Effect of curing temperature and architectural (monolayer and bilayer) of hybrid films modified with polyethylene glycol for the corrosion protection on tinplate

• Autor(a) principal: Kunst,Sandra Raquel
• Data de Publicação: 2014
• Outros Autores: Beltrami,Lilian Vanessa Rossa, Cardoso,Henrique Ribeiro Piaggio, Veja,Maria Rita Ortega, Baldin,Estela Knopp Kerstner, Menezes,Tiago Lemos, Malfatti,Célia de Fraga
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Materials research (São Carlos. Online)
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000400034
• topic: tinplate; temperature; bilayered systems; monolayered systems

Hybrid films obtained by a sol-gel process are based on two important reactions: hydrolysis and condensation. The condensation reaction is influenced by the curing temperature, since it induces the development of the intrinsic properties of the gel. The aim of this work is to coat tinplate, a substrate widely used in the packaging industry, with monolayered and bilayered hybrid films modified with polyethylene glycol and obtained through dip-coating. The results showed that the bilayered hybrid film obtained at 60ºC had a higher layer thickness, and the best performance in the electrochemical assays, as well as the most hydrophobic character, in relation to the other samples. For the monolayered systems, the 90ºC-cured system showed a lower layer thickness; however, this system showed a more compact, uniform and less porous layer, and presented better electrochemical impedance results, in comparison with the 60ºC-cured samples.