Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties

Detalhes bibliográficos
Autor(a) principal: Mungkalodom,Patcharin
Data de Publicação: 2015
Outros Autores: Paradee,Nophawan, Sirivat,Anuvat, Hormnirun,Pimpa
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392015000400669
Resumo: Poly(2,5-dimethoxyaniline) (PDMA) was synthesized using electrochemical polymerization of DMA in oxalic acid. The PDMA film coated onto ITO glass was studied for its chemical structure, morphology, electro-deposition, and electro-activity by FT-IR, TGA, SEM, cyclic voltammetry, and UV-Vis spectrophotometry. The PDMA film showed reversible color changes from yellow to blue representing the transition between the fully reduced state to the fully oxidized state upon switching the potentials. The response time of the PDMA film in term of color change was investigated under various applied potentials and different types of acid electrolyte (HCl and H2SO4). The fast response time of less than 2 sec was observed at the applied potential of 1.6 V. In comparison with HCl, the use of H2SO4 as an electrolyte resulted in the fastest response time. Thus, the PDMA is a potential candidate in electrochromic devices due to its reversible color change and fast response time.
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spelling Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Propertieselectrochromic polymerPoly(2,5–dimethoxyaniline)electrochemical polymerizationresponse timePoly(2,5-dimethoxyaniline) (PDMA) was synthesized using electrochemical polymerization of DMA in oxalic acid. The PDMA film coated onto ITO glass was studied for its chemical structure, morphology, electro-deposition, and electro-activity by FT-IR, TGA, SEM, cyclic voltammetry, and UV-Vis spectrophotometry. The PDMA film showed reversible color changes from yellow to blue representing the transition between the fully reduced state to the fully oxidized state upon switching the potentials. The response time of the PDMA film in term of color change was investigated under various applied potentials and different types of acid electrolyte (HCl and H2SO4). The fast response time of less than 2 sec was observed at the applied potential of 1.6 V. In comparison with HCl, the use of H2SO4 as an electrolyte resulted in the fastest response time. Thus, the PDMA is a potential candidate in electrochromic devices due to its reversible color change and fast response time.ABM, ABC, ABPol2015-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392015000400669Materials Research v.18 n.4 2015reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1516-1439.235513info:eu-repo/semantics/openAccessMungkalodom,PatcharinParadee,NophawanSirivat,AnuvatHormnirun,Pimpaeng2017-07-18T00:00:00Zoai:scielo:S1516-14392015000400669Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2017-07-18T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
title Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
spellingShingle Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
Mungkalodom,Patcharin
electrochromic polymer
Poly(2,5–dimethoxyaniline)
electrochemical polymerization
response time
title_short Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
title_full Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
title_fullStr Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
title_full_unstemmed Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
title_sort Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
author Mungkalodom,Patcharin
author_facet Mungkalodom,Patcharin
Paradee,Nophawan
Sirivat,Anuvat
Hormnirun,Pimpa
author_role author
author2 Paradee,Nophawan
Sirivat,Anuvat
Hormnirun,Pimpa
author2_role author
author
author
dc.contributor.author.fl_str_mv Mungkalodom,Patcharin
Paradee,Nophawan
Sirivat,Anuvat
Hormnirun,Pimpa
dc.subject.por.fl_str_mv electrochromic polymer
Poly(2,5–dimethoxyaniline)
electrochemical polymerization
response time
topic electrochromic polymer
Poly(2,5–dimethoxyaniline)
electrochemical polymerization
response time
description Poly(2,5-dimethoxyaniline) (PDMA) was synthesized using electrochemical polymerization of DMA in oxalic acid. The PDMA film coated onto ITO glass was studied for its chemical structure, morphology, electro-deposition, and electro-activity by FT-IR, TGA, SEM, cyclic voltammetry, and UV-Vis spectrophotometry. The PDMA film showed reversible color changes from yellow to blue representing the transition between the fully reduced state to the fully oxidized state upon switching the potentials. The response time of the PDMA film in term of color change was investigated under various applied potentials and different types of acid electrolyte (HCl and H2SO4). The fast response time of less than 2 sec was observed at the applied potential of 1.6 V. In comparison with HCl, the use of H2SO4 as an electrolyte resulted in the fastest response time. Thus, the PDMA is a potential candidate in electrochromic devices due to its reversible color change and fast response time.
publishDate 2015
dc.date.none.fl_str_mv 2015-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392015000400669
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392015000400669
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/1516-1439.235513
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.18 n.4 2015
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
_version_ 1754212666638860288

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