Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation Resistance
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500222 |
Resumo: | Abstract The coating formation by Fe-Cr-Si codeposition was done in a single step via Halide Activated Pack Cementation (HAPC) on Nb-Si alloy with the aim of improving the oxidation resistance. The activator salt and temperature selections for HAPC process were obtained by thermodynamic analysis. The isothermal oxidation test results for the coated alloy at 1200 °C for 62 h showed good oxidation resistance. The mass gain was 17.5 mg/cm2. Furthermore, no cracks and spallation on the oxide layers were observed for the coated alloy after the oxidation test, being that the oxidative kinetics curve is in accordance with the parabolic rate law. On the other hand, total oxidation was observed for the uncoated alloy after 12 h at 1200 °C in the isothermal oxidation test. The mass gain was 49.27 mg/cm2 and several cracks and spallation on the oxide layers led to a severe oxidation process. |
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Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation ResistanceNb-Si based alloysHalide Activated Pack Cementation (HAPC process)Fe-Cr-Si CodepositionThermodynamic AnalysisOxidation ResistanceAbstract The coating formation by Fe-Cr-Si codeposition was done in a single step via Halide Activated Pack Cementation (HAPC) on Nb-Si alloy with the aim of improving the oxidation resistance. The activator salt and temperature selections for HAPC process were obtained by thermodynamic analysis. The isothermal oxidation test results for the coated alloy at 1200 °C for 62 h showed good oxidation resistance. The mass gain was 17.5 mg/cm2. Furthermore, no cracks and spallation on the oxide layers were observed for the coated alloy after the oxidation test, being that the oxidative kinetics curve is in accordance with the parabolic rate law. On the other hand, total oxidation was observed for the uncoated alloy after 12 h at 1200 °C in the isothermal oxidation test. The mass gain was 49.27 mg/cm2 and several cracks and spallation on the oxide layers led to a severe oxidation process.ABM, ABC, ABPol2020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500222Materials Research v.23 n.5 2020reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2020-0105info:eu-repo/semantics/openAccessCruz,Anderson Weslei daGlória,Raphael FelcaNogueira,Rafaela de OliveiraChaia,NabilSilva,GilbertRodrigues,Geovanieng2020-11-30T00:00:00Zoai:scielo:S1516-14392020000500222Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2020-11-30T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation Resistance |
title |
Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation Resistance |
spellingShingle |
Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation Resistance Cruz,Anderson Weslei da Nb-Si based alloys Halide Activated Pack Cementation (HAPC process) Fe-Cr-Si Codeposition Thermodynamic Analysis Oxidation Resistance |
title_short |
Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation Resistance |
title_full |
Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation Resistance |
title_fullStr |
Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation Resistance |
title_full_unstemmed |
Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation Resistance |
title_sort |
Fe-Cr-Si Codeposition on Nb-Si based Alloys via Halide Activated Pack Cementation to Improve Oxidation Resistance |
author |
Cruz,Anderson Weslei da |
author_facet |
Cruz,Anderson Weslei da Glória,Raphael Felca Nogueira,Rafaela de Oliveira Chaia,Nabil Silva,Gilbert Rodrigues,Geovani |
author_role |
author |
author2 |
Glória,Raphael Felca Nogueira,Rafaela de Oliveira Chaia,Nabil Silva,Gilbert Rodrigues,Geovani |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Cruz,Anderson Weslei da Glória,Raphael Felca Nogueira,Rafaela de Oliveira Chaia,Nabil Silva,Gilbert Rodrigues,Geovani |
dc.subject.por.fl_str_mv |
Nb-Si based alloys Halide Activated Pack Cementation (HAPC process) Fe-Cr-Si Codeposition Thermodynamic Analysis Oxidation Resistance |
topic |
Nb-Si based alloys Halide Activated Pack Cementation (HAPC process) Fe-Cr-Si Codeposition Thermodynamic Analysis Oxidation Resistance |
description |
Abstract The coating formation by Fe-Cr-Si codeposition was done in a single step via Halide Activated Pack Cementation (HAPC) on Nb-Si alloy with the aim of improving the oxidation resistance. The activator salt and temperature selections for HAPC process were obtained by thermodynamic analysis. The isothermal oxidation test results for the coated alloy at 1200 °C for 62 h showed good oxidation resistance. The mass gain was 17.5 mg/cm2. Furthermore, no cracks and spallation on the oxide layers were observed for the coated alloy after the oxidation test, being that the oxidative kinetics curve is in accordance with the parabolic rate law. On the other hand, total oxidation was observed for the uncoated alloy after 12 h at 1200 °C in the isothermal oxidation test. The mass gain was 49.27 mg/cm2 and several cracks and spallation on the oxide layers led to a severe oxidation process. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500222 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500222 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2020-0105 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.23 n.5 2020 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212677867012096 |