. R.
Cella,N.
Sosman,L. P.
author_role author
author2 Pedro,S. S.
López,A.
Camara,A. R.
Cella,N.
Sosman,L. P.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Gomes,L. P. V.
Pedro,S. S.
López,A.
Camara,A. R.
Cella,N.
Sosman,L. P.
dc.subject.por.fl_str_mv Photoluminescence, photoacoustic
Ni2+
semiconductor material
topic Photoluminescence, photoacoustic
Ni2+
semiconductor material
description This work presents the investigation, at room temperature, of Zn2TiO4samples containing Ni2+ ions as substitutional impurities. Samples with molecular formula Zn2(1-x)Ni2xTiO4, where x = 0.00, 0.0007, 0.001, 0.0013, 0.002 and 0.003, in which Zn2+ ions were replaced by Ni2+ ions, were prepared through solid-state method, crystalline data were obtained by X-ray diffraction, the elemental composition was determined by X-ray fluorescence and the optical properties were investigated through photoluminescence and photoacoustic techniques. The photoluminescence spectra showed broadbands from 640 nm to 800 nm. The emission of the Zn2(1-x)Ni2xTiO4 samples was assigned to the overlapping of the Ni2+and the Zn2TiO4 emission. The most intense photoluminescence signal was obtained with excitation radiation at a wavelength of 360 nm for the sample with x = 0.001. The photoacoustic spectra showed absorption bands characteristic of semiconductor materials due to the host Zn2TiO4. The energy bandgap of the Zn2(1-x)Ni2xTiO4was obtained from photoacoustic absorption spectra.
publishDate 2020
dc.date.none.fl_str_mv 2020-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000300214
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000300214
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/1980-5373-mr-2020-0061
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.23 n.3 2020
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
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