Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocomposites

Detalhes bibliográficos
Autor(a) principal: Nguyen,Luan Thanh
Data de Publicação: 2021
Outros Autores: Le Tran,Hai, Mai,Phong Thanh, Duong,Vu Ba, Nguyen,Le-Thu T., Nguyen,Ha Tran
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000100202
Resumo: Abstract The synthesis of poly(L-glutamic acid) (PG) was investigated. Reduction of poly(benzyl-L-glutamate) by the palladium/charcoal catalyst proved to be an effective method for obtaining polyglutamic acid pure and particularly exhibiting in the α-helix secondary structure. The structure of this synthetic polypeptide was assessed by infrared spectroscopy, gel permeation chromatography, proton nuclear magnetic resonance spectroscopy, temperature-modulated differential scanning calorimetry and wide-angle powder X-ray diffraction methods. The α-helical PG was, for the first time, combined with multi-walled carbon nanotubes (MWCNTs). The obtained PG was demonstrated to be a promising matrix to disperse MWCNTs, forming MWCNT/PG biocomposites.
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spelling Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocompositesPoly(L-glutamic acid)nanocompositesmulti-walled carbon nanotubesAbstract The synthesis of poly(L-glutamic acid) (PG) was investigated. Reduction of poly(benzyl-L-glutamate) by the palladium/charcoal catalyst proved to be an effective method for obtaining polyglutamic acid pure and particularly exhibiting in the α-helix secondary structure. The structure of this synthetic polypeptide was assessed by infrared spectroscopy, gel permeation chromatography, proton nuclear magnetic resonance spectroscopy, temperature-modulated differential scanning calorimetry and wide-angle powder X-ray diffraction methods. The α-helical PG was, for the first time, combined with multi-walled carbon nanotubes (MWCNTs). The obtained PG was demonstrated to be a promising matrix to disperse MWCNTs, forming MWCNT/PG biocomposites.ABM, ABC, ABPol2021-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000100202Materials Research v.24 n.1 2021reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2020-0321info:eu-repo/semantics/openAccessNguyen,Luan ThanhLe Tran,HaiMai,Phong ThanhDuong,Vu BaNguyen,Le-Thu T.Nguyen,Ha Traneng2021-01-12T00:00:00Zoai:scielo:S1516-14392021000100202Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2021-01-12T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocomposites
title Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocomposites
spellingShingle Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocomposites
Nguyen,Luan Thanh
Poly(L-glutamic acid)
nanocomposites
multi-walled carbon nanotubes
title_short Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocomposites
title_full Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocomposites
title_fullStr Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocomposites
title_full_unstemmed Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocomposites
title_sort Poly(L-glutamic acid) via catalytical hydrogenation for the fabrication of carbon nanotube nanocomposites
author Nguyen,Luan Thanh
author_facet Nguyen,Luan Thanh
Le Tran,Hai
Mai,Phong Thanh
Duong,Vu Ba
Nguyen,Le-Thu T.
Nguyen,Ha Tran
author_role author
author2 Le Tran,Hai
Mai,Phong Thanh
Duong,Vu Ba
Nguyen,Le-Thu T.
Nguyen,Ha Tran
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Nguyen,Luan Thanh
Le Tran,Hai
Mai,Phong Thanh
Duong,Vu Ba
Nguyen,Le-Thu T.
Nguyen,Ha Tran
dc.subject.por.fl_str_mv Poly(L-glutamic acid)
nanocomposites
multi-walled carbon nanotubes
topic Poly(L-glutamic acid)
nanocomposites
multi-walled carbon nanotubes
description Abstract The synthesis of poly(L-glutamic acid) (PG) was investigated. Reduction of poly(benzyl-L-glutamate) by the palladium/charcoal catalyst proved to be an effective method for obtaining polyglutamic acid pure and particularly exhibiting in the α-helix secondary structure. The structure of this synthetic polypeptide was assessed by infrared spectroscopy, gel permeation chromatography, proton nuclear magnetic resonance spectroscopy, temperature-modulated differential scanning calorimetry and wide-angle powder X-ray diffraction methods. The α-helical PG was, for the first time, combined with multi-walled carbon nanotubes (MWCNTs). The obtained PG was demonstrated to be a promising matrix to disperse MWCNTs, forming MWCNT/PG biocomposites.
publishDate 2021
dc.date.none.fl_str_mv 2021-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000100202
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000100202
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/1980-5373-mr-2020-0321
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.24 n.1 2021
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
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