In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000400035 |
Resumo: | This study concerns the preparation and characterization of wood polymer nanocomposites based on impregnation of styrene acrylonitrile co-polymer-nanoclay intercalating system in presence of glycidyl methacrylate (GMA), a cross linking agent, and vinyl trichloro silane (VTCS) as additives into Simul (Bombex ceiba, L.), a soft wood. The effect of nanoclay and VTCS on the properties of the resultant wood polymer nanocomposites (WPNC) has been evaluated. FTIR spectroscopy shows the interaction among wood, polymers, GMA, nanoclay and VTCS. The penetration of polymer and nanoclay into the wood cell wall is supported by SEM study. The distribution of nanoclay in the SAN polymer matrix present within the wood cell wall has been evidenced by TEM study. TGA results show an improvement in the thermostability of the resultant composites. The inclusion of VTCS enhances the self extinguishing behaviour of the WPNC as revealed by limiting oxygen index (LOI) test. Due to treatment, the resultant WPNC exhibits an improvement in all the properties like water repellancy, dimensional stability, hardness, flexural, tensile and thermal stability compared to untreated wood. |
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In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical propertiesco-polymersflame retardancemechanical propertiesorganoclaythermogravimetric analysistransmission electron microscopyThis study concerns the preparation and characterization of wood polymer nanocomposites based on impregnation of styrene acrylonitrile co-polymer-nanoclay intercalating system in presence of glycidyl methacrylate (GMA), a cross linking agent, and vinyl trichloro silane (VTCS) as additives into Simul (Bombex ceiba, L.), a soft wood. The effect of nanoclay and VTCS on the properties of the resultant wood polymer nanocomposites (WPNC) has been evaluated. FTIR spectroscopy shows the interaction among wood, polymers, GMA, nanoclay and VTCS. The penetration of polymer and nanoclay into the wood cell wall is supported by SEM study. The distribution of nanoclay in the SAN polymer matrix present within the wood cell wall has been evidenced by TEM study. TGA results show an improvement in the thermostability of the resultant composites. The inclusion of VTCS enhances the self extinguishing behaviour of the WPNC as revealed by limiting oxygen index (LOI) test. Due to treatment, the resultant WPNC exhibits an improvement in all the properties like water repellancy, dimensional stability, hardness, flexural, tensile and thermal stability compared to untreated wood.ABM, ABC, ABPol2013-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000400035Materials Research v.16 n.4 2013reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392013005000071info:eu-repo/semantics/openAccessDevi,Rashmi RMaji,Tarun Keng2013-08-02T00:00:00Zoai:scielo:S1516-14392013000400035Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2013-08-02T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties |
title |
In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties |
spellingShingle |
In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties Devi,Rashmi R co-polymers flame retardance mechanical properties organoclay thermogravimetric analysis transmission electron microscopy |
title_short |
In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties |
title_full |
In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties |
title_fullStr |
In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties |
title_full_unstemmed |
In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties |
title_sort |
In situ polymerized wood polymer composite: effect of additives and nanoclay on the thermal, mechanical properties |
author |
Devi,Rashmi R |
author_facet |
Devi,Rashmi R Maji,Tarun K |
author_role |
author |
author2 |
Maji,Tarun K |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Devi,Rashmi R Maji,Tarun K |
dc.subject.por.fl_str_mv |
co-polymers flame retardance mechanical properties organoclay thermogravimetric analysis transmission electron microscopy |
topic |
co-polymers flame retardance mechanical properties organoclay thermogravimetric analysis transmission electron microscopy |
description |
This study concerns the preparation and characterization of wood polymer nanocomposites based on impregnation of styrene acrylonitrile co-polymer-nanoclay intercalating system in presence of glycidyl methacrylate (GMA), a cross linking agent, and vinyl trichloro silane (VTCS) as additives into Simul (Bombex ceiba, L.), a soft wood. The effect of nanoclay and VTCS on the properties of the resultant wood polymer nanocomposites (WPNC) has been evaluated. FTIR spectroscopy shows the interaction among wood, polymers, GMA, nanoclay and VTCS. The penetration of polymer and nanoclay into the wood cell wall is supported by SEM study. The distribution of nanoclay in the SAN polymer matrix present within the wood cell wall has been evidenced by TEM study. TGA results show an improvement in the thermostability of the resultant composites. The inclusion of VTCS enhances the self extinguishing behaviour of the WPNC as revealed by limiting oxygen index (LOI) test. Due to treatment, the resultant WPNC exhibits an improvement in all the properties like water repellancy, dimensional stability, hardness, flexural, tensile and thermal stability compared to untreated wood. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-08-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000400035 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000400035 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S1516-14392013005000071 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.16 n.4 2013 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212662912221184 |