Dynamic isotherms of dye in activated carbon

• Autor(a) principal: Matta,Gleisy Kelly Lopes
• Data de Publicação: 2008
• Outros Autores: Barros,Maria Angélica Simões Dornelas, Lambrecht,Rafael, Silva,Edison Antonio da, Lima,Oswaldo Curty da Motta
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Materials research (São Carlos. Online)
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392008000300022
• topic: activated carbon; dye; isotherm

Textile industrial wastewaters have significant quantities of dyes. Adsorption processes using industrials rejects may help in the treatment of these effluents. In this context, uptake of Reactive Blue 5G dye by babassu coconut shell activated carbon was studied with upstream flow fixed-bed experiments. First, the minimum flow rate that minimizes the diffusion effects of 4 mL/min was chosen within the range investigated (2-10 mL/min). Then, the breakthrough curves were obtained for this flow rate for different initial dye concentrations (13.15102.0 mg/L) and temperature of 30 °C. The mass retained until bed saturation in each experiment was used to obtain the dynamic isotherms, which showed a favorable dye uptake behavior with a maximum adsorption capacity of 12.9 mg.g-1. The irreversible model fitted the experimental data well when compared to Langmuir and Freundlich models. A LDF model simulated the experimental breakthrough curves, and the bed axial dispersion and mass transfer coefficients were estimated.