In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties

Detalhes bibliográficos
Autor(a) principal: Devi,Rashmi R
Data de Publicação: 2013
Outros Autores: Maji,Tarun K
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000400035
Resumo: This study concerns the preparation and characterization of wood polymer nanocomposites based on impregnation of styrene acrylonitrile co-polymer-nanoclay intercalating system in presence of glycidyl methacrylate (GMA), a cross linking agent, and vinyl trichloro silane (VTCS) as additives into Simul (Bombex ceiba, L.), a soft wood. The effect of nanoclay and VTCS on the properties of the resultant wood polymer nanocomposites (WPNC) has been evaluated. FTIR spectroscopy shows the interaction among wood, polymers, GMA, nanoclay and VTCS. The penetration of polymer and nanoclay into the wood cell wall is supported by SEM study. The distribution of nanoclay in the SAN polymer matrix present within the wood cell wall has been evidenced by TEM study. TGA results show an improvement in the thermostability of the resultant composites. The inclusion of VTCS enhances the self extinguishing behaviour of the WPNC as revealed by limiting oxygen index (LOI) test. Due to treatment, the resultant WPNC exhibits an improvement in all the properties like water repellancy, dimensional stability, hardness, flexural, tensile and thermal stability compared to untreated wood.
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spelling In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical propertiesco-polymersflame retardancemechanical propertiesorganoclaythermogravimetric analysistransmission electron microscopyThis study concerns the preparation and characterization of wood polymer nanocomposites based on impregnation of styrene acrylonitrile co-polymer-nanoclay intercalating system in presence of glycidyl methacrylate (GMA), a cross linking agent, and vinyl trichloro silane (VTCS) as additives into Simul (Bombex ceiba, L.), a soft wood. The effect of nanoclay and VTCS on the properties of the resultant wood polymer nanocomposites (WPNC) has been evaluated. FTIR spectroscopy shows the interaction among wood, polymers, GMA, nanoclay and VTCS. The penetration of polymer and nanoclay into the wood cell wall is supported by SEM study. The distribution of nanoclay in the SAN polymer matrix present within the wood cell wall has been evidenced by TEM study. TGA results show an improvement in the thermostability of the resultant composites. The inclusion of VTCS enhances the self extinguishing behaviour of the WPNC as revealed by limiting oxygen index (LOI) test. Due to treatment, the resultant WPNC exhibits an improvement in all the properties like water repellancy, dimensional stability, hardness, flexural, tensile and thermal stability compared to untreated wood.ABM, ABC, ABPol2013-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000400035Materials Research v.16 n.4 2013reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392013005000071info:eu-repo/semantics/openAccessDevi,Rashmi RMaji,Tarun Keng2013-08-02T00:00:00Zoai:scielo:S1516-14392013000400035Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2013-08-02T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties
title In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties
spellingShingle In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties
Devi,Rashmi R
co-polymers
flame retardance
mechanical properties
organoclay
thermogravimetric analysis
transmission electron microscopy
title_short In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties
title_full In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties
title_fullStr In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties
title_full_unstemmed In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties
title_sort In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties
author Devi,Rashmi R
author_facet Devi,Rashmi R
Maji,Tarun K
author_role author
author2 Maji,Tarun K
author2_role author
dc.contributor.author.fl_str_mv Devi,Rashmi R
Maji,Tarun K
dc.subject.por.fl_str_mv co-polymers
flame retardance
mechanical properties
organoclay
thermogravimetric analysis
transmission electron microscopy
topic co-polymers
flame retardance
mechanical properties
organoclay
thermogravimetric analysis
transmission electron microscopy
description This study concerns the preparation and characterization of wood polymer nanocomposites based on impregnation of styrene acrylonitrile co-polymer-nanoclay intercalating system in presence of glycidyl methacrylate (GMA), a cross linking agent, and vinyl trichloro silane (VTCS) as additives into Simul (Bombex ceiba, L.), a soft wood. The effect of nanoclay and VTCS on the properties of the resultant wood polymer nanocomposites (WPNC) has been evaluated. FTIR spectroscopy shows the interaction among wood, polymers, GMA, nanoclay and VTCS. The penetration of polymer and nanoclay into the wood cell wall is supported by SEM study. The distribution of nanoclay in the SAN polymer matrix present within the wood cell wall has been evidenced by TEM study. TGA results show an improvement in the thermostability of the resultant composites. The inclusion of VTCS enhances the self extinguishing behaviour of the WPNC as revealed by limiting oxygen index (LOI) test. Due to treatment, the resultant WPNC exhibits an improvement in all the properties like water repellancy, dimensional stability, hardness, flexural, tensile and thermal stability compared to untreated wood.
publishDate 2013
dc.date.none.fl_str_mv 2013-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000400035
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000400035
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S1516-14392013005000071
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.16 n.4 2013
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
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