Computer simulation of the mechanism for the synthesis of carbonado diamond
Autor(a) principal: | |
---|---|
Data de Publicação: | 2006 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392006000400012 |
Resumo: | The synthesis mechanism associated with the formation of carbonado type polycrystalline diamond has been analyzed. This analysis was performed by computer simulation of the field of temperature developed at the moment of graphite transformation into polycrystalline diamond. It was found that during the synthesis of this carbonado diamond, a strong non-steady thermal condition occurs, leading to changes in the thermodynamic equilibrium. As a consequence, a region comprising non-transformed graphite and carbonado with different characteristics is established. An experimental comparison was carried out between the carbonado hardness profile and the field of temperatures. The results show that the higher the temperature attained at local points inside the high-pressure chamber, the higher the hardness of the diamond. The simulation and experimental results indicated that concurrent mechanisms are acting during the carbonado synthesis. |
id |
ABMABCABPOL-1_b78ebad20681984ace2dd04375193815 |
---|---|
oai_identifier_str |
oai:scielo:S1516-14392006000400012 |
network_acronym_str |
ABMABCABPOL-1 |
network_name_str |
Materials research (São Carlos. Online) |
repository_id_str |
|
spelling |
Computer simulation of the mechanism for the synthesis of carbonado diamondcomputer simulationcarbonadopolycrystalline diamondfield of temperatureThe synthesis mechanism associated with the formation of carbonado type polycrystalline diamond has been analyzed. This analysis was performed by computer simulation of the field of temperature developed at the moment of graphite transformation into polycrystalline diamond. It was found that during the synthesis of this carbonado diamond, a strong non-steady thermal condition occurs, leading to changes in the thermodynamic equilibrium. As a consequence, a region comprising non-transformed graphite and carbonado with different characteristics is established. An experimental comparison was carried out between the carbonado hardness profile and the field of temperatures. The results show that the higher the temperature attained at local points inside the high-pressure chamber, the higher the hardness of the diamond. The simulation and experimental results indicated that concurrent mechanisms are acting during the carbonado synthesis.ABM, ABC, ABPol2006-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392006000400012Materials Research v.9 n.4 2006reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392006000400012info:eu-repo/semantics/openAccessRangel,João José de AssisRosenthal,RubenBobrovnitchii,Guerold SergueevitchMonteiro,Sergio Neveseng2007-03-22T00:00:00Zoai:scielo:S1516-14392006000400012Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2007-03-22T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Computer simulation of the mechanism for the synthesis of carbonado diamond |
title |
Computer simulation of the mechanism for the synthesis of carbonado diamond |
spellingShingle |
Computer simulation of the mechanism for the synthesis of carbonado diamond Rangel,João José de Assis computer simulation carbonado polycrystalline diamond field of temperature |
title_short |
Computer simulation of the mechanism for the synthesis of carbonado diamond |
title_full |
Computer simulation of the mechanism for the synthesis of carbonado diamond |
title_fullStr |
Computer simulation of the mechanism for the synthesis of carbonado diamond |
title_full_unstemmed |
Computer simulation of the mechanism for the synthesis of carbonado diamond |
title_sort |
Computer simulation of the mechanism for the synthesis of carbonado diamond |
author |
Rangel,João José de Assis |
author_facet |
Rangel,João José de Assis Rosenthal,Ruben Bobrovnitchii,Guerold Sergueevitch Monteiro,Sergio Neves |
author_role |
author |
author2 |
Rosenthal,Ruben Bobrovnitchii,Guerold Sergueevitch Monteiro,Sergio Neves |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Rangel,João José de Assis Rosenthal,Ruben Bobrovnitchii,Guerold Sergueevitch Monteiro,Sergio Neves |
dc.subject.por.fl_str_mv |
computer simulation carbonado polycrystalline diamond field of temperature |
topic |
computer simulation carbonado polycrystalline diamond field of temperature |
description |
The synthesis mechanism associated with the formation of carbonado type polycrystalline diamond has been analyzed. This analysis was performed by computer simulation of the field of temperature developed at the moment of graphite transformation into polycrystalline diamond. It was found that during the synthesis of this carbonado diamond, a strong non-steady thermal condition occurs, leading to changes in the thermodynamic equilibrium. As a consequence, a region comprising non-transformed graphite and carbonado with different characteristics is established. An experimental comparison was carried out between the carbonado hardness profile and the field of temperatures. The results show that the higher the temperature attained at local points inside the high-pressure chamber, the higher the hardness of the diamond. The simulation and experimental results indicated that concurrent mechanisms are acting during the carbonado synthesis. |
publishDate |
2006 |
dc.date.none.fl_str_mv |
2006-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392006000400012 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392006000400012 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S1516-14392006000400012 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.9 n.4 2006 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212658491424768 |