Corrosion Inhibition of Mild Steel with Tolyltriazole

Detalhes bibliográficos
Autor(a) principal: Fathabadi,H. E.
Data de Publicação: 2021
Outros Autores: Ghorbani,M., Ghartavol,H. Mokarami
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000400203
Resumo: Tolyltriazole (TTA) is a well-defined corrosion inhibitor for copper and copper alloys. However, there is little literature about its corrosion inhibition performance for mild steels in corrosive environments. This paper studied the electrochemical behavior of TTA in 0.5 M HCl solutions. Also, the morphology and nature of TTA layers on the steel surface were investigated. Electrochemical results showed that TTA is an excellent corrosion inhibitor for mild steel in acidic media with an efficiency of 91% for 0.07 M concentration. The results also indicated that TTA is a mixed-type inhibitor. XRD analysis revealed that the inhibition mechanism of TTA is based on the formation of an organic film due to the physically adsorbed molecules of TTA. AFM and EDS results showed that the formed layers decrease the adsorptivity of corrosive elements (Cl-) on the steel surface. Density Functional Theory (DFT) study confirmed the experimental results.
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spelling Corrosion Inhibition of Mild Steel with TolyltriazoleTolyltriazole (TTA)mild steelcorrosion inhibitorElectrochemicalmorphologyacidic mediaTolyltriazole (TTA) is a well-defined corrosion inhibitor for copper and copper alloys. However, there is little literature about its corrosion inhibition performance for mild steels in corrosive environments. This paper studied the electrochemical behavior of TTA in 0.5 M HCl solutions. Also, the morphology and nature of TTA layers on the steel surface were investigated. Electrochemical results showed that TTA is an excellent corrosion inhibitor for mild steel in acidic media with an efficiency of 91% for 0.07 M concentration. The results also indicated that TTA is a mixed-type inhibitor. XRD analysis revealed that the inhibition mechanism of TTA is based on the formation of an organic film due to the physically adsorbed molecules of TTA. AFM and EDS results showed that the formed layers decrease the adsorptivity of corrosive elements (Cl-) on the steel surface. Density Functional Theory (DFT) study confirmed the experimental results.ABM, ABC, ABPol2021-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000400203Materials Research v.24 n.4 2021reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2020-0395info:eu-repo/semantics/openAccessFathabadi,H. E.Ghorbani,M.Ghartavol,H. Mokaramieng2021-05-11T00:00:00Zoai:scielo:S1516-14392021000400203Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2021-05-11T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Corrosion Inhibition of Mild Steel with Tolyltriazole
title Corrosion Inhibition of Mild Steel with Tolyltriazole
spellingShingle Corrosion Inhibition of Mild Steel with Tolyltriazole
Fathabadi,H. E.
Tolyltriazole (TTA)
mild steel
corrosion inhibitor
Electrochemical
morphology
acidic media
title_short Corrosion Inhibition of Mild Steel with Tolyltriazole
title_full Corrosion Inhibition of Mild Steel with Tolyltriazole
title_fullStr Corrosion Inhibition of Mild Steel with Tolyltriazole
title_full_unstemmed Corrosion Inhibition of Mild Steel with Tolyltriazole
title_sort Corrosion Inhibition of Mild Steel with Tolyltriazole
author Fathabadi,H. E.
author_facet Fathabadi,H. E.
Ghorbani,M.
Ghartavol,H. Mokarami
author_role author
author2 Ghorbani,M.
Ghartavol,H. Mokarami
author2_role author
author
dc.contributor.author.fl_str_mv Fathabadi,H. E.
Ghorbani,M.
Ghartavol,H. Mokarami
dc.subject.por.fl_str_mv Tolyltriazole (TTA)
mild steel
corrosion inhibitor
Electrochemical
morphology
acidic media
topic Tolyltriazole (TTA)
mild steel
corrosion inhibitor
Electrochemical
morphology
acidic media
description Tolyltriazole (TTA) is a well-defined corrosion inhibitor for copper and copper alloys. However, there is little literature about its corrosion inhibition performance for mild steels in corrosive environments. This paper studied the electrochemical behavior of TTA in 0.5 M HCl solutions. Also, the morphology and nature of TTA layers on the steel surface were investigated. Electrochemical results showed that TTA is an excellent corrosion inhibitor for mild steel in acidic media with an efficiency of 91% for 0.07 M concentration. The results also indicated that TTA is a mixed-type inhibitor. XRD analysis revealed that the inhibition mechanism of TTA is based on the formation of an organic film due to the physically adsorbed molecules of TTA. AFM and EDS results showed that the formed layers decrease the adsorptivity of corrosive elements (Cl-) on the steel surface. Density Functional Theory (DFT) study confirmed the experimental results.
publishDate 2021
dc.date.none.fl_str_mv 2021-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000400203
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000400203
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/1980-5373-mr-2020-0395
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.24 n.4 2021
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
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