Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous medium
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000600023 |
Resumo: | Pure zirconium oxide (ZrO2) nanoparticles with diameters 10-25 nm were synthesized from ZrOCl2.8H2O and Zr(SO4)2.H2O with benzyl alcohol as non-aqueous solvent medium using sol-gel method. Sodium lauryl sulfate was added as surfactants to control the particle size. The synthesized ZrO2 nanoparticles have a mixture of tetragonal and monoclinic structure. The XRD showed the purity of obtained ZrO2 nanoparticles with tetragonal and monoclinic phase and the crystallite size for ZrOCl2.8H2O precursor was estimated to be 18.1 nm and that from Zr(SO4)2.H2O was 9.7 nm. The transmission electron microscopy and scanning electron microscopic studies also shows different sizes of nanoparticles and different morphology depending on the precursor used for the synthesis of ZrO2 nanoparticles |
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Materials research (São Carlos. Online) |
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Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous mediumzirconiananoparticleselectron microscopyprecursormorphologyPure zirconium oxide (ZrO2) nanoparticles with diameters 10-25 nm were synthesized from ZrOCl2.8H2O and Zr(SO4)2.H2O with benzyl alcohol as non-aqueous solvent medium using sol-gel method. Sodium lauryl sulfate was added as surfactants to control the particle size. The synthesized ZrO2 nanoparticles have a mixture of tetragonal and monoclinic structure. The XRD showed the purity of obtained ZrO2 nanoparticles with tetragonal and monoclinic phase and the crystallite size for ZrOCl2.8H2O precursor was estimated to be 18.1 nm and that from Zr(SO4)2.H2O was 9.7 nm. The transmission electron microscopy and scanning electron microscopic studies also shows different sizes of nanoparticles and different morphology depending on the precursor used for the synthesis of ZrO2 nanoparticlesABM, ABC, ABPol2012-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000600023Materials Research v.15 n.6 2012reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392012005000128info:eu-repo/semantics/openAccessSiddiqui,Mohammed Rafiq HussainAl-Wassil,Abdulaziz IbrahimAl-Otaibi,Abdullah MohmmedMahfouz,Refaat Mohamadeng2012-11-20T00:00:00Zoai:scielo:S1516-14392012000600023Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2012-11-20T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous medium |
title |
Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous medium |
spellingShingle |
Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous medium Siddiqui,Mohammed Rafiq Hussain zirconia nanoparticles electron microscopy precursor morphology |
title_short |
Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous medium |
title_full |
Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous medium |
title_fullStr |
Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous medium |
title_full_unstemmed |
Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous medium |
title_sort |
Effects of precursor on the morphology and size of ZrO2 nanoparticles, synthesized by sol-gel method in non-aqueous medium |
author |
Siddiqui,Mohammed Rafiq Hussain |
author_facet |
Siddiqui,Mohammed Rafiq Hussain Al-Wassil,Abdulaziz Ibrahim Al-Otaibi,Abdullah Mohmmed Mahfouz,Refaat Mohamad |
author_role |
author |
author2 |
Al-Wassil,Abdulaziz Ibrahim Al-Otaibi,Abdullah Mohmmed Mahfouz,Refaat Mohamad |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Siddiqui,Mohammed Rafiq Hussain Al-Wassil,Abdulaziz Ibrahim Al-Otaibi,Abdullah Mohmmed Mahfouz,Refaat Mohamad |
dc.subject.por.fl_str_mv |
zirconia nanoparticles electron microscopy precursor morphology |
topic |
zirconia nanoparticles electron microscopy precursor morphology |
description |
Pure zirconium oxide (ZrO2) nanoparticles with diameters 10-25 nm were synthesized from ZrOCl2.8H2O and Zr(SO4)2.H2O with benzyl alcohol as non-aqueous solvent medium using sol-gel method. Sodium lauryl sulfate was added as surfactants to control the particle size. The synthesized ZrO2 nanoparticles have a mixture of tetragonal and monoclinic structure. The XRD showed the purity of obtained ZrO2 nanoparticles with tetragonal and monoclinic phase and the crystallite size for ZrOCl2.8H2O precursor was estimated to be 18.1 nm and that from Zr(SO4)2.H2O was 9.7 nm. The transmission electron microscopy and scanning electron microscopic studies also shows different sizes of nanoparticles and different morphology depending on the precursor used for the synthesis of ZrO2 nanoparticles |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000600023 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000600023 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S1516-14392012005000128 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.15 n.6 2012 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212661672804352 |