Thermoplastic polyurethane synthesis using POSS as a chain modifier
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000400031 |
Resumo: | In this study, thermoplastic polyurethanes (TPUs) were synthesized using the one-shot process in solution. To obtain the samples n-phenylaminopropyl polyhedric oligomeric silsesquioxane (POSS) was added as a chain modifier during the synthesis in four different amounts. The samples were characterized by infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and capillary rheometry. FTIR confirm the TPU attainment due the absence of the band at ~2253 cm-1 suggesting a complete conversion of the isocyanate terminations. The TGA showed that incorporation of POSS decreased the rate of mass loss of TPU under isothermal conditions. The flexible phase showed an enhanced stability to temperature, probably due to increased phase separation between the rigid and flexible domains. The DSC showed that incorporation of 0.4 wt. (%) of POSS increased the glass transition temperature of the flexible phase. Moreover, addition of POSS modified the melting behaviour, providing samples with a higher melting enthalpy compared to neat TPU as a consequence of the formation of larger crystals. The capillary rheometry analysis revels that the POSS addition showed a clear tendency toward higher intrinsic viscosities as the amount of POSS was increased. |
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Materials research (São Carlos. Online) |
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Thermoplastic polyurethane synthesis using POSS as a chain modifierthermoplastic polyurethanePOSSFTIRthermal stabilityDSCcapillary rheometryIn this study, thermoplastic polyurethanes (TPUs) were synthesized using the one-shot process in solution. To obtain the samples n-phenylaminopropyl polyhedric oligomeric silsesquioxane (POSS) was added as a chain modifier during the synthesis in four different amounts. The samples were characterized by infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and capillary rheometry. FTIR confirm the TPU attainment due the absence of the band at ~2253 cm-1 suggesting a complete conversion of the isocyanate terminations. The TGA showed that incorporation of POSS decreased the rate of mass loss of TPU under isothermal conditions. The flexible phase showed an enhanced stability to temperature, probably due to increased phase separation between the rigid and flexible domains. The DSC showed that incorporation of 0.4 wt. (%) of POSS increased the glass transition temperature of the flexible phase. Moreover, addition of POSS modified the melting behaviour, providing samples with a higher melting enthalpy compared to neat TPU as a consequence of the formation of larger crystals. The capillary rheometry analysis revels that the POSS addition showed a clear tendency toward higher intrinsic viscosities as the amount of POSS was increased.ABM, ABC, ABPol2012-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000400031Materials Research v.15 n.4 2012reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392012005000085info:eu-repo/semantics/openAccessLopes,Gabriel HoyerJunges,JanaínaFiorio,RudineiZeni,MaraZattera,Ademir Joséeng2012-08-24T00:00:00Zoai:scielo:S1516-14392012000400031Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2012-08-24T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Thermoplastic polyurethane synthesis using POSS as a chain modifier |
title |
Thermoplastic polyurethane synthesis using POSS as a chain modifier |
spellingShingle |
Thermoplastic polyurethane synthesis using POSS as a chain modifier Lopes,Gabriel Hoyer thermoplastic polyurethane POSS FTIR thermal stability DSC capillary rheometry |
title_short |
Thermoplastic polyurethane synthesis using POSS as a chain modifier |
title_full |
Thermoplastic polyurethane synthesis using POSS as a chain modifier |
title_fullStr |
Thermoplastic polyurethane synthesis using POSS as a chain modifier |
title_full_unstemmed |
Thermoplastic polyurethane synthesis using POSS as a chain modifier |
title_sort |
Thermoplastic polyurethane synthesis using POSS as a chain modifier |
author |
Lopes,Gabriel Hoyer |
author_facet |
Lopes,Gabriel Hoyer Junges,Janaína Fiorio,Rudinei Zeni,Mara Zattera,Ademir José |
author_role |
author |
author2 |
Junges,Janaína Fiorio,Rudinei Zeni,Mara Zattera,Ademir José |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Lopes,Gabriel Hoyer Junges,Janaína Fiorio,Rudinei Zeni,Mara Zattera,Ademir José |
dc.subject.por.fl_str_mv |
thermoplastic polyurethane POSS FTIR thermal stability DSC capillary rheometry |
topic |
thermoplastic polyurethane POSS FTIR thermal stability DSC capillary rheometry |
description |
In this study, thermoplastic polyurethanes (TPUs) were synthesized using the one-shot process in solution. To obtain the samples n-phenylaminopropyl polyhedric oligomeric silsesquioxane (POSS) was added as a chain modifier during the synthesis in four different amounts. The samples were characterized by infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and capillary rheometry. FTIR confirm the TPU attainment due the absence of the band at ~2253 cm-1 suggesting a complete conversion of the isocyanate terminations. The TGA showed that incorporation of POSS decreased the rate of mass loss of TPU under isothermal conditions. The flexible phase showed an enhanced stability to temperature, probably due to increased phase separation between the rigid and flexible domains. The DSC showed that incorporation of 0.4 wt. (%) of POSS increased the glass transition temperature of the flexible phase. Moreover, addition of POSS modified the melting behaviour, providing samples with a higher melting enthalpy compared to neat TPU as a consequence of the formation of larger crystals. The capillary rheometry analysis revels that the POSS addition showed a clear tendency toward higher intrinsic viscosities as the amount of POSS was increased. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-08-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000400031 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000400031 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S1516-14392012005000085 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.15 n.4 2012 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212661606744064 |