Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism study

Detalhes bibliográficos
Autor(a) principal: Aslya,Elkebir
Data de Publicação: 2016
Outros Autores: Harrane,Amine, Belbachir,Mohamed
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000100132
Resumo: Maghnite- H+ is Algerian montmorillonite sheet alumino-silicate clay, exchanged with protons (H+). This solid non-toxic catalyst was successfully used as cationic catalyst for the polymerization of D,L-Lactid at 100°C. Interactions between Maghnite-H+ platelets and the monomer (D,L-Lactide) were studied by solid state 1H, 27Al and 29Si NMR spectroscopy. The results show that, the mechanism of the reaction involves both Brønsted and Lewis acid sites on Maghnite surface.
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spelling Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism studyDL-Lactidepoly (D,L-Lactide)PLASolid state NMRMontmorilloniteSolid CatalystMaghnite- H+ is Algerian montmorillonite sheet alumino-silicate clay, exchanged with protons (H+). This solid non-toxic catalyst was successfully used as cationic catalyst for the polymerization of D,L-Lactid at 100°C. Interactions between Maghnite-H+ platelets and the monomer (D,L-Lactide) were studied by solid state 1H, 27Al and 29Si NMR spectroscopy. The results show that, the mechanism of the reaction involves both Brønsted and Lewis acid sites on Maghnite surface.ABM, ABC, ABPol2016-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000100132Materials Research v.19 n.1 2016reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-MR-2015-0322info:eu-repo/semantics/openAccessAslya,ElkebirHarrane,AmineBelbachir,Mohamedeng2016-03-29T00:00:00Zoai:scielo:S1516-14392016000100132Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2016-03-29T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism study
title Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism study
spellingShingle Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism study
Aslya,Elkebir
D
L-Lactide
poly (D,L-Lactide)
PLA
Solid state NMR
Montmorillonite
Solid Catalyst
title_short Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism study
title_full Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism study
title_fullStr Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism study
title_full_unstemmed Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism study
title_sort Polymerization of DL-Lactide induced by Protonated Montmorillonite clay as a solid catalyst: Mechanism study
author Aslya,Elkebir
author_facet Aslya,Elkebir
Harrane,Amine
Belbachir,Mohamed
author_role author
author2 Harrane,Amine
Belbachir,Mohamed
author2_role author
author
dc.contributor.author.fl_str_mv Aslya,Elkebir
Harrane,Amine
Belbachir,Mohamed
dc.subject.por.fl_str_mv D
L-Lactide
poly (D,L-Lactide)
PLA
Solid state NMR
Montmorillonite
Solid Catalyst
topic D
L-Lactide
poly (D,L-Lactide)
PLA
Solid state NMR
Montmorillonite
Solid Catalyst
description Maghnite- H+ is Algerian montmorillonite sheet alumino-silicate clay, exchanged with protons (H+). This solid non-toxic catalyst was successfully used as cationic catalyst for the polymerization of D,L-Lactid at 100°C. Interactions between Maghnite-H+ platelets and the monomer (D,L-Lactide) were studied by solid state 1H, 27Al and 29Si NMR spectroscopy. The results show that, the mechanism of the reaction involves both Brønsted and Lewis acid sites on Maghnite surface.
publishDate 2016
dc.date.none.fl_str_mv 2016-02-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000100132
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000100132
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/1980-5373-MR-2015-0322
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.19 n.1 2016
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
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