Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative

Detalhes bibliográficos
Autor(a) principal: Lattmann,Bruno Henrique
Data de Publicação: 2019
Outros Autores: Lunelli,Carlos Eduardo, Scremin,Duanne M., Padilha,Bianca, Trindade,Eduardo Marques, Zawadzki,Sônia Faria
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700225
Resumo: Polystyrene (PS) is one of the most widely used polymers in the world, having a wide applicability. PS can be used in pure or modified forms, and the commercial materials most used for modifications are non-renewable and have high costs. For this reason, studies have been carried in order to evaluate renewable components application such as vegetable oils, for this purpose. In this context, different materials have been prepared from styrene (STY) and the common fatty oleic acid (FA) modified with allyl alcohol through esterification in acid catalysis. The allyl oleate (AOL) was obtained with yield of 89% (w/w) and it was submitted to a reaction with styrene at variable concentrations. The copolymers (PS-AOL) were obtained and characterized by conventional techniques. The results indicated that the copolymerization occurred. Therefore, the proposed methodology allows the compatibilization between a renewable matrix and PS for the new materials obtaining.
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spelling Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester DerivativePolystyreneallyl oleateesterificationcopolymerPolystyrene (PS) is one of the most widely used polymers in the world, having a wide applicability. PS can be used in pure or modified forms, and the commercial materials most used for modifications are non-renewable and have high costs. For this reason, studies have been carried in order to evaluate renewable components application such as vegetable oils, for this purpose. In this context, different materials have been prepared from styrene (STY) and the common fatty oleic acid (FA) modified with allyl alcohol through esterification in acid catalysis. The allyl oleate (AOL) was obtained with yield of 89% (w/w) and it was submitted to a reaction with styrene at variable concentrations. The copolymers (PS-AOL) were obtained and characterized by conventional techniques. The results indicated that the copolymerization occurred. Therefore, the proposed methodology allows the compatibilization between a renewable matrix and PS for the new materials obtaining.ABM, ABC, ABPol2019-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700225Materials Research v.22 suppl.1 2019reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2018-0905info:eu-repo/semantics/openAccessLattmann,Bruno HenriqueLunelli,Carlos EduardoScremin,Duanne M.Padilha,BiancaTrindade,Eduardo MarquesZawadzki,Sônia Fariaeng2019-10-04T00:00:00Zoai:scielo:S1516-14392019000700225Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2019-10-04T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
title Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
spellingShingle Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
Lattmann,Bruno Henrique
Polystyrene
allyl oleate
esterification
copolymer
title_short Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
title_full Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
title_fullStr Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
title_full_unstemmed Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
title_sort Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
author Lattmann,Bruno Henrique
author_facet Lattmann,Bruno Henrique
Lunelli,Carlos Eduardo
Scremin,Duanne M.
Padilha,Bianca
Trindade,Eduardo Marques
Zawadzki,Sônia Faria
author_role author
author2 Lunelli,Carlos Eduardo
Scremin,Duanne M.
Padilha,Bianca
Trindade,Eduardo Marques
Zawadzki,Sônia Faria
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Lattmann,Bruno Henrique
Lunelli,Carlos Eduardo
Scremin,Duanne M.
Padilha,Bianca
Trindade,Eduardo Marques
Zawadzki,Sônia Faria
dc.subject.por.fl_str_mv Polystyrene
allyl oleate
esterification
copolymer
topic Polystyrene
allyl oleate
esterification
copolymer
description Polystyrene (PS) is one of the most widely used polymers in the world, having a wide applicability. PS can be used in pure or modified forms, and the commercial materials most used for modifications are non-renewable and have high costs. For this reason, studies have been carried in order to evaluate renewable components application such as vegetable oils, for this purpose. In this context, different materials have been prepared from styrene (STY) and the common fatty oleic acid (FA) modified with allyl alcohol through esterification in acid catalysis. The allyl oleate (AOL) was obtained with yield of 89% (w/w) and it was submitted to a reaction with styrene at variable concentrations. The copolymers (PS-AOL) were obtained and characterized by conventional techniques. The results indicated that the copolymerization occurred. Therefore, the proposed methodology allows the compatibilization between a renewable matrix and PS for the new materials obtaining.
publishDate 2019
dc.date.none.fl_str_mv 2019-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700225
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700225
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/1980-5373-mr-2018-0905
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.22 suppl.1 2019
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
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