Polyaniline synthesized with functionalized sulfonic acids for blends manufacture
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000400017 |
Resumo: | Polyaniline (PAni), an electronic conductive polymer, has poor mechanical properties, such as low tensile, compressive and flexural strength that render PAni a non-ideal material to be processed for practical applications. Desired properties of polyaniline can be enhanced by mixing it with a polymer that has good mechanical properties. In this work, PAni was synthesised using functionalized sulfonic acids like camphorsulfonic acid (CSA) and dodecilbenzene sulfonic acid (DBSA) in order to promote PAni doping and improve its solubility, making possible conductive blends manufacture. The different forms of PAni were characterized by infra-red spectroscopy, thermal analysis, scanning electron microscopy and conductivity measurements. A conductive blend composed of PAni/DBSA and lower density polyethylene (LDPE) was obtained via solubilization method and its thermal, morphological and electrical properties were investigated. Concentrations as low as 5 wt. (%) of PAni was able to lead to electrical conductivities of PAni/LDPE blends in the range of 10-3 S.cm-1, showing great potential to be used in antistatic packing, electromagnetic shielding, anti-corrosion shielding or as a semiconductor. |
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Materials research (São Carlos. Online) |
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Polyaniline synthesized with functionalized sulfonic acids for blends manufacturepolyanilinelower density polyethyleneconductive blendsPolyaniline (PAni), an electronic conductive polymer, has poor mechanical properties, such as low tensile, compressive and flexural strength that render PAni a non-ideal material to be processed for practical applications. Desired properties of polyaniline can be enhanced by mixing it with a polymer that has good mechanical properties. In this work, PAni was synthesised using functionalized sulfonic acids like camphorsulfonic acid (CSA) and dodecilbenzene sulfonic acid (DBSA) in order to promote PAni doping and improve its solubility, making possible conductive blends manufacture. The different forms of PAni were characterized by infra-red spectroscopy, thermal analysis, scanning electron microscopy and conductivity measurements. A conductive blend composed of PAni/DBSA and lower density polyethylene (LDPE) was obtained via solubilization method and its thermal, morphological and electrical properties were investigated. Concentrations as low as 5 wt. (%) of PAni was able to lead to electrical conductivities of PAni/LDPE blends in the range of 10-3 S.cm-1, showing great potential to be used in antistatic packing, electromagnetic shielding, anti-corrosion shielding or as a semiconductor.ABM, ABC, ABPol2007-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000400017Materials Research v.10 n.4 2007reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392007000400017info:eu-repo/semantics/openAccessCardoso,Mara Joelma RauppLima,Martha Fogliato SantosLenz,Denise Mariaeng2008-02-07T00:00:00Zoai:scielo:S1516-14392007000400017Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2008-02-07T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Polyaniline synthesized with functionalized sulfonic acids for blends manufacture |
title |
Polyaniline synthesized with functionalized sulfonic acids for blends manufacture |
spellingShingle |
Polyaniline synthesized with functionalized sulfonic acids for blends manufacture Cardoso,Mara Joelma Raupp polyaniline lower density polyethylene conductive blends |
title_short |
Polyaniline synthesized with functionalized sulfonic acids for blends manufacture |
title_full |
Polyaniline synthesized with functionalized sulfonic acids for blends manufacture |
title_fullStr |
Polyaniline synthesized with functionalized sulfonic acids for blends manufacture |
title_full_unstemmed |
Polyaniline synthesized with functionalized sulfonic acids for blends manufacture |
title_sort |
Polyaniline synthesized with functionalized sulfonic acids for blends manufacture |
author |
Cardoso,Mara Joelma Raupp |
author_facet |
Cardoso,Mara Joelma Raupp Lima,Martha Fogliato Santos Lenz,Denise Maria |
author_role |
author |
author2 |
Lima,Martha Fogliato Santos Lenz,Denise Maria |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Cardoso,Mara Joelma Raupp Lima,Martha Fogliato Santos Lenz,Denise Maria |
dc.subject.por.fl_str_mv |
polyaniline lower density polyethylene conductive blends |
topic |
polyaniline lower density polyethylene conductive blends |
description |
Polyaniline (PAni), an electronic conductive polymer, has poor mechanical properties, such as low tensile, compressive and flexural strength that render PAni a non-ideal material to be processed for practical applications. Desired properties of polyaniline can be enhanced by mixing it with a polymer that has good mechanical properties. In this work, PAni was synthesised using functionalized sulfonic acids like camphorsulfonic acid (CSA) and dodecilbenzene sulfonic acid (DBSA) in order to promote PAni doping and improve its solubility, making possible conductive blends manufacture. The different forms of PAni were characterized by infra-red spectroscopy, thermal analysis, scanning electron microscopy and conductivity measurements. A conductive blend composed of PAni/DBSA and lower density polyethylene (LDPE) was obtained via solubilization method and its thermal, morphological and electrical properties were investigated. Concentrations as low as 5 wt. (%) of PAni was able to lead to electrical conductivities of PAni/LDPE blends in the range of 10-3 S.cm-1, showing great potential to be used in antistatic packing, electromagnetic shielding, anti-corrosion shielding or as a semiconductor. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000400017 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000400017 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S1516-14392007000400017 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.10 n.4 2007 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212658850037760 |