Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700225 |
Resumo: | Polystyrene (PS) is one of the most widely used polymers in the world, having a wide applicability. PS can be used in pure or modified forms, and the commercial materials most used for modifications are non-renewable and have high costs. For this reason, studies have been carried in order to evaluate renewable components application such as vegetable oils, for this purpose. In this context, different materials have been prepared from styrene (STY) and the common fatty oleic acid (FA) modified with allyl alcohol through esterification in acid catalysis. The allyl oleate (AOL) was obtained with yield of 89% (w/w) and it was submitted to a reaction with styrene at variable concentrations. The copolymers (PS-AOL) were obtained and characterized by conventional techniques. The results indicated that the copolymerization occurred. Therefore, the proposed methodology allows the compatibilization between a renewable matrix and PS for the new materials obtaining. |
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Materials research (São Carlos. Online) |
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Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester DerivativePolystyreneallyl oleateesterificationcopolymerPolystyrene (PS) is one of the most widely used polymers in the world, having a wide applicability. PS can be used in pure or modified forms, and the commercial materials most used for modifications are non-renewable and have high costs. For this reason, studies have been carried in order to evaluate renewable components application such as vegetable oils, for this purpose. In this context, different materials have been prepared from styrene (STY) and the common fatty oleic acid (FA) modified with allyl alcohol through esterification in acid catalysis. The allyl oleate (AOL) was obtained with yield of 89% (w/w) and it was submitted to a reaction with styrene at variable concentrations. The copolymers (PS-AOL) were obtained and characterized by conventional techniques. The results indicated that the copolymerization occurred. Therefore, the proposed methodology allows the compatibilization between a renewable matrix and PS for the new materials obtaining.ABM, ABC, ABPol2019-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700225Materials Research v.22 suppl.1 2019reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2018-0905info:eu-repo/semantics/openAccessLattmann,Bruno HenriqueLunelli,Carlos EduardoScremin,Duanne M.Padilha,BiancaTrindade,Eduardo MarquesZawadzki,Sônia Fariaeng2019-10-04T00:00:00Zoai:scielo:S1516-14392019000700225Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2019-10-04T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative |
title |
Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative |
spellingShingle |
Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative Lattmann,Bruno Henrique Polystyrene allyl oleate esterification copolymer |
title_short |
Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative |
title_full |
Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative |
title_fullStr |
Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative |
title_full_unstemmed |
Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative |
title_sort |
Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative |
author |
Lattmann,Bruno Henrique |
author_facet |
Lattmann,Bruno Henrique Lunelli,Carlos Eduardo Scremin,Duanne M. Padilha,Bianca Trindade,Eduardo Marques Zawadzki,Sônia Faria |
author_role |
author |
author2 |
Lunelli,Carlos Eduardo Scremin,Duanne M. Padilha,Bianca Trindade,Eduardo Marques Zawadzki,Sônia Faria |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Lattmann,Bruno Henrique Lunelli,Carlos Eduardo Scremin,Duanne M. Padilha,Bianca Trindade,Eduardo Marques Zawadzki,Sônia Faria |
dc.subject.por.fl_str_mv |
Polystyrene allyl oleate esterification copolymer |
topic |
Polystyrene allyl oleate esterification copolymer |
description |
Polystyrene (PS) is one of the most widely used polymers in the world, having a wide applicability. PS can be used in pure or modified forms, and the commercial materials most used for modifications are non-renewable and have high costs. For this reason, studies have been carried in order to evaluate renewable components application such as vegetable oils, for this purpose. In this context, different materials have been prepared from styrene (STY) and the common fatty oleic acid (FA) modified with allyl alcohol through esterification in acid catalysis. The allyl oleate (AOL) was obtained with yield of 89% (w/w) and it was submitted to a reaction with styrene at variable concentrations. The copolymers (PS-AOL) were obtained and characterized by conventional techniques. The results indicated that the copolymerization occurred. Therefore, the proposed methodology allows the compatibilization between a renewable matrix and PS for the new materials obtaining. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700225 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700225 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2018-0905 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.22 suppl.1 2019 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212675609427968 |