Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl Media
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000100201 |
Resumo: | Abstract The present work aims to study the aqueous cotton seeds extract as a natural inhibitor of the corrosion of mild steel in 1 mol L−1 HCl using gravimetric tests, potentiodynamic polarization curves, electrochemical impedance measurements and surface morphological analysis by scanning electron microscopy (SEM). The aqueous cotton seed extract acted as a good corrosion inhibitor reaching an inhibition efficiency of 95.7% after 24 h of immersion for 800 mg L−1 inhibitor concentration. For the gravimetric tests varying the temperature, a decrease of the activation energy (Ea) was observed, suggesting a chemical adsorption on the surface of the metal. 400 mg L−1 of the high molecular weight fraction isolated from the total extract showed inhibition efficiency equal to 800 mg L−1 of the total extract, 97.3% and 94.2% from electrochemical impedance and polarization curves data, respectively, suggesting that the macromolecules present a fundamental participation in the inhibitive process. |
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Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl MediaMild steelcorrosion inhibitorcotton seednatural productsAbstract The present work aims to study the aqueous cotton seeds extract as a natural inhibitor of the corrosion of mild steel in 1 mol L−1 HCl using gravimetric tests, potentiodynamic polarization curves, electrochemical impedance measurements and surface morphological analysis by scanning electron microscopy (SEM). The aqueous cotton seed extract acted as a good corrosion inhibitor reaching an inhibition efficiency of 95.7% after 24 h of immersion for 800 mg L−1 inhibitor concentration. For the gravimetric tests varying the temperature, a decrease of the activation energy (Ea) was observed, suggesting a chemical adsorption on the surface of the metal. 400 mg L−1 of the high molecular weight fraction isolated from the total extract showed inhibition efficiency equal to 800 mg L−1 of the total extract, 97.3% and 94.2% from electrochemical impedance and polarization curves data, respectively, suggesting that the macromolecules present a fundamental participation in the inhibitive process.ABM, ABC, ABPol2021-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000100201Materials Research v.24 n.1 2021reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2020-0235info:eu-repo/semantics/openAccessHernandes,Isabel da SilvaCunha,Jéssica Nogueira daSantana,Carolina AraujoAquino Rodrigues,José GuilhermeD’Elia,Elianeeng2020-12-07T00:00:00Zoai:scielo:S1516-14392021000100201Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2020-12-07T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl Media |
title |
Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl Media |
spellingShingle |
Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl Media Hernandes,Isabel da Silva Mild steel corrosion inhibitor cotton seed natural products |
title_short |
Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl Media |
title_full |
Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl Media |
title_fullStr |
Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl Media |
title_full_unstemmed |
Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl Media |
title_sort |
Application of an Aqueous Extract of Cotton Seed as a Corrosion Inhibitor for Mild Steel in HCl Media |
author |
Hernandes,Isabel da Silva |
author_facet |
Hernandes,Isabel da Silva Cunha,Jéssica Nogueira da Santana,Carolina Araujo Aquino Rodrigues,José Guilherme D’Elia,Eliane |
author_role |
author |
author2 |
Cunha,Jéssica Nogueira da Santana,Carolina Araujo Aquino Rodrigues,José Guilherme D’Elia,Eliane |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Hernandes,Isabel da Silva Cunha,Jéssica Nogueira da Santana,Carolina Araujo Aquino Rodrigues,José Guilherme D’Elia,Eliane |
dc.subject.por.fl_str_mv |
Mild steel corrosion inhibitor cotton seed natural products |
topic |
Mild steel corrosion inhibitor cotton seed natural products |
description |
Abstract The present work aims to study the aqueous cotton seeds extract as a natural inhibitor of the corrosion of mild steel in 1 mol L−1 HCl using gravimetric tests, potentiodynamic polarization curves, electrochemical impedance measurements and surface morphological analysis by scanning electron microscopy (SEM). The aqueous cotton seed extract acted as a good corrosion inhibitor reaching an inhibition efficiency of 95.7% after 24 h of immersion for 800 mg L−1 inhibitor concentration. For the gravimetric tests varying the temperature, a decrease of the activation energy (Ea) was observed, suggesting a chemical adsorption on the surface of the metal. 400 mg L−1 of the high molecular weight fraction isolated from the total extract showed inhibition efficiency equal to 800 mg L−1 of the total extract, 97.3% and 94.2% from electrochemical impedance and polarization curves data, respectively, suggesting that the macromolecules present a fundamental participation in the inhibitive process. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000100201 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000100201 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2020-0235 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.24 n.1 2021 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212678058901504 |