Sulfonated polyaniline: influence of sulfonation routes on its thermal and structural characteristics

• Autor(a) principal: Mendes,Luis Claudio
• Data de Publicação: 2011
• Outros Autores: Falco,Ana Paula Santiago, Pinho,Magali Silveira, Marques,Priscila Oliveira
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Materials research (São Carlos. Online)
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392011000400007
• topic: SPAni; TG/DTG; DSC; FT-IR; UV-vis

In order to study the influence of different sulfonation routes on its thermal and structural properties sulfonated polyaniline (SPAni) was prepared. FT-IR revealed that the formation of PAni salt or ring sulfonation depends on the route. UV-visible spectra pointed out that the level of the PAni protonation was dependent on the sulfonation route. A new approach was given for TG/DTG and DSC results correlating different energy levels with the distinguished sulfonation routes. The TG/DTG degradation steps and the amount of the released material corroborated the structural differences of the polyanilines. For each DSC first regime of heating, a broad and intense peak (from -30 to 250 ºC) with different level of energy was noticed. That peak could be ascribed to the multiple relaxations and breaking of the PAni intra and inter hydrogen bonds after sulfonation.