Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline Solution
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000500221 |
Resumo: | The effect of the increase in crystalline defects in the structure generated by high-pressure torsion (HPT) on the corrosion behavior of metallic materials is not well understood. This report evaluates the influence of HPT on the corrosion behavior of a solution treated Al-3wt% Mg-0.2wt% Sc alloy in a 3.5 wt./v.% NaCl solution. The electrochemical behavior of the alloy was evaluated using cyclic polarization, electrochemical impedance spectroscopy (EIS), Mott Schottky, X-ray photoelectron spectroscopy, and chronoamperometry testing. The passive current density decreased after HPT processing, indicating a more protective oxide layer was formed on the surface of the HPT-processed alloy. Mott Schottky analysis confirmed the higher protection efficiency of the passive layer on the HPT-processed alloy. The film formed in the solution-treated alloy was a p-type and an n-type semiconductor while the alloy processed by HPT exhibited only an n-type semiconductor behavior. EIS showed that corrosion resistance in a saline medium increased with HPT processing. |
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Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline SolutionAluminum alloycorrosionhigh-pressure torsionultrafine microstructureThe effect of the increase in crystalline defects in the structure generated by high-pressure torsion (HPT) on the corrosion behavior of metallic materials is not well understood. This report evaluates the influence of HPT on the corrosion behavior of a solution treated Al-3wt% Mg-0.2wt% Sc alloy in a 3.5 wt./v.% NaCl solution. The electrochemical behavior of the alloy was evaluated using cyclic polarization, electrochemical impedance spectroscopy (EIS), Mott Schottky, X-ray photoelectron spectroscopy, and chronoamperometry testing. The passive current density decreased after HPT processing, indicating a more protective oxide layer was formed on the surface of the HPT-processed alloy. Mott Schottky analysis confirmed the higher protection efficiency of the passive layer on the HPT-processed alloy. The film formed in the solution-treated alloy was a p-type and an n-type semiconductor while the alloy processed by HPT exhibited only an n-type semiconductor behavior. EIS showed that corrosion resistance in a saline medium increased with HPT processing.ABM, ABC, ABPol2019-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000500221Materials Research v.22 n.5 2019reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2019-0343info:eu-repo/semantics/openAccessLage,Michelle Dias AlvesSoares,Renata BragaPereira,Pedro Henrique R.Figueiredo,Roberto B.Lins,Vanessa Freitas C.Langdon,Terence G.eng2019-11-01T00:00:00Zoai:scielo:S1516-14392019000500221Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2019-11-01T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline Solution |
title |
Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline Solution |
spellingShingle |
Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline Solution Lage,Michelle Dias Alves Aluminum alloy corrosion high-pressure torsion ultrafine microstructure |
title_short |
Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline Solution |
title_full |
Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline Solution |
title_fullStr |
Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline Solution |
title_full_unstemmed |
Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline Solution |
title_sort |
Effect of High-pressure Torsion on Corrosion Behavior of a Solution-treated Al-Mg-Sc Alloy in a Saline Solution |
author |
Lage,Michelle Dias Alves |
author_facet |
Lage,Michelle Dias Alves Soares,Renata Braga Pereira,Pedro Henrique R. Figueiredo,Roberto B. Lins,Vanessa Freitas C. Langdon,Terence G. |
author_role |
author |
author2 |
Soares,Renata Braga Pereira,Pedro Henrique R. Figueiredo,Roberto B. Lins,Vanessa Freitas C. Langdon,Terence G. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Lage,Michelle Dias Alves Soares,Renata Braga Pereira,Pedro Henrique R. Figueiredo,Roberto B. Lins,Vanessa Freitas C. Langdon,Terence G. |
dc.subject.por.fl_str_mv |
Aluminum alloy corrosion high-pressure torsion ultrafine microstructure |
topic |
Aluminum alloy corrosion high-pressure torsion ultrafine microstructure |
description |
The effect of the increase in crystalline defects in the structure generated by high-pressure torsion (HPT) on the corrosion behavior of metallic materials is not well understood. This report evaluates the influence of HPT on the corrosion behavior of a solution treated Al-3wt% Mg-0.2wt% Sc alloy in a 3.5 wt./v.% NaCl solution. The electrochemical behavior of the alloy was evaluated using cyclic polarization, electrochemical impedance spectroscopy (EIS), Mott Schottky, X-ray photoelectron spectroscopy, and chronoamperometry testing. The passive current density decreased after HPT processing, indicating a more protective oxide layer was formed on the surface of the HPT-processed alloy. Mott Schottky analysis confirmed the higher protection efficiency of the passive layer on the HPT-processed alloy. The film formed in the solution-treated alloy was a p-type and an n-type semiconductor while the alloy processed by HPT exhibited only an n-type semiconductor behavior. EIS showed that corrosion resistance in a saline medium increased with HPT processing. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000500221 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000500221 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2019-0343 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.22 n.5 2019 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212675379789824 |